专利号:US-8067633-B2 优先权日:2006-12-05 标 题:Method for the synthesis of (meth)acrylic esters catalysed by a polyol titanate 发明人:PAUL JEAN-MICHEL 权利人:PAUL JEAN-MICHEL; ARKEMA FRANCE 摘要:The subject of the invention is a method for the synthesis of (meth)acrylic esters by transesterification in the presence of a catalyst corresponding to the formula [(R′O) 3 Ti] x R″ in which R′ is a linear or branched alkyl radical having from 2 to 8 carbon atoms which may contain heteroatoms or R′ is a phenyl radical, R′ is a polyfunctional radical, originating from a polyol R′(OH) x comprising x alcohol functional groups and x is an integer ranging from 2 to 6. The method according to the invention is particularly well suited to the synthesis of dialkylaminoalkyl (meth)acrylates from methyl (meth)acrylate and a dialkylaminoalcohol.
专利号:US-2024368099-A1 优先权日:2022-01-18 标 题:Methods for the synthesis of di(hydroxymethyl)tetrahydrofuran and its application in polyesters and polyurethanes 发明人:SPIEGELBERG BRIAN; BRANDT ADRIAN; BECK HORST; KUX ALEXANDER; TIN SERGEY; DE VRIES JOHANNES GERARDUS 权利人:HENKEL AG & CO KGAA 摘要:The present invention relates to the synthesis of di(hydroxymethyl)tetrahydrofuran (DHMTHF) and the preparation of trans-enriched mixtures of DHMTHF. The invention further refers to polyester polyols which are obtained by reaction of cis/trans DHMTHF mixtures with a dicarboxylic acid. The invention further relates to polyurethanes and compositions containing a polyester polyol comprising DHMTHF, in particular to such polyurethane-containing (adhesive) compositions.
专利号:US-8105809-B2 优先权日:2008-07-03 标题 :Enzymatic synthesis of acetoacetate esters and derivatives 发明人:HENDERSON SAMUEL T 权利人:HENDERSON SAMUEL T; ACCERA INC 摘要:In one embodiment, the present invention includes a method for the synthesis of an ester derivative of acetoacetate. The method includes providing a first ester of acetoacetate and providing an alcohol. The method further includes combining the first ester of acetoacetate and the alcohol in the presence of an enzyme capable of transesterification in a non-aqueous solvent to form the ester derivative of acetoacetate. The method results in the formation of the ester derivative of acetoacetate, which, in one embodiment, is monoacetoacetin.
专利号:US-8053522-B2 优先权日:2006-02-28 标题 :Synthesis of polyester-graft-poly(meth)acrylate copolymers 发明人:LOEHDEN GERD; BALK SVEN; BRAND THORSTEN; BRENNER GABRIELE; ARNOLD THOMAS; BAUMANN CORNELIA 权利人:EVONIK ROEHM GMBH 摘要:The present invention relates to a novel synthesis of (meth)acrylate-grafted polyesters and their action as compatibilizers.
专利号:US-6201101-B1 优先权日:1998-11-19 标 题:Catalyst and its use for the synthesis of polyol polyethers 发明人:TOZZOLA GABRIELLA; PO' RICCARDO; CARDI NICOLETTA 权利人:ENICHEM SPA 摘要:The present invention relates to a catalyst having general formula (I):wherein: M represents at least one cation of an element selected from earth-alkaline metals belonging to groups IIA, IIIA, VA, or transition metals belonging to groups IIB, IIIB, VB or VIIIB; n represents an integer between 0 and 2 and x is an integer between 2 and 5.The invention also relates to a process for the synthesis of polyol polyethers which uses a catalyst having general formula (I).
专利号:US-9617372-B2 优先权日:2012-10-24 标 题 :Sulphur-comprising polyaromatic polyamine that can be used in the synthesis of polyurea 发明人:FEDURCO MILAN; RIBEZZO MARCO 权利人:MICHELIN & CIE; MICHELIN RECH TECH 摘要:A sulphur-comprising polyaromatic polyamine compound can be used as a monomer or prepolymer, when n is different from zero, in the synthesis of polyurea. The compound corresponds to the formula (I):n nH 2 N—Ar 1 —NH—CH 2 —CH(OH)—(CH 2 ) m —O—Z 1 —O—(CH 2 ) m —CH(OH)—CH 2 —[X] n —HN—Ar 2 —NH 2 n nin which X represents the string:n n—HN—Ar 3 —NH—(CH 2 )—CH(OH)—(CH 2 ) m —O—Z 2 —O—(CH 2 ) m —CH(OH)—(CH 2 )—n nand in which n represents an integer equal to zero or different from zero; m, which are identical or different, represent an integer within a range from 1 to 10; Z 1 and Z 2 , which are identical or different, represent a divalent bonding group comprising from 1 to 30 carbon atoms; and Ar 1 , Ar 2 and Ar 3 , which are identical or different, each represent a phenylene group, at least one of these phenylene groups bearing one, two, three or four groups of formula —S x —R in which “xâ€? is an integer from 1 to 8 and R represents hydrogen or a hydrocarbon group which can comprise a heteroatom and which comprises from 1 to 10 carbon atoms.
参考文献:10.1002/anie.200600359 摘要:Hungria AB, Raja R, Adams RD, Captain B, Thomas JM, Midgley PA, Golovko V, Johnson BF. Single-step conversion of dimethyl terephthalate into cyclohexanedimethanol with Ru5PtSn, a trimetallic nanoparticle catalyst. Angew Chem Int Ed Engl. 2006 Jul 17;45(29):4782–5. doi: 10.1002/anie.200600359.