CAS: 77758-51-1; Methyl 5-Hexynoate

该化合物是一种有机化合物,其特点是具有以终端烷基功能组为主的静脉结构,该化合物是5-甲基酸和甲醇的酯,形成甲基酯形态,一般看起来是无色的,色色色的黄色液体,有独特的气味; 碳基化合物组的存在具有独特的再活动性,使其在各种有机合成应用中有用,特别是在碳碳基联结的形成方面.其分子结构包括一个六碳链,第五和第六碳原子之间有三联,有助于其不饱和性. 5-甲基丙酸,甲基酯在有机溶剂中溶解,并表现出中度极性.必须小心地处理这一化合物,因为如果吸入或摄取,可能会对健康造成危害.

结构式图片

相似化合物

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上下游产品

CAS号67-56-1 甲醇 | CAS号53293-00-8 5-己炔酸 | CAS号186581-53-3 重氮甲烷 | CAS号74-88-4 碘甲烷 | CAS号14918-21-9 己炔腈 | CAS号928-90-5 5-己炔-1-醇 | CAS号14267-92-6 5-氯-1-戊炔 | CAS号764-60-3 2-己炔-1-醇 | CAS号18420-41-2 2-(氯甲基)四氢吡喃 | CAS号100-72-1 四氢吡喃-2-甲醇 | CAS号108212-58-4 10,10-difluoroa... | CAS号506-32-1 花生四烯酸 | CAS号928-90-5 5-己炔-1-醇 | CAS号18829-89-5 methyl tetradec... | CAS号28093-53-0 1H-Indole-2-but... | CAS号79551-86-3 20-羟基二十碳-5Z,8Z,... | CAS号53293-00-8 5-己炔酸 | CAS号1191-85-1 花生四烯酸 | CAS号10417-94-4 顺式-5,8,11,14,17... | CAS号155193-71-8 N-benzylhex-5-y...

合成工艺路线路线简述

    📜四氢吡喃-2-甲醇置于chromium(Vi) Oxide,氯化亚砜,硫酸,Sodium,Potassium Carbonate体系中,用 吡啶,氨 作为反应溶剂,化学反应生成 5-己炔酸甲酯
    参考文献:9(S)-和9(R)-Hete的立体选择性全合成
    标题:9(S)-和9(R)-Hete的立体选择性全合成
    摘要:一种简单有效的立体选择性全合成,使用碱诱导的手性2的开口,合成甲基9(S)-和9(R)-羟基-5(z),7(e),11(z),14(z)-二十碳四烯酸酯描述了,3-环氧氯.
    DOI:10.1016/s0040-4020(98)00119-7

    海关参考信息

    专利信息


    专利号:US-2006223947-A1
    优先权日:2005-04-05
    标题 :Chemical synthesis of polymeric nanomaterials and carbon nanomaterials
    发明人:OLESIK SUSAN V; DING LUNHAN
    权利人:UNIV OHIO STATE RES FOUND
    摘要:A high yield method for chemically synthesizing low polydispersivity carbon microspheres, nanospheres, nanocrystals, nanotubes, or nanofibers comprising dispersing a self-polymerizing end-capped polyyne in a solvent; heating the dispersed self-polymerizing end-capped tetrayne to form a polymeric material selected from the group consisting of polymer microspheres, polymer nanospheres, polymer nanocrystals, polymer nanotubes, and polymer nanofibers; and pyrolyzing the polymeric material to form a carbon material selected from the group consisting of carbon microspheres, carbon nanospheres, carbon nanocrystals carbon nanotubes, and carbon nanofibers, wherein the polydispersivity is less than 2.

    专利号:WO-2025045973-A1
    优先权日:2023-08-31
    标题 :Synthesis of lanifibranor intermediate
    发明人:BOUBIA BENAÃ?SSA; GONZALEZ JÉRÔME; BELL FRÉDÉRIC
    权利人:INVENTIVA
    摘要:The present disclosure is directed to a process for preparing a compound of formula (I), which comprises a palladium-free coupling reaction between N-(4-chloro-2-iodo-phenyl)-1,3-benzothiazole-6-sulfonamide and methyl 5-hexynoate in the presence of a copper catalyst.

