CAS: 96489-71-3; Pyridaben

该化合物是一种选择性杀虫剂,对包括虱子,和昆虫在内的各种害虫具有功效.它独特的行动方式抑制了米托昆德里亚麻黄碱的生产,导致快速击倒和长期控制. 这一特性使得它成为各种农业环境中综合虫害管理战略的有吸引力的选择.

结构式图片

物理性质

欧盟法规

统一分类与标签压力设备指令-第1组危险流体REACH注册ECHA物质ECHA物质欧盟农药活性物质工作场所安全标识要求C&L通报REACH预注册废弃物危险特性清单

上下游产品

CAS号19692-45-6 4-叔丁基苄氯 | CAS号96490-18-5 4-氯-2-(1,1-二甲基乙... | CAS号18880-00-7 4-叔丁基苄溴

合成工艺路线路线简述

  • 96490-18-5 = 96489-71-3
    反应条件:1.1 Reagents: Tert-Butyl Peroxide Catalysts: N-Bromosuccinimide,Nickel Acetate,Bathocuproine Solvents: Benzene; 24 H,140 °C
    标题:Preparation Method Of Alkyl Thioether By Oxidative Dehydrogenation Coupling Reaction
    参考文献:China]

    = 96489-71-3 [标题:Reaction Conditions
    标题:Preparation Of Insecticidal Pyridazinone Derivatives
    参考文献:Canada]

    = 96489-71-3 [标题:Reaction Conditions
    标题:Preparation Of Pyridazinone Derivatives And Their Use As Antiallergics
    参考文献:Japan]

    = 96489-71-3 [标题:Reaction Conditions
    标题:Pyridazinones
    参考文献:Japan]

    49543-63-7 + 84956-71-8 = 96489-71-3
    反应条件:1.1 Reagents: Sodium Methoxide Solvents: Methanol; 1 H,10 - 15 °C
    标题:Synthesis And Crystal Structure Of 2-Tert-Butyl-5-(4-Tert-Butylbenzylthio)-4-Chloropyridazin-3(2H)-One
    作者:Xu,Liang-Zhong; Yu,Guan-Ping; Xu,Zhong-Jie; Zhang,Gong-Sheng; Zhai,Zhi-Wei
    参考文献:Chemical Research In Chinese Universities 日期:2006 卷标:22(6) 页码:763-764]

    49543-63-7 + 84956-71-8 = 96489-71-3
    反应条件:1.1 Reagents: Sodium Methoxide Solvents: Methanol; 0 - 15 °C; 1 H,5 °C
    标题:Synthesis Of Pyridaben Active Compound With High Content
    作者:Wu,Xing-Ye; Wang,Chong-Lei
    参考文献:Huaxue Yu Nianhe 日期:2014 卷标:36(6) 页码:430-432]

    899788-67-1 + 84956-71-8 = 96489-71-3
    反应条件:1.1 Reagents: Sodium Ethoxide Solvents: Ethanol; 0 - 5 °C; 1 H,10 - 15 °C
    标题:Process For One-Step Synthesis Of Pyridaben By Nucleophilic Substitution Reaction
    参考文献:China]

    96490-18-5 = 96489-71-3
    反应条件:1.1 Reagents: Tert-Butyl Peroxide Catalysts: Nickel Acetate,Bathocuproine; 24 H,140 °C
    标题:Nickel-Catalyzed Oxidative Dehydrogenative Coupling Of Alkane With Thiol For C(Sp3)-S Bond Formation
    作者:Liu,Shengping; Jin,Shengnan; Wang,Hao; Qi,Zaojuan; Hu,Xiaoxue; Et Al
    参考文献:Tetrahedron Letters 日期:2021 卷标:68]

    19692-45-6 + 96490-18-5 = 96489-71-3 [标题:Reaction Conditions
    标题:Pyridazinone Derivatives
    参考文献:Japan]

    = 96489-71-3 [标题:Reaction Conditions
    标题:Thiadiazolyl Oxime Ether Methoxy Acrylate Derivative,Synthesis Method And Application Thereof
    参考文献:China]

    = 96489-71-3 [标题:Reaction Conditions
    标题:The Study On Synthesis Of Pyridaben
    作者:Hu,Wenbin; Xue,Zhengqing
    参考文献:Jaingxi Nongye Daxue Xuebao 日期:1999 卷标:21(4) 页码:612-615]

