CAS: 701261-35-0; Neopentylboronic Acid

相似化合物

1150655-02-9 84110-40-7 98139-72-1

新戊基三氟硼酸钾置于iron(Iii) Chloride,水体系中,用 四氢呋喃 作为反应溶剂,化学反应 0.42H,以98%的收率获得产物新戊基硼酸
参考文献:三氯化铁促进有机三氟硼酸钾的水解
标题:三氯化铁促进有机三氟硼酸钾的水解
摘要:在三氯化铁的存在下,有机三氟硼酸钾的水解在室温下平稳进行,以非常好或优异的产率提供相应的有机硼酸.水解对于芳基三氟硼酸盐以及烯基-和烷基三氟硼酸盐是有效的.
DOI:10.1016/j.Tetlet.2011.09.140

专利信息

专利号:US-8207337-B2
优先权日:2007-01-29
标 题:Reagent for organic synthesis reaction containing organic triol borate salt
发明人：MIYAURA NORIO; YAMAMOTO YASUNORI
权利人:MIYAURA NORIO; YAMAMOTO YASUNORI; WAKO PURE CHEM IND LTD
摘要:[Problem] n To provide an organoboron compound-containing reagent for organic synthesis reactions which undergoes no trimerization with dehydration, does not necessitate activation with a base, and is stable and highly active. n [Means for Solving Problems] n The reagent for organic synthesis reactions contains an organic triol borate salt represented by any of the general formulae (I) to (III) and general formula (XVI): (wherein R 1 represents alkyl, alkenyl, etc.; R 2 represents optionally substituted alkyl, alkenyl, alkynyl, etc. or represents hydrogen; m + represents an alkaline metal ion, phosphonium ion, or given ammonium ion; M 2+ represents an alkaline earth metal; X represents halogen or alkoxide; Y represents an alkali metal ion, etc.; A represents optionally substituted methylene; and n represents an integer).