CAS: 886-65-7; 4-Phenylbuta-1,3-Dienyl]Benzene

该化合物是一种共生有机化合物,其特征是扩展的 --电子系统,使其在材料科学和光化学应用中具有价值,其硬性平板结构能增强荧光特性,使其作为焚化器或有机发光二极管(OLEDs)有用,该化合物还作为合成多环芳烃和其他先进有机材料的关键中间体,其高热稳定性和定义明确的电子转换使其适合光谱研究和调查聚合效应的模型复合体.此外,该化合物还表现出强大的紫外线吸收作用,这对光聚合和光物理研究具有优势.

结构式图片

相似化合物

538-81-8 27331-25-5 37985-13-0

物理性质

MSDS等安全信息

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

(E)-3-phenylpropenal benzyltriphenylphosphonium chloride (E)-buta-1,3-dienylbenzene benzene diazonium chloride 4,7-diphenyl-2-benzofuran-1,3-dione non-3-ene-7,9-dionecis-2,5-diphenyl-8-oxabicyclo4.3.0non-3-ene-7,9-dione phenyl[1, 1'; 4', 1'']terphenyl-2'-yl-methanone 4-nitro-3,5,6-triphenyl-cyclohexene

合成工艺路线路线简述

  • 79159-76-5 = 886-65-7
    反应条件:1.1 Reagents: Chloroacetone Catalysts: Triphenylphosphine,Bis(Benzonitrile)Dichloropalladium Solvents: Dimethyl Sulfoxide; 0.5 H,80 °C
    标题:Oxidative Coupling Of Organostannanes Under Palladium Catalysis,Part 1: Homo-Coupling Of Organostannanes
    作者:Kukukawa,Kiyoshi; Kariya,Masaki; Shin-Ya,Yoshihisa
    参考文献:Kinki Daigaku Sangyo Rikogakubu Kenkyu Hokoku 日期:2009 卷标:10 页码:1-5]

    886-66-8 = 886-65-7
    反应条件:1.1 Reagents: Dimethylformamide,Potassium Hydroxide Catalysts: Palladium Diacetate; 6 H,145 °C
    标题:Highly Chemo- And Stereoselective Palladium-Catalyzed Transfer Semihydrogenation Of Internal Alkynes Affording Cis-Alkenes
    作者:Li,Jie; Hua,Ruimao; Liu,Tao
    参考文献:Journal Of Organic Chemistry 日期:2010 卷标:75(9) 页码:2966-2970]

    4363-35-3 = 886-65-7
    反应条件:1.1 Reagents: Sodium Carbonate Catalysts: Tosyl Chloride,Palladium Chloride Solvents: Ethanol,Water
    标题:Ligandless Palladium Chloride-Catalyzed Homo-Coupling Of Arylboronic Acids In Aqueous Media
    作者:Kabalka,George W.; Wang,Lei
    参考文献:Tetrahedron Letters 日期:2002 卷标:43(16) 页码:3067-3068]

    588-73-8 + 588-72-7 = 886-65-7
    反应条件:1.1 Catalysts: Nickel,Bis(2,2′-Bipyridine-Kn1,Kn1′)-,(T-4)- Solvents: N-Methyl-2-Pyrrolidone
    标题:The Coupling Of Organic Groups By The Electrochemical Reduction Of Organic Halides: Catalysis By 2,2'-Bipyridinenickel Complexes
    作者:Rollin,Yolande; Troupel,Michel; Tuck,Dennis G.; Perichon,Jacques
    参考文献:Journal Of Organometallic Chemistry 日期:1986 卷标:303(1) 页码:131-7]

    103-64-0 = 886-65-7
    反应条件:1.1 Reagents: Chlorotrimethylsilane,4-Methoxybenzaldehyde Catalysts: 1,1,2,2-Ethenetetramine,N1,N1,N1′,N1′,N2,N2,N2′,N2′-Octamethyl-,Chromium Chloride (Crcl3),Nickel Bromide Solvents: Dimethylformamide
    标题:Tetrakis(Dimethylamino)Ethylene (Tdae) As A Potent Organic Electron Source: Alkenylation Of Aldehydes Using An Ni/cr/tdae Redox System
    作者:Kuroboshi,Manabu; Tanaka,Muneaki; Kishimoto,Suguru; Goto,Kentaro; Mochizuki,Misato; Et Al
    参考文献:Tetrahedron Letters 日期:2000 卷标:41(1) 页码:81-84]

