CAS: 787-84-8; N,N-Dibenzoylhydrazine

该化合物是一种有机化合物,其特性是附于苯并酸碱的氢氮功能组,该化合物一般是白色的脱白晶状固体,可溶于乙醇和丙酮等有机溶剂,但因其湿润结构,在水中溶解性有限;该水合会组的存在具有特定的再活性,使其能够参与各种化学反应,包括凝聚和细胞化;苯并酸衍生物,包括该化合物,经常因其在制药,农用化学品和有机合成的中间体的潜在用途而受到研究;此外,该化合物可能展示生物活动,使其对医药化学感兴趣;应参考安全数据处理和接触准则,如任何化学物质.

结构式图片

物理性质

MSDS等安全信息

上下游产品

pyridine benzoyl thiosemicarbazide benzoyl chloride N'-benzoyl-hydrazidethioformic acid N'-benzoyl-hydrazidetribenzoylhydrazine tetrabenzoyl-hydrazine benzoic acid anhydride 4-(p-anisyl)-3,5-diphenyl-4H-1,2,4-triazole

合成工艺路线路线简述

  • 98-88-4 = 787-84-8
    反应条件:1.1 Reagents: Bromine,Hydrazine Hydrate (1:1); 0 °C1.2 0 - 10 °C; 5 S,0 - 10 °C
    标题:Rapid Generation Of N,N'-Diacylhydrazines By I2 Or Br2/hydrazine Hydrate: A Facile Route To 1,3,4-Oxadiazoles
    作者:Pamar,Malavath Geeta; Gannimani,Ramesh; Govender,Patrick; Ramjugernath,Deresh; Nanjundaswamy,Hemmaragala Marishetty
    参考文献:Organic Chemistry: An Indian Journal 日期:2014 卷标:10(1) 页码:17-23]

    591-50-4 + 613-94-5 = 787-84-8
    反应条件:1.1 Reagents: Cesium Carbonate Catalysts: Palladium (Reaction Product With Tetraallylglycoluril-Vinyl Pyridine Copolymer),Imidazo[4,5-D]Imidazole-2,5(1H,3H)-Dione,Tetrahydro-1,3,4,6-Tetra-2-Propen-1-Yl... Solvents: Dimethyl Sulfoxide; 4 Mpa,120 °C
    标题:Stability Or Flexibility: Metal Nanoparticles Supported Over Cross-Linked Functional Polymers As Catalytic Active Sites For Hydrogenation And Carbonylation
    作者:Chen,Bingfeng; Li,Fengbo; Huang,Zhijun; Lu,Tao; Yuan,Guoqing
    参考文献:Applied Catalysis 日期:2014 卷标:481 页码:54-63]

    98-88-4 + 613-94-5 = 787-84-8
    反应条件:1.1 Reagents: Sodium Carbonate Solvents: Tetrahydrofuran,Water; 0 °C; 1.5 H,Rt
    标题:Copper-Catalyzed Cross-Coupling Between (E)-1,2-Diiodoethene And Carbazates: Entry To β-Functionalized N-Alkenylcarbazates
    作者:Casault,Pamela; Ricard,Simon; Daoust,Benoit
    参考文献:Letters In Organic Chemistry 日期:2022 卷标:19(9) 页码:803-810]

    55-21-0 + 613-94-5 = 787-84-8
    反应条件:1.1 Catalysts: Boric Acid (H4B2O5) (Sulfated) Solvents: Dimethyl Sulfoxide; 45 Min,70 °C; 70 °C -> Rt1.2 Reagents: Water; Rt
    标题:Phthaloylation Of Amines,Hydrazines,And Hydrazides By N-Substituted Phthalimides Using Recyclable Sulfated Polyborate
    作者:Ganwir,Prerna; Jaydeokar,Swati; Chaturbhuj,Ganesh U.
    参考文献:Results In Chemistry 日期:2022 卷标:4]

    65-85-0 = 787-84-8
    反应条件:1.1 Reagents: Triethylamine,(Chloromethylene)Dimethylammonium Chloride,Hydrazine Hydrate (1:1) Solvents: Acetonitrile; 7 H,Rt
    标题:Synthesis Of Acylhydrazines And,Symmetrical And Asymmetrical Diacylhydrazines From Carboxylic Acid Via The Vilsmeier Reagent Mediated Process
    作者:Zarei,Maaroof; Nakhli,Maliheh Eslami
    参考文献:Research On Chemical Intermediates 日期:2017 卷标:43(3) 页码:1909-1918]

    618-32-6 + 825-56-9 = 787-84-8
    反应条件:1.1 Reagents: Water
    标题:Diazomethanes. V. The Reactive Behavior Of Diazomethyllithium
    作者:Muller,Eugen; Ludsteck,Dieter
    参考文献:Chemische Berichte 日期:1955 卷标:88 页码:921-33]

