CAS: 7205-91-6; (Chloromethyl)(Phenyl)Sulfane

上下游产品

CAS号100-68-5 茴香硫醚 | CAS号74-97-5 溴氯甲烷 | CAS号108-98-5 硫酚 | CAS号50-00-0 甲醛 | CAS号17873-08-4 三甲基(苯硫甲基)硅烷 | CAS号1193-82-4 苯亚砜甲酯 | CAS号56814-31-4 (phenylseleno)m... | CAS号701-65-5 trichloromethyl... | CAS号7205-94-9 氯甲基苯亚砜 | CAS号56-23-5 四氯化碳 | CAS号110361-69-8 2-diazonio-1-et... | CAS号10575-06-1 but-3-ynylsulfa... | CAS号3561-67-9 二苯硫基甲烷 | CAS号831-91-4 苄基苯基硫醚 | CAS号104803-86-3 n-butoxymethyl ... | CAS号60839-94-3 Fluoromethylphe... | CAS号527-60-6 2,4,6-三甲酚 | CAS号5384-21-4 4,4'-亚甲基双(2,6-二甲基)苯酚

茴香硫醚置于n-氯代丁二酰亚胺体系中,用 四氯化碳 作为反应溶剂,化学反应生成 氯甲基苯硫醚
参考文献:硫醛的 Diels-Alder 反应中的非对映选择性
标题:硫醛的 Diels-Alder 反应中的非对映选择性
摘要:La 反应 De Diels-Alder De Thioaldehydes Avec Le Cyclopentadiene Produitpreferentiellement L'Isomere End.la Selectivite La Plus Elevee Est Obtenue Avec Les 硫醛 Rchs Ou Rest Un Groupe 烷基化 Tel Que T-丁基 Ou 异丙基
DOI:10.1021/ja00224A033

专利信息

专利号:US-4707554-A
优先权日:1984-12-07
标 题 :Method of obtaining derivatives of 4β-/1'-alken-1'-yl/-2ξ,5α-dαβ-4,5,6,6α.beta.
发明人：ACHMATOWICZ BARBARA; DANIEWSKI ANDRZEJ R; MARCZAK STANISLAW; PANKOWSKI JACEK; WICHA JERZY
权利人:POLSKA AKADEMIA NAUK INSTYTUT
摘要:A new method has been disclosed for obtaining derivatives of 4β-/1'-alken-1'-yl/-2ξ,5â•?-dihydroxy-3,3aβ,4,5,6,6aβ-hexahydro-2H-cyclopenta [b] furane useful in the synthesis of prostaglandins or their analogs, and a method for obtaining new sulphonyl initial compounds of the general formula 4, in which Z denotes a hydrogen atom or a protective group, Y denotes a group of the formula â•?CHOZ 1 , in which Z 1 has the meaning stated for Z, whereby protective groups Z and Z 1 may be the same or different, and Ar denotes optionally a substituted aryl group. n In the method according to the invention the new sulphonyl derivative of the general formula 4 is alkylated with an electrophilic agent comprising: carbonyl derivatives, oxiranes and halohydrins or their derivatives; the alkylation product is transformed into derivatives of 4β-/1'-alken-1'-yl/-2ξ,5α-dihydroxy-3,3aβ,4,5,6,6a.beta.-hexahydro-2H-cyclopenta[b] furane in reactions which ensure obtaining a double bond C 13 -C 14 . n New sulphonyl initial compounds of the general formula 4 are obtained from lactone of the general formula 11, in which Z has the above stated meaning and L° denotes a leaving group, which is transformed into a sulphide; the obtained lactone-sulphide is reduced to lactol, and thereafter lactol-sulphide is oxidized to te sulphonyl derivative.

专利号:US-5922889-A
优先权日:1996-06-21
标题 :Synthesis of isochromans and their derivatives
发明人：CUTLER HORACE G; MAJETICH GEORGE; TIAN XINRONG; SPEARING PAUL
权利人:US AGRICULTURE; UNIV GEORGIA
摘要:Isochromans and their derivatives have been chemically synthesized. These compounds possess significant phytotoxic activity which may be used as a biodegradable contact herbicide. The synthetic method allows for economic production of these herbicides.

专利号:US-4269773-A
优先权日:1976-04-27
标 题:Fused oxazolidine compounds
发明人：MITSURU YOSHIOKA; TERUJI TSUJI; YASUHIRO NISHITANI; WATARU NAGATA
权利人:SHIONOGI & CO
摘要:Compounds represented by the following formula prepared from 6-aminopenicillanic acid are key intermediates in a stereo-specific synthesis of 1-oxadethiacephalosporins, highly active antibiotics: +TR [wherein COA and COB each is carboxy or protected carboxy; COX is carboxy, protected carboxy, or a group of the formula -COCQ=N2 or -COCHQ-Z (in which Q is hydrogen, lower alkyl or aryl; and Z is hydrogen or a nucleophilic group); Hal is halogen; R is lower alkyl or aralkyl; and Y is hydrogen or acyl].

专利号:JP-H0778100-B2
优先权日:1990-06-27
标题 :Novel sulfur-containing acrylic compounds, a process for their preparation and their use in the synthesis of new polymers

专利号:WO-8801619-A1
优先权日:1986-08-29
标题 :1'-methyl-beta-lactam compounds and their production
发明人：TERASHIMA SHIRO; KIMURA YOSHIKAZU; ITO YOSHIO; KAWABATA TAKEO; SAKAI KUNIKAZU; HIYAMA TAMEJIRO; SUNAGAWA MAKOTO; SASAKI AKIRA
权利人:SUMITOMO PHARMA; SAGAMI CHEM RES
摘要:A 1'-methyl-beta-lactam compound of formula (I), wherein R1 is an optionally substituted diarylmethyl group or an optionally substituted aryl group and R2 is a protective group for hydroxyl, which is useful as an intermediate in the synthesis of antimicrobial agents.

专利号:US-11192908-B2
优先权日:2018-08-17
标题:Octamolybdate compounds exhibiting bright emission
发明人：DANIELS STEVEN; PICKETT NIGEL; SAVJANI NICKY; GAVRILIUC VIRGIL
权利人:NANOCO 2D MAT LIMITED; UNIV MANCHESTER
摘要:Methods for the synthesis of a polyoxometalate compounds include heating a metal precursor in the presence of an organic salt. The polyoxometalate compounds produced herein display high photoluminescence quantum yields and photoluminescence maximums in the blue and/or violet regions of the electromagnetic spectrum.