    100-52-7 + 1530-35-4 = 886-65-7
    反应条件:1.1 Reagents: 2,8,9-Trimethyl-2,5,8,9-Tetraaza-1-Phosphabicyclo[3.3.3]Undecane Solvents: Tetrahydrofuran
    标题:P(Mench2Ch2)3N: An Efficient Nonionic Superbase For Wittig And Wittig-Horner Reactions
    作者:Wang,Zhigang; Verkade,John G.
    参考文献:Heteroatom Chemistry 日期:1998 卷标:9(7) 页码:687-689]

    104-55-2 + 134988-30-0 = 886-65-7
    反应条件:1.1 Catalysts: Potassium Tert-Butoxide
    标题:Synthetic Application Of Elemento-Organic Compounds Of The 15Th And 16Th Groups. 81. Reactions Of Carbonyl Compounds With Benzyldibutyltelluronium Bromide Mediated By Different Strong Bases
    作者:Li,Saowei; Zhou,Zhang-Lin; Huang,Yaozeng; Shi,Lilan
    参考文献:Journal Of The Chemical Society 日期:1991 卷标:(5) 页码:1099-100]

    = 886-65-7
    反应条件:1.1 Reagents: Piperidine Catalysts: 2,2′-Biimidazole,Magnetite (Fe3O4),Cuprous Iodide; 10 Min,Rt1.2 Solvents: Water; 1.5 H,Reflux
    标题:Nano Magnetite Supported Metal Ions As Robust,Efficient And Recyclable Catalysts For Green Synthesis Of Propargylamines And 1,4-Disubstituted 1,2,3-Triazoles In Water
    作者:Tajbakhsh,Mahmood; Farhang,Maryam; Baghbanian,Seyed Meysam; Hosseinzadeh,Rahman; Tajbakhsh,Mahghol
    参考文献:New Journal Of Chemistry 日期:2015 卷标:39(3) 页码:1827-1839]

    = 886-65-7
    反应条件:1.1 Reagents: Oxygen Catalysts: Copper Hydroxide Solvents: Acetone
    标题:Catalytic Properties Of Polymeric Copper-Amine-Cellulose Complexes
    作者:Muralidharan,S.; Freiser,H.
    参考文献:Journal Of Molecular Catalysis 日期:1989 卷标:50(2) 页码:181-93]

    = 886-65-7
    反应条件:1.1 Reagents: Oxygen Catalysts: 1542161-53-4 (Silica-Bound) Solvents: Dimethyl Sulfoxide; 4 H,100 °C
    标题:Cu(Ii) Complex Heterogenized On Sba-15: A Highly Efficient And Additive-Free Solid Catalyst For The Homocoupling Of Alkynes
    作者:Narani,Anand; Marella,Ravi Kumar; Ramudu,Pochamoni; Rama Rao,Kamaraju Seetha; Burri,David Raju
    参考文献:Rsc Advances 日期:2014 卷标:4(8) 页码:3774-3781]

    87960-48-3 = 886-65-7
    反应条件:1.1 Reagents: Selectfluor Solvents: Acetonitrile; 1 H,Rt
    标题:Gold-Catalysis: Reactions Of Organogold Compounds With Electrophiles
    作者:Hashmi,A. Stephen K.; Ramamurthi,Tanuja Dondeti; Todd,Matthew H.; Tsang,Althea S.-K.; Graf,Katharina
    参考文献:Australian Journal Of Chemistry 日期:2010 卷标:63(12) 页码:1619-1626]

