CAS: 999-90-6; S-Tert-Butyl Ethanethioate
该化合物是一种硫酸箱酸酯,其特点是其异丁基硫酸.该化合物主要用于有机合成,作为一种多用途中间体,特别是用于制造硫酯和含硫衍生物.其受到发育阻力的乙丁基组组增强了稳定性,使其适合需要控制再活性的反应.二碳基功能允许选择性的转化,包括核分裂替代和聚合.该化合物的界定明确的结构和纯度确保了研究和工业应用的一贯性.建议由于对湿气和氧化的潜在敏感性,在惰性条件下进行适当处理.
- 英文名称S-Tert-Butyl Ethanethioate
- 中文名称S-叔丁基硫代乙酸酯
- IUPAC名称S-tert-butyl ethanethioate
- 其它别名2-Propanethiol,2-methyl-, acetate (6CI); Acetic acid, thio-, S-tert-butyl ester (7CI,8CI); S-tert-Butyl thioacetate
- CAS编号999-90-6
- MFCD编号:MFCD00042941
- EINECS号:627-172-5
- 分子式:C6H12OS分子量:132.22
- 产品CID: 2033820
- 产品分类化学试剂 → 有机试剂 → 硫醇酯
物理性质
MSDS等安全信息
欧盟法规
ECHA物质C&L通报上下游产品
CAS号108-24-7 乙酸酐 | CAS号75-66-1 叔丁基硫醇 | CAS号631-61-8 乙酸铵 | CAS号75-36-5 乙酰氯 | CAS号463-51-4 乙烯酮 | CAS号507-19-7 溴代叔丁烷 | CAS号507-09-5 硫代乙酸 | CAS号507-20-0 氯代叔丁烷 | CAS号34832-35-4 SODIUM THIOLACETATE | CAS号75-05-8 乙腈 | CAS号507-20-0 氯代叔丁烷 | CAS号75-36-5 乙酰氯 | CAS号214287-10-2 1-tert-butylsul... | CAS号15925-47-0 乙酰硫代乙酸S-叔丁酯 | CAS号110-06-5 叔丁基二硫 | CAS号121534-52-9 (2-tert-butylsu... | CAS号17510-46-2 (1-叔丁基乙烯氧基)三甲基硅烷 | CAS号68931-52-2 (3-Oxo-2-pent-2... | CAS号58058-57-4 3-hydroxy-3,3-d...合成工艺路线路线简述
📜Tert-Butylmercapto-Acetylen置于硫酸,Mercury(II) Sulfate体系中,化学反应生成 S-叔丁基硫代乙酸酯
参考文献:Arens Et Al.,Recueil Des Travaux Chimiques Des Pays-Bas,1956,Vol. 75,P. 1459,1467
标题:Arens Et Al.,Recueil Des Travaux Chimiques Des Pays-Bas,1956,Vol. 75,P. 1459,1467
海关参考信息
- 2912110000-甲醛
2912120000-乙醛
2930909099-其他有机硫化合物 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-2004018598-A1
优先权日:2000-05-30
标题 :Bio-intermediates for use in the chemical synthesis of polyketides
发明人：SANTI DANIEL; ASHLEY GARY; MYLES DAVID C
摘要:The present invention relates to compounds made by a subset of modules from one or more polyketide synthase (“PKSâ€?) genes that are used as starting material in the chemical synthesis of novel molecules, particularly naturally occurring polyketides or derivatives thereof. The biologically derived intermediates (“bio-intermediatesâ€?) generally represent particularly difficult compounds to synthesize using traditional chemical approaches due to one or more stereocenters. In one aspect of the invention, an intermediate in the synthesis of epothilone is provided that feeds into the synthetic protocol of Danishefsky and co-workers. In another aspect of the invention, intermediates in the synthesis of discodermolide are provided that feed into the synthetic protocol of Smith and co-workers. By taking advantage of the inherent stereochemical specificity of biological processes, the syntheses of key intermediates and thus the overall syntheses of compounds like epothilone and discodermolide are greaty simplified.
专利号:WO-0212534-A2
优先权日:2000-08-09
标题 :Bio-intermediates for use in the chemical synthesis of polyketides
专利号:EP-1307579-A2
优先权日:2000-08-09
标 题 :Bio-intermediates for use in the chemical synthesis of polyketides
专利号:US-2002052028-A1
优先权日:2000-08-09
标题:Bio-intermediates for use in the chemical synthesis of polyketides
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
摘要:Witt, D., Science of Synthesis Knowledge Updates, (2011) 3, 297.
📝 需求与反馈
尽可能描述清楚需求与问题信息
