CAS: 14165-55-0; Germanium Tetraethoxide

该化合物是一种金属-有机化合物,广泛用于溶胶过程和薄膜沉降过程,其高纯度和再活性使它成为二氧化(GeO2)和其他基于的材料合成的首选前体,该化合物在有机溶剂中表现出极高溶性,有利于光学涂层,半导体和催化等应用中形成同质薄膜,其受控制的水解特性使得能够精确地调整纳米材料的特性.

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2414-98-4 925-93-9 20398-06-5

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sodium ethanolate ethanol germaniumtetrachloride tributyltin ethoxidegermanium silica gel

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    专利号:US-2007074541-A1
    优先权日:2003-10-10
    标 题:Synthesis of germanium sulphide and related compounds
    发明人:BADDING JOHN V; HEWAK DANIEL W; HUANG CHUNG-CHE
    权利人:UNIV SOUTHAMPTON
    摘要:The invention relates to synthesis of germanium sulphide glasses and optical devices formed therefrom. In a chemical vapour deposition process, germanium tetrachloride is reacted with hydrogen sulphide at temperatures in the range 450-700° C. to form germanium sulphide. Lower temperatures within this range of 450-550° C. directly produce a glass, whereas higher temperatures within the range of 600-700° C. produce a crystalline powder which can then be reduced to a glass by subsequent melting and annealing. The reaction is preferably carried out at atmospheric pressure or slightly higher. Thin films and bulk glasses suitable for optical waveguides can be formed directly in one processing step as can powders and microspheres. The materials synthesised are of a high purity with low oxide impurities and only trace levels of transition metal ions.

    专利号:US-10273161-B2
    优先权日:2017-01-11
    标题:Synthesis of MFI framework type molecular sieves
    发明人:XIE DAN
    权利人:CHEVRON USA INC
    摘要:A method is provided for the synthesis of MFI framework type molecular sieves using 1,6-bis(cyclopropylmethyl)-1,1,6,6-tetramethylhexane-1,6-diaminium cations as a structure directing agent.

    专利号:US-6193784-B1
    优先权日:1998-06-29
    标 题:Method for production of zeolite membrane
    发明人:YAZAWA TETSUO; JIN TETSURO; KURAOKA KOJI
    权利人:AGENCY IND SCIENCE TECHN
    摘要:A method for the formation of a zeolite membrane, which comprises preparing raw materials (a) and (b) for the synthesis of zeolite, at least one of the raw materials containing water, positioning the raw material (a) for the synthesis of zeolite so as to contact one lateral face of a porous body and the raw material (b) therefor so as to contact the other lateral face of the porous body, causing the two raw materials (a) and (b) to permeate the porous body thereby forming an interface of the two raw material in pores of the porous body, and inducing a reaction of hydrothermal synthesis at the interface, a porous body obtained by the method and having a zeolite membrane formed in the pores thereof, and a membrane used for separation and purification of gas and formed of the porous body.

    专利号:US-4565896-A
    优先权日:1984-10-22
    标 题 :Process for low pressure synthesis of ethylene glycol from synthesis gas
    发明人:KNIFTON JOHN F; DURANLEAU ROGER G
    权利人:TEXACO INC
    摘要:This invention relates to the manufacture of ethylene glcyol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus formaldehyde in the presence of a homogeneous liquid catalyst containing an effective amount of cobalt-containing compound and a silicon or germanium-containing promoter and a solvent at a temperature of at least 50 DEG C. and a pressure of at least 500 psi wherein said ethylene glycol product separates as a separate liquid phase from the solvent.

    专利号:US-4609768-A
    优先权日:1984-10-22
    标题 :Process for synthesis of ethylene glycol from synthesis gas plus 1,3-dioxolane using 1,3-dioxolane as a solvent
    发明人:KNIFTON JOHN F; LIN JIANG-JEN; GRICE NEAL J
    权利人:TEXACO INC
    摘要:This invention relates to the manufacture of ethylene glycol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus 1,3-dioxolane in the presence of a homogenous liquid catalyst containing an effective amount of cobalt-containing compound, a silane or germane-containing promoter dispersed in a dioxolane solvent at a temperature of at least 50° C. and a pressure of at least 500 psi.

    专利号:US-4568780-A
    优先权日:1984-10-22
    标 题 :Process for low pressure synthesis of ethylene glycol from synthesis gas plus 1,3-dioxolane
    发明人:KNIFTON JOHN F
    权利人:TEXACO INC
    摘要:This invention relates to the manufacture of ethylene glycol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus 1,3-dioxolane in the presence of a homogenous liquid catalyst containing an effective amount of cobalt-containing compound and a silane or germane-containing promoter dispersed in a hydrocarbon solvent at a temperature of at least 50 DEG C. and a pressure of at least 500 psi, where the particular solvents used allow the desired product to be separated from the reaction mixture by phase separation.

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