专利号:US-9716239-B2 优先权日:2015-09-25 标题 :Phototunable metal-organic framework compositions, and methods of synthesis thereof 发明人:MU BIN; SHAN BOHAN 权利人:UNIV ARIZONA STATE; ARIZONA BOARD OF REGENTS ON BEHALF OF ARI 摘要:Some embodiments include a method of preparing a phototuned metal-organic framework by forming a first solution by dissolving ZrOCl 2 .8H 2 O in dimethylformamide (DMF) and formic acid, mixing and dissolving 1,4-phenylenediacrylic acid in a second solution of dimethylformamide (DMF) and trimethylamine, and at least partially mixing the first and second solutions to form a mixture. The method further includes sealing the mixture in an autoclave and heating the mixture to above ambient temperature for a specified period of time to prepare ZrPDA metal-organic framework, and extracting the ZrPDA metal-organic framework and at least partially reacting to a specified degree at least some of ZrPDA metal-organic framework through [2+2] cycloaddition reactions. The specified degree can be tunable based at least in part on at least one of the intensity of UV radiation, the exposure time, and the UV wavelength.
专利号:WO-2004050654-A1 优先权日:2002-11-29 标 题 :Synthesis of pyrrolidine compound and salt thereof 发明人:KAWANISHI YASUYUKI; UENAKA MASAAKI; IDE YUTAKA; SHINOMOTO SHOJI; OKUNO TAKAYUKI 权利人:SHIONOGI & CO; KAWANISHI YASUYUKI; UENAKA MASAAKI; IDE YUTAKA; SHINOMOTO SHOJI; OKUNO TAKAYUKI 摘要:A p-toluenesulfonate, sulfate, or hydrochloride of the compound represented by the formula (I): (I) a solvate of any of these, or crystals of any of these; and processes for producing these.
专利号:US-2014120075-A1 优先权日:2011-05-24 标 题 :Nanozyme Compositions and Methods of Synthesis and Use Thereof 发明人:KABANOV ALEXANDER V; MANICKAM DAVIKA SOUNDARA; BRYNSKIKH ANNA M 权利人:UNIV NEBRASKA 摘要:Nanozymes and methods of use and synthesis thereof are provided.
专利号:US-2017092879-A1 优先权日:2015-09-25 标题:Phototunable metal-organic framework compositions, and methods of synthesis thereof
专利号:WO-2012162490-A1 优先权日:2011-05-24 标 题 :Nanozyme compositions and methods of synthesis and use thereof
专利号:US-5019379-A 优先权日:1987-07-31 标题 :Unsaturated polyanhydrides 发明人:DOMB ABRAHAM J; LANGER ROBERT S 权利人:MASSACHUSETTS INST TECHNOLOGY 摘要:A class of unsaturated polyanhydrides having double bonds available for secondary polymerization is disclosed. A crosslinked material having improved or different physical and mechanical properties can be prepared from these polyanhydrides, via secondary polymerization. The synthesis and characteristics of one unsaturated polyanhydride based on fumaric acid and its copolymers with aliphatic and aromatic diacids, prepared by either the melt-polycondensation method or by solution polymerization, is described in detail. These polymers are well suited for use in controlled release drug delivery devices. The polymers can also be used as a bioerodible bone cement where the polymer is first cast as a solution onto a bone fracture and then crosslinked by radiation or radical polymerization to yield a strong, adhesive material.
摘要:National Toxicology Program, Institute of Environmental Health Sciences, National Institutes of Health (NTP). 1992. National Toxicology Program Chemical Repository Database. Research Triangle Park, North Carolina. 摘要:Kellogg, R. M., Science of Synthesis, (2006) 8, 1511.