    613-94-5 = 787-84-8
    反应条件:1.1 Reagents: Potassium Peroxymonosulfate Sulfate (2Khso5.Khso4.K2So4) Solvents: Water
    标题:A Simple And Efficient Oxidation Of Hydrazides To N,N'-Diacylhydrazines Using Oxone In An Aqueous Medium
    作者:Kulkarni,P. P.; Kadam,A. J.; Desai,Uday V.; Mane,R. B.; Wadgaonkar,P. P.
    参考文献:Journal Of Chemical Research 日期:2000 卷标:(4) 页码:184-185]

    98-88-4 + 613-94-5 = 787-84-8 [标题:Reaction Conditions
    标题:Acetylenic Ketones. Part Vi. Reaction Of Aroylphenylacetylenes With Hydrazine Derivatives
    作者:Baddar,F. G.; Al-Hajjar,F. H.; El-Rayyes,N. R.
    参考文献:Journal Of Heterocyclic Chemistry 日期:1978 卷标:15(3) 页码:385-93]

    15646-46-5 + 613-94-5 = 787-84-8
    反应条件:1.1 Solvents: 1,4-Dioxane1.2 Reagents: Water
    标题:Migration Of An Acyl Group In The Pyrazole System: Synthesis Of 1-Acyl-3-Hydroxy-1H-Pyrazoles And Related Derivatives. A New Preparation Of N,N '-Diacylhydrazines
    作者:Kepe,Vladimir; Pozgan,Franc; Golobic,Amalija; Polanc,Slovenko; Kocevar,Marijan
    参考文献:Journal Of The Chemical Society 日期:1998 卷标:(17) 页码:2813-2816]

    613-94-5 = 787-84-8
    反应条件:1.1 Reagents: Methanaminium,N,N,N-Trimethyl-,Periodate (1:1) (Polymer-Supported)
    标题:Ammonium Periodate,Polymer-Supported
    作者:Ley,Steven V.; Hazelwood,Andrew J.
    参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2002 卷标:1 页码:1-2]

    613-94-5 = 787-84-8 [标题:Reaction Conditions
    标题:Polymer Supported Periodate: Convenient Method For Oxidation Of Hydrazides
    作者:Salunkhe,D. G.; Jagdale,M. H.; Swami,S. S.; Salunkhe,M. M.
    参考文献:Current Science 日期:1986 卷标:55(18) 页码:922-3]

    98-88-4 = 787-84-8
    反应条件:1.1 Reagents: Hydrazine Hydrate (1:1) Solvents: Tetrahydrofuran; 4 H,0 °C
    标题:N-Amino-1,8-Naphthalimide Is A Regenerated Protecting Group For Selective Synthesis Of Mono-N-Substituted Hydrazines And Hydrazides
    作者:Manoj Kumar,Mesram; Venkataramana,Parikibanda; Yadagiri Swamy,Parikibanda; Chityala,Yadaiah
    参考文献:Chemistry - A European Journal 日期:2021 卷标:27(70) 页码:17713-17721]

    613-94-5 = 787-84-8
    反应条件:1.1 Reagents: Sodium Peroxoborate Solvents: Acetic Acid
    标题:Oxidation Of Hydrazides Using Sodium Perborate: Formation Of N,N'-Diacylhydrazines
    作者:Jadhav,Vidyadhar K.; Wadagaonkar,Prakash P.; Salunkhe,Manikrao M.
    参考文献:Journal Of The Chinese Chemical Society (Taipei) 日期:1998 卷标:45(6) 页码:831-833]

    98-88-4 + 613-94-5 = 787-84-8
    反应条件:1.1 Reagents: Pyridine Catalysts: 4-(Dimethylamino)Pyridine Solvents: Dichloromethane; Rt; 6 H,Rt
    标题:N-Methoxyamide: An Alternative Amidation Reagent In The Rhodium(Iii)-Catalyzed C-H Activation
    作者:Zhou,Chao; Zhao,Junqi; Guo,Weicong; Jiang,Jijun; Wang,Jun
    参考文献:Organic Letters 日期:2019 卷标:21(23) 页码:9315-9319]

    100-52-7 = 787-84-8
    反应条件:1.1 Reagents: Tert-Butyl Hydroperoxide,Hydrazine Hydrate (1:1) Catalysts: Pyridinium,1-(3-Sulfopropyl)-,Tetracosa-μ-Oxododecaoxo[μ12-[phosphato(3-)-Ko:K...; 8 H,90 °C
    标题:Direct Oxidative Amidation Of Aldehydes With Amines Catalyzed By Heteropolyanion-Based Ionic Liquids Under Solvent-Free Conditions Via A Dual-Catalysis Process
    作者:Fu,Renzhong; Yang,Yang; Zhang,Jin; Shao,Jintao; Xia,Xuming; Et Al
    参考文献:Organic & Biomolecular Chemistry 日期:2016 卷标:14(5) 页码:1784-1793]

