CAS: 15983-86-5; But-3-Enyl-Dichloro-Methylsilane

📜4-溴-1-丁烯,甲基三氯硅烷置于magnesium体系中,用 乙醚 用作溶剂,化学反应 15.5H,反应生成丁烯基二氯甲基硅烷
参考文献:Enzymatic Synthesis Of Enantiomerically Enriched D-And L-3-Silylated Alanines By Deracemization Of Dl-5-Silylmethylated Hydantoins
标题:Enzymatic Synthesis Of Enantiomerically Enriched D-And L-3-Silylated Alanines By Deracemization Of Dl-5-Silylmethylated Hydantoins
摘要:The Hydantoinase Process Was Shown To Be Extendable To The Production Of Highly Lipophilic,Silicon-Containing Amino Acids. Two Hydantoinases Of Different Origin And Stereoselectivities And One L-N-Carbamoylase Were Used For The Highly Stereoselective Bioconversion Of (Dimethyl)Phenylsilyl-And 1-Methyl-1-Silacyclopentyl Substituted Alanine Derivatives. The Enantiomeric Purities And Absolute Configuration Of The Products Were Determined With Reference Compounds That Were Synthesized With The Aid Of The Evans Oxazolidinone Auxiliary. (C) 2001 Elsevier Science Ltd. All Rights Reserved.
Doi:10.1016/s0957-4166(01)00028-3