2,5-二甲基吡啶 以 水 用作溶剂,以59%的收率获得2,5-二吡啶羧酸 参考文献:Anodic Oxidation Of Methyl-Substituted Nitrogen-Containing Heterocyclic Compounds At The 标题:Anodic Oxidation Of Methyl-Substituted Nitrogen-Containing Heterocyclic Compounds At The 摘要: Doi:10.1007/bf01171298
专利号:WO-2009018504-A1 优先权日:2007-08-01 标题 :Process for the synthesis of diaminopyridine and related compounds 发明人:RITTER JOACHIM C 权利人:DU PONT; RITTER JOACHIM C 摘要:A process is provided for the synthesis of a diaminopyridine, such as 2,6-diaminopyridine and related compounds, which are used industrially as compounds and as components in the synthesis of a variety of useful materials. The synthesis proceeds by means of a chlorine-ammonia displacement in the presence of a copper source.
专利号:US-8084569-B2 优先权日:2006-12-21 标 题 :Process for the synthesis of diaminopyridines from glutarimidines 发明人:MINTER AARON; STOKES BERLIN 权利人:MINTER AARON; STOKES BERLIN; DU PONT 摘要:A liquid-phase process is provided for the synthesis from glutarimidines of diaminopyridines and related compounds, which are used industrially as compounds and as components in the synthesis of a variety of useful materials. The synthesis proceeds by means of a dehydrogenative aromatization process.
专利号:US-8022167-B2 优先权日:2006-12-21 标 题 :Process for the synthesis of diaminopyridines from glutaronitriles 发明人:MINTER AARON; STOKES BERLIN 权利人:MINTER AARON; STOKES BERLIN 摘要:A liquid-phase process is provided for the manufacture from glutaronitriles and related compounds of 2,6-diaminopyridine and related compounds, which are used industrially as compounds and as components in the synthesis of a variety of useful materials. The synthesis proceeds by means of a dehydrogenative aromatization process.
专利号:US-7999057-B2 优先权日:2008-07-08 标 题:Gas-phase process for the synthesis of diaminopyridines from glutaronitriles 发明人:HUTCHENSON KEITH W; MINTER AARON; SUNSHINE GREGG 权利人:DU PONT 摘要:A gas-phase, continuous process is provided for the manufacture of 2,6-diaminopyridine and related compounds from glutaronitriles, which are used industrially as compounds and as components in the synthesis of a variety of useful materials. The synthesis proceeds by means of a dehydrogenative aromatization process.
专利号:US-2011301314-A1 优先权日:2008-12-18 标题:Continuous liquid-phase process for the synthesis of diaminopyridines from glutaronitriles 发明人:HUTCHENSON KEITH W; MINTER AARON 权利人:HUTCHENSON KEITH W; MINTER AARON; DU PONT 摘要:A liquid-phase, continuous process is provided for the manufacture of 2,6-diaminopyridine and related compounds from glutaronitriles, which are used industrially as compounds and as components in the synthesis of a variety of useful materials. The synthesis proceeds by means of a dehydrogenative aromatization process.
专利号:WO-2024208876-A1 优先权日:2023-04-03 标题 :Ductile polyamide with the in situ synthesis of a polyimide phase by reactive extrusion 发明人:CASSAGNAU PHILIPPE; DELAGE KARIM; BOUNOR-LEGARE VÉRONIQUE; MARESTIN CATHERINE; DUBOIS CHARLOTTE; GAROIS NICOLAS 权利人:TOTALENERGIES ONETECH; UNIV CLAUDE BERNARD LYON 1 UCBL; CENTRE NAT RECH SCIENT; UNIV JEAN MONNET SAINT ETIENNE UJM; INSTITUT NAT DES SCIENCES APPLIQUEES DE LYON INSA LYON 摘要:The disclosure relates to a ductile polyamide and to a process to produce a ductile polyamide comprising providing components comprising one or more polyamides, one or more dianhydrides, and one or more diamines; wherein the one or more polyamides are provided at a content of at least 60 wt.% based on the total weight of the components; and wherein the one or more polyamides comprise at least one polyamide having amide groups separated by less than 10 carbon atoms; performing in situ synthesis of a polyimide by reactive extrusion of the components wherein the residence time is less than 10 minutes; and recovering a polyamide-polyimide blend being a ductile polyamide comprising a continuous polyamide phase and a dispersed polyimide phase.
参考标题:Structure Prediction And Synthesis Of Pyridine-Based Macrocyclic Peptide Natural Products 作者:Graham A. Hudson,Annie R. Hooper,Adam J. Dicaprio,David Sarlah,Douglas A. Mitchell |发布日期:2021.1.15 摘要:Characterization Of Natural Products Is Vastly Outpaced By The Bioinformatic Identification Of Biosynthetic Gene Clusters (Bgcs) That Encode Such Molecules. Uniting Our Knowledge Of Bioinformatics And Enzymology To Predict And Synthetically Access Natural Products Is An Effective Platform For Investigating Cryptic/silent Bgcs. We Report The Identification, Biosynthesis, And Total Synthesis Of A Minimalistic
合成参考文献
参考文献:10.1107/s1600536811007446 摘要:Shen FM, Lush SF. Poly[[dodeca-aqua-hexa-kis-(μ(2)-pyridine-2,5-dicarboxyl-ato)tricopper(II)diytterbium(III)] dihydrate]. Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 01;67(Pt 4):m406–7. 参考文献:10.1107/s1600536811012360 摘要:Zhang W, Chen Y, Lei T, Li Y, Li W. catena-Poly[diimidazolium [bis-(μ-pyridine-2,5-dicarboxyl-ato)bis-[diaqua-praseodymate(III)]]-bis-(μ-pyridine-2,5-dicarboxyl-ato)]. Acta Crystallogr Sect E Struct Rep Online. 2011 May 01;67(Pt 5):m569–70. 参考文献:10.1107/s1600536811014048 摘要:Lush SF, Shen FM. Poly[[octa-aqua-tetra-kis-(μ(3)-pyridine-2,5-dicarboxyl-ato)copper(II)diytterbium(III)] monohydrate]. Acta Crystallogr Sect E Struct Rep Online. 2011 May 01;67(Pt 5):m615–6.