    103-64-0 = 886-65-7
    反应条件:1.1 Reagents: Tetrabutylammonium Hydroxide,Dl-Glucose Catalysts: Gold Triacetate Solvents: Water; 15 H,90 °C
    标题:Ullmann Homocoupling Catalysed By Gold Nanoparticles In Water And Ionic Liquid
    作者:Monopoli,Antonio; Cotugno,Pietro; Palazzo,Gerardo; Ditaranto,Nicoletta; Mariano,Bruno; Et Al
    参考文献:Advanced Synthesis & Catalysis 日期:2012 卷标:354(14-15) 页码:2777-2788]

    4843-72-5 = 886-65-7
    反应条件:1.1 Reagents: (T-4)-Dichloroethoxyoxovanadium Solvents: Tetrahydrofuran; 1 H,-78 °C
    标题:Dichloro(Ethoxy)Oxovanadium(V)
    作者:Ohshiro,Yoshiki; Hirao,Toshikazu; Nikonov,George
    参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2011 卷标:1 页码:1-5]

    18736-43-1 = 886-65-7
    反应条件:1.1 Catalysts: Isoquinoline,Lithium Chloride,Palladium Chloride Solvents: N-Methyl-2-Pyrrolidone
    标题:Pd-Catalyzed Decarbonylative Olefination Of Aryl Esters: Towards A Waste-Free Heck Reaction
    作者:Goossen,Lukas J.; Paetzold,J.
    参考文献:Angewandte Chemie 日期:2002 卷标:41(7) 页码:1237-1241]

    588-73-8 = 886-65-7
    反应条件:1.1 Reagents: Tetrabutylammonium Bromide,Tripotassium Phosphate Catalysts: (Sp-4-3)-Chloro[1,3-Dihydro-1,3-Bis[2,4,6-Tris(1-Methylethyl)Phenyl]-2H-Imidazol... Solvents: Dimethylformamide; 5 H,140 °C; 140 °C -> Rt
    标题:Study On The Heck Reaction Promoted By Carbene Adduct Of Cyclopalladated Ferrocenylimine And The Related Reaction Mechanism
    作者:Ren,Gerui; Cui,Xiuling; Yang,Erbing; Yang,Fan; Wu,Yangjie
    参考文献:Tetrahedron 日期:2010 卷标:66(23) 页码:4022-4028]

    19477-77-1 = 886-65-7
    反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran; -78 °C -> -60 °C; 3 H,-60 °C1.2 Reagents: Hydrochloric Acid Solvents: Methanol; -60 °C -> Rt; 12 H,Rt
    标题:Te-Li Exchange Reaction Of Tellurophene-Containing π-Conjugated Polymer As Potential Synthetic Tool For Functional π-Conjugated Polymers
    作者:Zheng,Feng; Komatsuzaki,Yusuke; Shida,Naoki; Nishiyama,Hiroki; Inagi,Shinsuke; Et Al
    参考文献:Macromolecular Rapid Communications 日期:2019 卷标:40(20)]

    30094-01-0 = 886-65-7
    反应条件:1.1 Catalysts: Tetrakis(Triphenylphosphine)Palladium Solvents: Tetrahydrofuran
    标题:Palladium-Catalyzed Coupling Of N-Substituted Isocyanide Dichlorides With Alkynyltin Compounds: New Synthesis Of Dialkynylketones
    作者:Ito,Yoshihiko; Inouye,Masahiko; Murakami,Masahiro
    参考文献:Tetrahedron Letters 日期:1988 卷标:29(42) 页码:5379-82]

    64326-57-4 = 886-65-7
    反应条件:1.1 Reagents: Tert-Butyl Peroxide,Oxygen Catalysts: Palladium Diacetate Solvents: Acetonitrile; 12 H,60 °C
    标题:Copper-Free Palladium-Catalysed Desulfinative Homocoupling Of Sodium Arylsulfinates Under Mild And Aerobic Conditions
    作者:Zhang,Wei
    参考文献:Journal Of Chemical Research 日期:2017 卷标:41(1) 页码:1-3]

