Wismutnitrat 反应生成氢氧化铋 参考文献:Mercuiro,J. P.;Lambachri,A.;Frit,B.,Sci. Ceram. 14: Proc. 14Th Int. Conf.,Canterbury,Sept. 7-9Th,1987,Sto+ 标题:Mercuiro,J. P.;Lambachri,A.;Frit,B.,Sci. Ceram. 14: Proc. 14Th Int. Conf.,Canterbury,Sept. 7-9Th,1987,Sto+
专利信息
专利号:WO-2006067109-A1 优先权日:2004-12-22 标 题 :Process for the mechanochemical synthesis of metal carboxylate 发明人:ROBIN JEAN-JACQUES; TIFFES DOMINIQUE; HANNECART ETIENNE 权利人:SOLVAY; ROBIN JEAN-JACQUES; TIFFES DOMINIQUE; HANNECART ETIENNE 摘要:Process for the mechanochemical synthesis of metal carboxylate Process for the mechanochemical synthesis of metal carboxylate, according to which, in a first stage, a mixture (M) comprising at least one acidic substance (A) selected from carboxylic acids and carboxylic acid anhydrides, at least one basic inorganic metal compound (B), water (C) and at least one third solid body (D) which is chemically inert with regard to the components (A), (B) and (C) and the metal carboxylate is formed and, in a second stage, the abovesaid mixture (M) is subjected to a mechanical stress sufficient to bring about a mechanochemical reaction between the acidic substance (A) and the basic inorganic metal compound (B).
专利号:US-5753726-A 优先权日:1995-12-20 标 题:Synthesis of modified epoxy resins for cathodic electrodeposition with catalyst deactivation and diol modification 发明人:REUTER HARDY; JOUCK WALTER; OTT GUENTHER 权利人:BASF LACKE & FARBEN 摘要:Epoxy resins for preparing water-dispersible binders for cathodic electrodeposition coating materials, the epoxy resin being preparable by reacting a) polyepoxides having at least one glycidyl group per molecule b) and, optionally, up to 60% by weight, based on the overall epoxy resin reaction product, of aliphatic and/or alicyclic hydroxy compounds having preferably two or on average less than two hydroxyl groups per molecule and a molecular weight of less than 9000 g/mol, c) in the presence of a catalyst consisting of neutral metal salts, such as alkali metal salts and alkaline earth metal salts, zinc salts and nickel salts of tetrafluoroboric, tetrachloroboric, hexafluoro- antimonic,hexachloroantimonic,hexafluorophosphoric, perchlorate and periodic acid, and d) adding a deactivating agent which prevents the epoxy groups reacting further or effectively reduces the rate of such reaction as soon as the phenolic hydroxyl groups have already substantially reacted and at least 0.6% by weight of epoxy groups are still present, based on the overall weight of the epoxy resin reaction product.\\!
专利号:US-11629137-B2 优先权日:2017-04-24 标 题:Methods of manufacturing of niraparib 发明人:STEWART ALISTAIR; TOTO ANTHONY JOSEPH; CHEN FRANK XING; WU GEORGE 权利人:TESARO INC 摘要:Disclosed herein are methods and processes of preparing niraparib and pharmaceutically acceptable salts thereof, and intermediates and their salts useful for the synthesis of niraparib.
专利号:US-3641082-A 优先权日:1969-02-17 标题 :Process for the alkylation alkenylation or arylation of heavy-metla salts by means of organo-triptychsiloxazolidines 发明人:MULLER RICHARD; FREY HANS; DATHE CHRISTIAN 权利人:INST SILIKON & FLUORKARBONCHEM 摘要:PROCESS FOR THE ALKYLATOR, XXXVLATION OR ARYLATION OF SALTS OR HYDROXIDES OF HEAVY METALS, SUCH AS MERCURY, BXXOUTH, ANTIMONY AND XXX COMPRISING REACTING THEM WITH ORGANO-TRIPTYCH-SILEXXOLIDINES IN THE PRESENCE OF FLUORINE. THE PRODUCTS ACCORDING TO THIS INVENTION ARE USEFUL AS PHARMACEUTICALS AND PESTICIDES, AND MAY ALSO SERVE IN THE SYNTHESIS OF OTHER USEFUL PRODUCTS.
