CAS: 6166-86-5; 2,4,6,8,10-Pentamethyl-1,3,5,7,9,2λ3,4λ3,6λ3,8λ3,10λ3-Pentaoxapentasilecane

该化合物是一个环硅烷化合物,其独特结构由五人环组成,内含硅和氧原子;该化合物的五组甲基附于硅原子,造成其疏水性能和低地表紧张;五甲基环球天花氧烷一般没有色和无味,具有低粘度和高热稳定性,适合化妆品,个人护理产品和工业配方的各种应用;其化学稳定性和在环境条件下对降解的耐受性增强了其在需要长期性能的配方中的效用;此外,众所周知,该化合物具有传播丝质感和产品传播能力;然而,与许多硅氧一样,其环境影响和潜在生物累积性是正在进行的研究和监管审查的主题;

结构式图片

欧盟法规

REACH注册ECHA物质C&L通报REACH预注册

上下游产品

CAS号75-54-7 甲基二氯硅烷 | CAS号7732-18-5 水 | CAS号75-77-4 三甲基氯硅烷 | CAS号60-29-7 乙醚 | CAS号1873-88-7 双三甲基硅氧基甲基硅烷

合成工艺路线路线简述

  • 合成目标产物 Pentamethylcyclopentasiloxane 主要起始原料 Dichloromethylsilane And Water
  • (文献来源)合成步骤主要原料 Dichloromethylsilane 和 Water
📜甲基二氯硅烷置于乙醚,甲基安非他命体系中,化学反应生成 2,4,6,8,10-环五硅氧烷,Alkaline Earth Salt Of/the/ Methylsulfuric Acid
参考文献:Sauer; Scheiber; Brewer,Journal Of The American Chemical Society,1946,Vol. 68,P. 963
标题:Sauer; Scheiber; Brewer,Journal Of The American Chemical Society,1946,Vol. 68,P. 963

专利信息


专利号:US-7569652-B2
优先权日:2004-08-20
标 题 :Synthesis and characterization of novel cyclosiloxanes and their self- and co-condensation with silanol-terminated polydimethylsiloxane
发明人:KENNEDY JOSEPH P; DAUM JEREMY; ERDODI GABOR
权利人:UNIV AKRON
摘要:The present invention is directed to syntheses of cyclolinear networks. Two novel cyclic siloxanes were used as starting materials. The cyclic siloxanes are self-condensed and co-condensed with silanol-terminated polydimethylsiloxane to vinyl-terminated cyclolinear polymers. Cyclolinear networks can be synthesized by hydrosilylation of vinyl-terminated cyclolinear polyorganosiloxanes with a copolymer of dimethylsiloxane and methylhydrosiloxane.

专利号:US-8344170-B2
优先权日:2002-08-16
标 题:Poly (cyclosiloxane) composition and method of synthesis thereof
发明人:KENNEDY JOSEPH P; KURIAN PIOUS
权利人:UNIV AKRON; KENNEDY JOSEPH P; KURIAN PIOUS
摘要:A poly(cyclosiloxane) network comprises the hydrosilation reaction product of a cyclosiloxane of the formula (I) wherein R and R 2 are the same or different for each siloxane moiety of hydrogen, an alkyl group, an aryl group, and a cycloalkyl group, and wherein n is an integer from 3 to 8, wherein the cyclosiloxanes are joined by moieties selected from the group consisting of oxygen atoms, linear silanols, branched silanols, halosilanes, alkoxysilanes, vinyl silanes, allyl silanes, vinyl siloxanes, and allyl siloxanes, wherein the Si—O bonds of the cyclosiloxanes are substantially unrearranged compared to the cyclosiloxane precursors of the network. A process for the preparation of a poly(cyclosiloxane) network comprises providing a cyclosiloxane; providing a crosslinking group selected from the group consisting of linear silanols, branched silanols, halosilanes, alkoxysilanes, vinyl silanes, allyl silanes, vinyl siloxanes, and allyl siloxanes; contacting the cyclosiloxane and crosslinking group under condensation reaction conditions such that the crosslinking groups provide Si—O—Si linkages between the cyclosiloxane moieties to form a poly(cyclosiloxane) network composition.

专利号:US-7071277-B2
优先权日:2001-10-16
标题 :Poly(cyclosiloxane) composition and synthesis
发明人:KENNEDY JOSEPH P; KURIAN PIOUS
权利人:UNIV AKRON
摘要:A poly(cyclosiloxane) is synthesized by oxidation with water in the presence of a Pt catalyst, followed immediately by polycondensation of the Si—OH groups to form Si—O—Si linkages. Thus, pentamethylcyclopentasiloxane can be polymerized into poly(pentamethycyclopentasiloxane).

专利号:US-7642332-B2
优先权日:2006-08-14
标 题:Amphiphilic networks, process for producing same, and products made therefrom
发明人:KENNEDY JOSEPH P; KARUNAKARAN RADHAKRISHNAN
权利人:UNIV AKRON
摘要:The present invention relates to the production of amphiphilic copolymer networks, or co-networks, and to methods for preparing amphiphilic co-networks. Furthermore, the present invention relates to products and/or films made from the amphiphilic co-networks produced in accordance with the synthesis methods of the present invention. Additionally, the present invention relates to crosslinked amphiphilic co-networks comprising at least one hydrophilic segment and at least one hydrophobic segment. In one embodiment, the hydrophilic segments include at least one polyalkyl glycol (e.g., polyethylene glycol (PEG)) and the hydrophobic segments include at least one di-alkenyl and/or di-alkynyl terminated polysiloxane (e.g., polydimethylsiloxane (PDMS)). In another embodiment, the amphiphilic co-networks of the present invention are optically clear and highly oxophilic.

专利号:US-2006041098-A1
优先权日:2004-08-20
标题 :Synthesis and characterization of novel cyclosiloxanes and their self- and co-condensation with silanol-terminated polydimethylsiloxane

供应商参考报价(招募中)

品牌试剂参考报价(招募中)

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

合成参考文献


参考文献:10.1007/s10965-024-03918-4
摘要:Men Y, Meng Y, Sun Y, Wang X, Liu S, Li C. Photo actuation performances of animal hair fiber-reinforced polysiloxane liquid crystalline elastomer composites. J Polym Res. 2024 Feb 27;31(3). doi: 10.1007/s10965-024-03918-4.
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