    = 96489-71-3 [标题:Reaction Conditions
    标题:Antitumor Agents,Novel 3(2H)-Pyridazinone Derivatives,And Their Preparation.
    参考文献:European Patent Organization]

    = 96489-71-3 [标题:Reaction Conditions
    标题:A New Process For The Preparation Of Pesticidal 2-Tert-Butyl-4-Chloro-5-[(P-Tert-Butylbenzyl)Thio]-3(2H)-Pyridazine
    参考文献:Japan]

    = 96489-71-3 [标题:Reaction Conditions
    标题:Pyridazinone Derivatives
    参考文献:Japan]

    = 96489-71-3 [标题:Reaction Conditions
    标题:Pesticidal Pyridazinones
    参考文献:Japan
4-氯-2-(1,1-二甲基乙基)-5-疏基-3(2H)-吡嗪酮 反应生成 哒螨灵
参考文献:Masakazu;Masalkazu;Hirose,Masayoshi;Baba,Masatoshi;Hirata,Kiminori;och+
标题:Masakazu;Masalkazu;Hirose,Masayoshi;Baba,Masatoshi;Hirata,Kiminori;och+

海关参考信息

专利信息


专利号:WO-2025056767-A1
优先权日:2023-09-15
标题 :Process for the preparation of enantiomerically enriched aliphatic amines
发明人:BOU HAMDAN FARHAN; GODINEAU EDOUARD; SMEJKAL TOMAS; DUMEUNIER RAPHAEL; BOUSSEMGHOUNE MOHAMED ABDELOUAHAB; BLUM MATHIAS
权利人:SYNGENTA CROP PROTECTION AG
摘要:The present invention relates to a process for the preparation of enantiomerically enriched cyclobutylamines of formula (I) from α-tertiary cyclobutanones and reacting said enantiomerically enriched cyclobutylamines to enantiomerically enriched cyclobutylamides. Such compounds are useful intermediates in the synthesis of microbiocidal thiazole compounds.

专利号:US-11751567-B2
优先权日:2021-09-23
标 题:Steroidal piperidone derivative, synthesis method, and use thereof
发明人:SHI BAOJUN; JIANG WEIQI; MA SHICHUANG; HU YUXIAO; WANG QIANGPING
权利人:UNIV NORTHWEST A&F
摘要:A steroidal piperidone derivative, a synthesis method, and a use thereof are provided. The steroidal piperidone derivative has a chemical structure shown in general formula (1) or general formula (2), where R is any one selected from the group consisting of alkyl, phenyl, substituted phenyl, and a heterocycle. In the synthesis method of the steroidal piperidone derivative, dehydroepiandrosterone (DHEA) is used as a basic raw material to prepare the steroidal piperidone derivative of the present disclosure through a series of reactions. A product prepared by the synthesis method has a high yield and is easily separated, and thus the synthesis method is the optimal method for preparing the steroidal piperidone derivative of the present disclosure. The present steroidal piperidone derivative exhibits prominent toxic activity against sucking pests, such as aphids, spider mites, rice planthoppers, and B. tabaci, and can be used for the control of a plant pest.

专利号:US-9603951-B2
优先权日:2010-02-08
标题 :Methods and apparatus for synthesizing imaging agents, and intermediates thereof
发明人:LAZEWATSKY JOEL; DEVINE MARYBETH
权利人:LANTHEUS MEDICAL IMAGING INC
摘要:The present invention generally relates to methods and system for the synthesis of imaging agents, and precursors thereof. The methods may exhibit improved yields and may allow for the large-scale synthesis of imaging agents, including imaging agents comprising a radioisotope (e.g., 18 F). Various embodiments of the invention may be useful as sensors, diagnostic tools, and the like. In some cases, methods for evaluating perfusion, including myocardial perfusion, are provided. Synthetic methods of the invention have also been incorporated into an automated synthesis unit to prepare and purify imaging agents that comprise a radioisotope. In some embodiments, the present invention provides a novel methods and systems comprising imaging agent 1, including methods of imaging in a subject comprising administering a composition comprising imaging agent 1 to a subject by injection, infusion, or any other known method, and imaging the area of the subject wherein the event of interest is located.