    4363-35-3 = 886-65-7
    反应条件:1.1 Reagents: Oxygen Catalysts: Palladium Diacetate Solvents: Dimethyl Sulfoxide; 24 H,50 °C1.2 Reagents: Sodium Chloride Solvents: Water
    标题:Tetrasubstituted Olefin Synthesis Via Pd-Catalyzed Addition Of Arylboronic Acids To Internal Alkynes Using O2 As An Oxidant
    作者:Zhou,Chengxiang; Larock,Richard C.
    参考文献:Journal Of Organic Chemistry 日期:2006 卷标:71(8) 页码:3184-3191
📜β-溴苯乙烯置于bis(1,5-Cyclooctadiene)Nickel (0),4-碘苯甲酸甲酯,4,4'-二叔丁基-2,2'-二吡啶,Magnesium Chloride,锌体系中,用 四氢呋喃 作为反应溶剂,化学反应 2.5H,以16%的收率获得产物1,4-二苯基1,3-丁二烯
参考文献:镍卤化物与乙烯基溴的镍催化还原偶联制备乙烯基芳烃
标题:镍卤化物与乙烯基溴的镍催化还原偶联制备乙烯基芳烃
摘要:这项工作强调了在温和且易于操作的镍催化反应条件下,通过芳基卤化物与乙烯基溴的还原偶联来合成取代的乙烯基芳烃.广泛使用的芳基卤化物,包括杂芳族化合物和乙烯基溴化物,以中等至优异的收率生产了具有高官能团耐受性的产品.镍催化系统在两个c(sp 2)-卤化物偶合体之间显示出非常好的化学选择性,从而证明了不同于其他逐步方案的机理途径.
DOI:10.1002/anie.201607959

海关参考信息

专利信息


专利号:US-2003162992-A1
优先权日:2001-12-14
标 题 :Preparation of intermediates useful in the synthesis of antiviral nucleosides
发明人：WATANABE KYOICHI A; DU JINFA
摘要:The present invention is an efficient process for the manufacture of α-acyloxyacetaldehyde, a key intermediate in the synthesis of 1,3-oxathiolane and 1,3-dioxolane nucleosides.

专利号:WO-9847910-A1
优先权日:1997-04-21
标题:Method for solution phase synthesis of oligonucleotides
发明人：PIEKEN WOLFGANG; MCGEE DANNY; SETTLE ALECIA; ZHAI YANSHENG; HUANG JIANPING; HILL KEN; SMITH RANDALL S
权利人:NEXSTAR PHARMACEUTICALS INC; PIEKEN WOLFGANG; MCGEE DANNY; SETTLE ALECIA; ZHAI YANSHENG; HUANG JIANPING; HILL KEN; SMITH RANDALL S
摘要:This invention discloses an improved method for the sequential solution phase synthesis of oligonucleotides. The method lends itself to automation and is ideally suited for large scale manufacture oligonucleotides with high efficiency.

专利号:US-6479599-B1
优先权日:1997-04-04
标题:Catalyst system for high yield synthesis of polyolefins
发明人：PEIL KEVIN P; WILSON DAVID R
权利人:BP CHEM INT LTD
摘要:This invention relates to a supported metallocene catalyst system for the high yield synthesis of polyolefins, to methods of preparation of the catalyst system, to polymerization processes which use the catalyst system and to polyolefin polymers produced by the polymerization processes.

专利号:US-6162882-A
优先权日:1996-07-10
标 题:Preparation of novel homo- and copolymers using atom transfer radical polymerization
发明人：MATYJASZEWSKI KRZYSZTOF; COCA SIMION; GAYNOR SCOTT G; NAKAGAWA YOSHIKI; JO SEONG MU
权利人:UNIV CARNEGIE MELLON
摘要:The present invention is directed to a process of atom (or group) transfer radical polymerization for the synthesis of novel homopolymer or a block or graft copolymer, optionally containing at least one polar group, with well defined molecular architecture and narrow polydipersity index, in the presence of an initiating system comprising (i) an initiator having a radically transferrable atom or group, (ii) a transition metal compound, and (iii) a ligand, the present invention is also directed to the synthesis of a macromolecule having at least two halogen groups which can be used as a macroinitiator component (i) to subsequently form a block or graft copolymer by an atom or group transfer radical polymerization process; the present invention is also directed to a process of atom or group transfer radical polymerization for the synthesis of a branched or hyperbranched polymer; in addition, the present invention is directed to a process of atom or group transfer radical polymerization for the synthesis of a macroinitiator which can subsequently be used to produce a block or graft copolymer.