专利号:RU-2186055-C2 优先权日:1995-05-24 标 题 :Method of synthesis of derivatives 3-carboxy-4-hydroxybenzaldehyde, method of synthesis of 4-hydroxybenzaldehyde, methods of synthesis of vanillin and ethylvanillin
专利号:US-2011198530-A1 优先权日:2010-02-18 标题:Method of Producing a Bismuth Vanadium Oxide Derivative of Bi4V2O11 Using Molten Salt Synthesis, and Product Produced 发明人:ROY BANASRI 权利人:NEW MEXICO TECHNICAL FOUNDATION 摘要:A method comprising mixing a bismuth precursor, a vanadium precursor, and at least one metal dopant precursor together with a salt or salt mixture having a eutectic melting temperature of no greater than 680° C. to form a homogeneous mixture, which is heated to a temperature of from 550° C. to 700° C. to produce a molten state of the salt or salt mixture and to obtain a metal doped bismuth vanadium oxide product that is a derivative of Bi 4 V 2 O 11 , which is then cooled. The thus-produced metal doped bismuth vanadium oxide product is present in loose platelet form, with the platelets capable of being aligned such that their planes are substantially parallel to one another.
参考标题:Investigation Of The Formation Process Of Zeolite-Like 3D Frameworks Constructed With ε-Keggin-Type Polyoxovanadomolybdates With Binding Bismuth Ions And Preparation Of A Nano-Crystal 作者:Zhenxin Zhang,Masahiro Sadakane,Toru Murayama,Wataru Ueda 摘要:Reaction Conditions For The Synthesis Of An îµ-Keggin-Type Polyoxometalate-Based 3D Framework, (Nh4)2.8H0.9[îµ-Vmo9.4V2.6O40Bi2]A.7.2H2O (Denoted As Moâvâbi Oxide), Are Studied. It Is Found That The Reaction Time, Temperature, Ph Of The Solution, And Starting Compounds Affect The Production Of Moâvâbi Oxide. The Crystal Size Of Moâvâbi Oxide Is Controllable By Changing Bismuth Compounds. Nanometer-Sized Moâvâbi Oxide Is Produced Using A Water-Soluble Bismuth Compound, Bi(No3)3A.5H2O, Whereas Micrometer To Submicrometer-Sized Moâvâbi Oxide Is Produced Using Bi(Oh)3, Which Is Less Soluble In Water. The Particle Size Of The Material Affects The Properties Of The Material, Such As Surface Area And Catalysis. The Investigation Of The Formation Process Of The Material Is Carried Out With Raman Spectroscopy, Which Indicates That Mixing (Nh4)6Mo7O24A.4H2O, Voso4A.5H2O, And Bismuth Ions In Water Produces The îµ-Keggin Polyoxovanadomolybdate Together With A Ball-Shaped Polyoxovanadomolybdate, [mo72V30O282(H2O)56(So4)12]36A (Denoted As Mo72V30}). By Heating The Reaction Mixture, The îµ-Keggin Polyoxovanadomolybdate Assembles With Bismuth Ions To Form Moâvâbi Oxide, Whereas Mo72V30} Assembles With Other Vanadium And Molybdenum Ions To Form Orthorhombic Moâv Oxide.
合成参考文献
摘要:Merck Index - O'Neil MJ, Heckelman PE, Dobbelaar PH, Roman KJ (eds). The Merck Index, An Encyclopedia of Chemicals, Drugs, and Biologicals, 15th Ed. Cambridge, UK: The Royal Society of Chemistry, 2013.