CAS: 1055-23-8; 9,9'-Bianthracene

该化合物是一个以紫外线和可见区域中异常稳定和强吸收而闻名的同质有机化合物,其独特的分子结构允许建造高效光电装置,该化合物在环境条件下的降解程度极小,成为可持续能源应用的理想候选物.

结构式图片

上下游产品

CAS号84-65-1 蒽醌 | CAS号90-44-8 蒽酮 | CAS号1564-64-3 9-溴蒽 | CAS号871248-66-7 2-((Z)-but-1-en... | CAS号4393-30-0 9-(9-hydroxy-10... | CAS号434-84-4 二蒽酮基 | CAS号61832-79-9 9-anthracen-9-y... | CAS号100-75-4 N-亚硝基哌啶 | CAS号120-12-7 蒽 | CAS号86-74-8 咔唑 | CAS号231606-51-2 9-iodo-10-(10-i... | CAS号613-31-0 9,10-二氢蒽 | CAS号103266-00-8 10-anthracen-9-... | CAS号121848-75-7 10,10'-二溴-9,9'-联二蒽

合成工艺路线路线简述

    📜蒽酮置于溶剂黄146,锌体系中,用25%的收率获得9,9'-联蒽
    参考文献:蒽阴离子与氯化铍的反应
    标题:蒽阴离子与氯化铍的反应
    摘要:蒽自由基阴离子与becl 2在thf中的反应生成结晶的聚合有机金属化合物,在水解时可生成9,9',10,10'-四氢-9,9'-联蒽(thba).用d 2 O水解仅产生反式-10-D,反式-10'-D烃.蒽二价阴离子与becl 2在thf中的反应导致溶剂裂解并形成顺式-9,10-二氢-9,10-双(4-羟基丁基)蒽.还讨论了环辛酸酯二烯二阴离子的可比反应.结果指出了碳-铍键的共价性.
    Doi:10.1016/s0022-328X(00)93560-5

    专利信息


    专利号:US-2014076403-A1
    优先权日:2012-05-15
    标 题 :Dipyrin based materials for photovoltaics, compounds capable of undergoing symmetry breaking intramolecular charge transfer in a polarizing medium and organic photovoltaic devices comprising the same
    发明人:FORREST STEPHEN R; THOMPSON MARK E; CHEN JOHN J; SOMMER JONATHAN R; DJUROVICH PETER I; ALLEN KATHRYN R
    权利人:UNIV SOUTHERN CALIFORNIA; UNIV MICHIGAN
    摘要:The present disclosure generally relates to organic photosensitive optoelectronic devices comprising at least one boron dipyrrin compound. In addition, the present disclosure relates to methods of making organic photosensitive optoelectronic devices comprising at least one boron dipyrrin compound. The present disclosure also generally relates to chromophoric compounds that combine strong absorption of light at visible wavelengths with the ability to undergo symmetry-breaking intramolecular charge transfer (ICT), and their use for the generation of free carriers in organic photovoltaic cells (OPVs) and electric-field-stabilized geminate polaron pairs. The present disclosure also relates to the synthesis of such compounds, methods of manufacture, and applications in photovoltaic systems and organic lasers.

    专利号:WO-2010133128-A1
    优先权日:2009-05-22
    标 题 :Process for synthesis of 9,9'-dianthracene

    专利号:DE-112012006817-B3
    优先权日:2011-07-22
    标题 :Process for the synthesis of a dibenzo [c, g] carbazole compound.

    专利号:US-9508941-B2
    优先权日:2010-12-24
    标题:Light-emitting elements comprising iridium organometallic complexes comprising aryl-substituted pyrazines
    发明人:INOUE HIDEKO; NAKAGAWA TOMOKA; SEO SATOSHI
    权利人:SEMICONDUCTOR ENERGY LAB
    摘要:Provided is a novel organometallic complex which can be synthesized easily and emits phosphorescence, or a compound which emits red phosphorescence. The inventors focused on easy synthesis of an m-aminophenyl pyrazine derivative represented by the following general formula (G0), synthesized an organometallic complex having a structure in which the derivative is coordinated to a Group 9 or Group 10 metal ion, and further synthesized a useful substance which emits red phosphorescence.

    专利号:US-2012065445-A1
    优先权日:2009-05-22
    标 题:Process For Synthesis of 9,9'-Dianthracene

    专利号:WO-2010133129-A1
    优先权日:2009-05-22
    标题:Process for synthesis of 10,10'-dibromo-9,9'-dianthracene

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    参考标题:Synthesis And Optical Properties Of Novel Blue Fluorescent Conjugated Polymers
    作者:Martin Baumgarten,Timucin Yüksel
    摘要:In The Present Paper We Describe New Approaches Towards The Synthesis Of Conjugated Polymers With Defined Conjugation Length, Resulting In A Blue Or Green Fluorescence. The New Approach Reported Here Is To Use 1,3-Phenylene (Type 1) And 10,10′-Bianthrylene (Type 2) Bridges Of Conjugated Segments Such As Stilbenes And Thiophenes Which Can Easily Be Varied To Further Change The Optical Properties.

    合成参考文献


    参考文献:10.1039/c4pp00073k
    摘要:Thyrhaug E, Hammershøj P, Kjær KS, Sørensen TJ, Harrit NH, Nielsen MM, Bechgaard K. Excited state kinetics of anthracene-bridge-aniline intramolecular exciplexes. Photochemical & Photobiological Sciences. 2014 Jul 01;13(7):1093–105. doi: 10.1039/c4pp00073k.
    参考文献:10.1007/bf00261899
    摘要:Ballini J-, Daniels M, Vigny P. Synchrotron-excited time-resolved fluorescence spectroscopy of adenosine, protonated adenosine and 6N, 6N-dimethyladenosine in aqueous solution at room temperature. European Biophysics Journal. 1988 Sep;16(3):131–42. doi: 10.1007/bf00261899.
    摘要:Summary Tables of Biological Tests, National Research Council Chemical-Biological Coordination Center., 6(145), 1954
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