专利号:US-5498734-A
优先权日:1991-09-23
标 题:Preparation and use of (2-butene-1,4-diyl)magnesium complexes in organic synthesis
发明人：RIEKE REUBEN D
权利人:UNIV NEBRASKA
摘要:The magnesium complexes of cyclic hydrocarbons containing conjugated dienes, such as 1,2-dimethylenecycloalkanes, and 1,3-butadienes, are readily prepared in high yields using highly reactive magnesium. Reactions of these (2-butene-1,4 diyl)magnesium reagents with electrophiles such as dibromoalkanes, alkylditosylates, alkylditriflates, bromoalkylnitriles, esters, or amides serve as a convenient method for synthesizing carbocyclic systems. Significantly, carbocycles prepared by this method contain functional groups such as the exocyclic double bond or a keto group in one of the rings which could be used for further elaboration of these molecules. Furthermore, fused bicyclic systems containing a substituted five-membered ring can be conveniently prepared at high temperatures by the reactions of (2-butene-1,4-diyl)magnesium complexes with carboxylic esters or acid halides whereas low temperatures lead to regioselective synthesis of β,γ-unsaturated ketones. Additionally, γ-lactones, including spiro γ-lactones, can be easily prepared in a one pot synthesis from the reaction of (2-butene-1,4-diyl)magnesium complexes with a ketone or aldehyde and carbon dioxide. Also, δ-lactones can be easily prepared in a one pot synthesis from the reaction of (2-butene-1,4-diyl)magnesium complexes with epoxides followed by reaction with CO 2 . Use of α-hydroxy epoxides without the addition of CO 2 leads to the synthesis of vicinal diols. Chiral epoxides lead to chiral alcohols.

专利号:US-5581004-A
优先权日:1991-09-23
标题 :Preparation and use of (2-butene-1,4-diyl) magnesium complexes in organic synthesis
发明人：RIEKE REUBEN D
权利人:UNIV NEBRASKA
摘要:The magnesium complexes of cyclic hydrocarbons and conjugated dienes, such as 1,2-dimethylenecycloalkanes and 1,3-butadienes, are readily prepared in high yields using highly reactive magnesium. Reactions of these (2-butene-1,4-diyl)magnesium reagents with electrophiles such as dibromoalkanes, alkylditosylates, alkylditriflates, bromoalkylnitriles, esters, or amides serve as a convenient method for synthesizing carbocyclic systems. Significantly, carbocycles prepared by this method contain functional groups such as the exocyclic double bond or a keto group in one of the rings which could be used for further elaboration of these molecules. Furthermore, fused bicyclic systems containing a substituted five-membered ring can be conveniently prepared at high temperatures by the reactions of (2-butene-1,4-diyl)magnesium complexes with carboxylic esters or acid halides whereas low temperatures lead to regioselective synthesis of β,γ-unsaturated ketones. Additionally, γ-lactones, including spiro γ-lactones, can be easily prepared in a one pot synthesis from the reaction of (2-butene-1,4-diyl)magnesium complexes with a ketone or aldehyde and carbon dioxide.

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合成参考文献


参考文献:10.1021/ja0381611
摘要:Chen EY, Campbell RE, Devore DD, Green DP, Link B, Soto J, Wilson DR, Abboud KA. Divalent ansa-zirconocenes: stereoselective synthesis and high activity for propylene polymerization. J Am Chem Soc. 2004 Jan 14;126(1):42–3. doi: 10.1021/ja0381611.
参考文献:10.1016/j.bmc.2010.01.032
摘要:Miyazaki H, Sai H, Ohmizu H, Murakami J, Ohtani A, Ogiku T. Synthesis and evaluation of 1,4-diphenylbutadiene derivatives as inhibitors of plasminogen activator inhibitor-1 (PAI-1) production. Bioorg Med Chem. 2010 Mar 01;18(5):1968–79. doi: 10.1016/j.bmc.2010.01.032.
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