    98-88-4 + 613-94-5 = 787-84-8
    反应条件:1.1 Solvents: Pyridine; 36 H,Reflux
    标题:Synthesis And In Vitro Urease Inhibitory Activity Of Benzohydrazide Derivatives,In Silico And Kinetic Studies
    作者:Abbas,Azhar; Ali,Basharat; Kanwal; Khan,Khalid Mohammed; Iqbal,Jamshed; Et Al
    参考文献:Bioorganic Chemistry 日期:2019 卷标:82 页码:163-177]

    98-88-4 + 613-94-5 = 787-84-8
    反应条件:1.1 Reagents: Pyridine,4-(Dimethylamino)Pyridine Solvents: Dichloromethane; 6 H,Rt
    标题:Molecular Logic Gates And Switches Based On 1,3,4-Oxadiazoles Triggered By Metal Ions
    作者:Li,Ai-Fang; Ruan,Yi-Bin; Jiang,Qian-Qian; He,Wen-Bin; Jiang,Yun-Bao
    参考文献:Chemistry - A European Journal 日期:2010 卷标:16(19) 页码:5794-5802]

    65-85-0 + 3426-89-9 = 787-84-8
    反应条件:1.1 Reagents: Hydrazine
    标题:A New Synthesis Of Hydrazides By A Direct Condensation Reaction
    作者:Chiriac,C. I.
    参考文献:Revue Roumaine De Chimie 日期:1982 卷标:27(3) 页码:411-14]

    613-94-5 = 787-84-8
    反应条件:1.1 Reagents: Benzoyl Chloride Solvents: Toluene; 2.5 H,Reflux
    标题:A Ceric Ammonium Nitrate N-Dearylation Of N-P-Anisylazoles Applied To Pyrazole,Triazole,Tetrazole,And Pentazole Rings: Release Of Parent Azoles. Generation Of Unstable Pentazole,Hn5/n5-,In Solution
    作者:Butler,Richard N.; Hanniffy,John M.; Stephens,John C.; Burke,Luke A.
    参考文献:Journal Of Organic Chemistry 日期:2008 卷标:73(4) 页码:1354-1364
📜Benzoylacetaldehyde Benzoylhydrazone 反应生成 二苯甲酰肼
参考文献:V. Auwers; Mauss,Journal Fur Praktische Chemie (Leipzig 1954),1927,Vol. <2> 117,P. 331
标题:V. Auwers; Mauss,Journal Fur Praktische Chemie (Leipzig 1954),1927,Vol. <2> 117,P. 331

海关参考信息

专利信息


专利号:US-5110986-A
优先权日:1988-04-26
标题:Synthesis of n-t-alkyl-1,2-diacylhydrazines
发明人：KELLY MARTHA J
权利人:ROHM & HAAS
摘要:A process for preparing a N-t-alkyl-1,2-diacylhydrazine comprises reacting a 1, 3, 4-oxadiazole with a tertiary alkyl cation precursor in the presence of a strong acid catalyst.

专利号:CN-1038277-A
优先权日:1988-04-26
标题:Synthesis of N-tert-alkyl-1,2-diacylhydrazines

专利号:IE-891227-L
优先权日:1988-04-26
标 题 :SYNTHESIS OF N-t-ALKYL-1,2-DIACYLHYDRAZINES

专利号:IE-63326-B1
优先权日:1988-04-26
标 题:Synthesis of n-t-alkyl-1,2-diacylhydrazines

专利号:CN-102285935-A
优先权日:2011-08-02
标 题:Synthesis of 2,2'-(1,3-phenylene)bis{5-[4-(1,1-dimethylethyl)phenyl]}-1,3,4-oxadiazole

专利号:DE-68906715-T2
优先权日:1988-04-26
标题:Synthesis of N-t-alkyl-1,2-diacylhydrazines.

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主要参考文献

参考标题:Studies On Acyl Alkyl Diimides
作者:Thomas R. Lynch,Frederick N. Maclachlan,Yum Kuen Siu |发布日期:1971.5.15
摘要:A Number Of Acyclic Acyl Alkyl Diimides Have Been Obtained By Oxidation Of The Corresponding Alkyl Hydrazides. A New Method For The Synthesis Of α-Cyanoalkyl Hydrazides, The Reaction Of Acid Hydrazides With Ketones In The Presence Of Sodium Cyanide, Has Been Explored. All The Acyl Alkyl Diimides So Obtained Exhibit A Medium To Weak I.R. Band At Ca. 1550 Cm−1; Evidence Supporting The Assignment Of This Band To The -N=n- Stretch Is Given. The Results Of Oxidation Of 5-Methyl And 5-Phenyl-Pyrazolidin-3-One Are Reported, Together With The Synthesis And Oxidation Of Tetrahydro-6-Methyl-3(2H)-Pyridazinone.

合成参考文献


摘要:Mourad, A. K.; Czekelius, C., Science of Synthesis Knowledge Updates, (2011) 3, 88.
摘要:U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals., NX#01359
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