    专利号:US-2022340514-A1
    优先权日:2019-09-10
    标题 :Cannabinoid derivatives and precursors, and asymmetric synthesis for same
    发明人:ABDUR-RASHID KAMALUDDIN; JIA WENLI; ABDUR-RASHID KAREEM
    权利人:KARE CHEMICAL TECH INC
    摘要:The present disclosure relates to new cannabinoid derivatives and precursors and catalytic asymmetric processes for their preparation. The disclosure also relates to pharmaceutical compositions and pharmaceutical and analytical uses of the new cannabinoid derivatives. For instance, the disclosure relates to the preparation of new precursors, and the use of such precursor compounds for the preparation of isotope labelled cannabinoid products using chiral and achiral catalysts and catalytic processes. The deuterium, carbon-13 and carbon-14 containing compounds can be prepared and purified prior to transformation to the desired individual deuterated cannabinoid products.

    专利号:US-11001783-B2
    优先权日:2016-08-16
    标题:Synthesis and use of ω-hydroxylated polyunsaturated fatty acids
    发明人:ZHANG GUODONG; HAMMOCK BRUCE; HWANG SUNG HEE; WANG WEICANG
    权利人:UNIV CALIFORNIA; UNIV MASSACHUSETTS
    摘要:The present invention provides a synthetic chemical method for preparing ω-hydroxylated polyunsaturated fatty acids (PUFAs) including 20-hydroxyeicosatetraenoic acid (20-HETE), 20-hydroxyeicosapentaenoic acid (20-HEPE), and 22-hydroxydocosahexaenoic acid (22-HDoHE) and a method of use thereof for treating cancer and macular degeneration.

    专利号:US-2019270950-A1
    优先权日:2016-08-16
    标 题:Synthesis and use of omega-hydroxylated polyunsaturated fatty acids

    专利号:US-2014315720-A1
    优先权日:2012-10-24
    标 题 :Polysaccharide ester microspheres and methods and articles relating thereto
    发明人:FALLON DENIS G; GARRETT THOMAS S; KIZER LAWTON E; ZAZZARA KAREN L; COMBS MICHAEL T; JOHNSON RICHARD K; DEHART GARY
    权利人:CELANESE ACETATE LLC
    摘要:A method for producing a polysaccharide ester microsphere may include forming a polysaccharide ester product from a polysaccharide synthesis, wherein the polysaccharide ester product comprises a polysaccharide ester and a solvent; diluting the polysaccharide ester product, thereby yielding a polysaccharide ester dope; and forming a plurality of polysaccharide ester microspheres from the polysaccharide ester dope. Suitable polysaccharides may include, but are not limited to, starch, cellulose, hemicellulose, algenates, chitosan, and any combination thereof. Esters thereof may be organic esters (e.g., acetate and the like), inorganic esters (e.g., sulfonates and the like), or combinations thereof. Further, the solids conent of the polysaccharide ester dope, in some instances, may be greater than about 16 wt %.

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Anderson, E. A.; Lim, D. S. W., Science of Synthesis Knowledge Updates, (2015) 1, 89.
    摘要:Delvos, L. B.; Oestreich, M., Science of Synthesis Knowledge Updates, (2017) 1, 86.
    摘要:Lubell, W. D.; St-Cyr, D. J.; Dufour-Gallant, J.; Hopewell, R.; Boutard, N.; Kassem, T.; Dörr, A.; Zelli, R., Science of Synthesis Knowledge Updates, (2013) 1, 213.
    摘要:Silva, V. L. M.; Pinto, D. C. G. A.; Santos, C. M. M.; Rocha, D. H. A., Science of Synthesis Knowledge Updates, (2022) 3, 184.
    摘要:Huy, P.; Czekelius, C., Science of Synthesis Knowledge Updates, (2019) 2, 200.
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