专利号:US-10906880-B2
优先权日:2016-01-26
标题:Kind of isothiazole oxime ether-containing strobilurin derivatives and its preparation methods and application
发明人:FAN ZHIJIN; CHEN LAI; GUO XIAOFENG; ZHU YUJIE; QIAN XIAOLIN; MA LIUYONG; ZHANG NAILOU; WANG HAIXIA; ZHANG ZHIMING; XU JINGHUA; SONG YINQI
权利人:UNIV NANKAI
摘要:The present invention is that provided a synthesis method of a series of isothiazole oxime ether containing strobilurin derivatives IV. The present invention relates to 3,4-dichloroisothiazolyl oxime ether strobilurin derivatives, and their chemical structural formula is as shown by IV. n n n n n n n n n n The invention discloses the structural formula of the above compound, the synthesis method and the use as an insecticide, a fungicide, an anti-plant virus agent, and an agriculturally acceptable auxiliary or synergist and a commercial insecticide. The use of a fungicide, an anti-plant virus agent and an acaricide in combination for controlling agricultural, forestry, horticultural plant pests, diseases, virus diseases and preparation methods.

专利号:US-9919064-B2
优先权日:2012-08-10
标 题 :Compositions, methods, and systems for the synthesis and use of imaging agents
发明人:CESATI RICHARD R; RADEKE HEIKE S; PANDEY SURESH K; PUROHIT AJAY; ROBINSON SIMON P
权利人:LANTHEUS MEDICAL IMAGING INC
摘要:The present invention provides compounds with imaging moieties for imaging a subject. The present invention also relates to systems, compositions, and methods for the synthesis and use of imaging agents, or precursors thereof. An imaging agent precursor may be converted to an imaging agent using the methods described herein. In some cases, a composition or plurality of imaging agents is enriched in 18 F. In some cases, an imaging agent may be used to image an area of interest in a subject, including, but not limited to, the heart, cardiovascular system, cardiac vessels, brain, and other organs.

专利号:US-9550000-B2
优先权日:2011-09-09
标题 :Compositions, methods, and systems for the synthesis and use of imaging agents
发明人:ROBINSON SIMON P; YU MING
权利人:ROBINSON SIMON P; YU MING; LANTHEUS MEDICAL IMAGING INC
摘要:The present invention relates to systems, compositions, and methods for the synthesis and use of imaging agents, or precursors thereof. An imaging agent precursor may be converted to an imaging agent using the methods described herein. In some cases, the imaging agent is enriched in 18 F. In some cases, an imaging agent may be used to image an area of interest in a subject, including, but not limited to, the heart, cardiovascular system, cardiac vessels, brain, and other organs. In some embodiments, methods and compositions for assessing perfusion and innervation mismatch in a portion of a subject are provided.
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主要参考文献


1: Park M, Kim SH, Bae S, Im MH. Monitoring of Pesticide Residues in Chili Peppers Using International Pesticide Monitoring Data for Safety Management. Toxics. 2024 Jul 15;12(7):508. doi: 10.3390/toxics12070508.
2: Jiang L, Wang H, Qiao K, Wu C. Increasing Cyetpyrafen Spray Volume and Ozone Spray Improves the Control Effects against Two-Spotted Spider Mite (Tetranychus urticae) in Strawberries. Plants (Basel). 2024 Jun 28;13(13):1792. doi: 10.3390/plants13131792.
3: Song L, Yu C, Li W, Liu L, Sun Q, Liu H, Wang S. Differential Antioxidant Enzyme Gene Expression and Functional Analysis of Pyridaben-Susceptible and -Resistant Strains of Tetranychus truncatus (Acari: Tetranychidae) under High Temperature Stress. Insects. 2024 May 23;15(6):381. doi: 10.3390/insects15060381.

合成参考文献


参考文献:10.1021/tx200098r
摘要:Boyd J, Saksena A, Patrone JB, Williams HN, Boggs N, Le H, Theodore M. Exploring the boundaries of additivity: mixtures of NADH: quinone oxidoreductase inhibitors. Chem Res Toxicol. 2011 Aug 15;24(8):1242–50. doi: 10.1021/tx200098r.
参考文献:10.1007/s10493-005-1423-3
摘要:Pree DJ, Whitty KJ, Van Driel L. Baseline Susceptibility and Cross Resistances of Some New Acaricides in the European Red Mite, Panonychus ulmi*. Experimental and Applied Acarology. 2005 Dec;37(3-4):165. doi: 10.1007/s10493-005-1423-3.
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