CAS: 589-55-9; 4-Heptanol

上下游产品

2-propenylfuran diethyl ether 4-heptanone isopropylmagnesium bromide 4-heptanone 4-bromoheptane 4-heptylamine hept-3-ene Alcohols ( diethyl ether sodium acetylide benzaldehyde Dimethoxymethane R)-1-phenyl-prop-2-ynyl ester)carbamic acid-((R)-1-phenyl-prop-2-ynyl ester) meso-1,4-diphenyl-but-2-yne-1,4-diolmeso-1,4-diphenyl-but-2-yne-1,4-diol S:S)-1.4-diphenyl-butyne-(2)-diol-(1.4)(S:S)-1.4-diphenyl-butyne-(2)-diol-(1.4) (R)-1-phenyl-2,3-butanedien-1-ol

Trans-4-Ethoxy-3-Hepten置于三甲基氯硅烷,Benzyltriethylammonium Borohydride,氧气体系中,用 二氯甲烷 作为反应溶剂,化学反应 3.0H,以65%的收率获得产物4-庚醇
参考文献:烯醇醚与苄基三乙基氢硼化铵和三甲基氯硅烷的新颖而不同寻常的反应
标题:烯醇醚与苄基三乙基氢硼化铵和三甲基氯硅烷的新颖而不同寻常的反应
摘要:已发现苄基三乙基硼氢化铵-氯三甲基硅烷试剂体系在非常温和的反应条件下,与环状和环状烯醇醚1进行新颖而不同寻常的反应,分别分别高收率地分别反应生成二醇和醇2.
DOI:10.1016/s0040-4039(00)60976-0

专利信息

专利号:US-3676506-A
优先权日:1969-12-29
标题:Synthesis of novel compounds useful for production of juvabione
发明人：CRAWFORD ROBERT J
权利人:PROCTER & GAMBLE
摘要:Disclosed herein are processes for the production of 6-methyl-2(4-methylcyclohex-3-en-1-yl)hept-1-en-4-ol and 2-methyl-6-(4methylcyclohex-3-en-1-yl)heptan-4-ol using metalated limonene as the starting reactant. The novel compounds of the invention are useful in the synthesis of juvabione, a product having juvenile hormone activity.

专利号:US-2014245658-A1
优先权日:2013-02-08
标 题 :Synthesis of ethanol and higher alcohols by hydrogenation of ketene
发明人：HENRI JOHN T; ZYGMUNT JAN; BERGGREN MARK; ZUBRIN ROBERT
权利人:PIONEER ENERGY INC
摘要:Ketene chemistry and hydrogenation reactions are used to synthesize fuels and chemicals. Ketene from acetic acid is hydrogenated to form fuels and chemicals; acetic acid can be synthesized from synthesis gas which is produced from coal, biomass, natural gas, etc. In one embodiment, the present application discloses methods to selectively synthesize higher alcohols and hydrocarbons useful as fuels and industrial chemicals from syngas and biomass.

专利号:US-9296665-B2
优先权日:2012-12-13
标题:Synthesis of drop-in liquid fuels and chemicals from methanol, ethanol or syngas using mixed catalysts
发明人：KORTAN ADAM M; KELLY MICHAEL T; ROSE HEATHER A; ZUBRIN ROBERT M
权利人:Pioneer Energy; PIONEER ENERGY INC
摘要:The present invention discloses a system for converting methanol or synthesis gas to liquid hydrocarbons with comparable energy content to gasoline within a mixed bed single reactor or double reactor systems. Varying catalyst composition and temperature profiles allow for significant tailoring of reaction conditions to the specific feedstocks or the desired products.

专利号:US-9080119-B2
优先权日:2011-11-10
标 题:Synthesis of high caloric fuels and chemicals including pentanol from coal, natural gas, and biomass
发明人：HENRI JOHN; ZYGMUNT JAN; BERGGREN MARK; ZUBRIN ROBERT
权利人:PIONEER ENERGY INC; Pioneer Energy
摘要:In one embodiment, the present application discloses methods to selectively synthesize higher alcohols and hydrocarbons useful as fuels and industrial chemicals from syngas and biomass. Ketene and ketonization chemistry along with hydrogenation reactions are used to synthesize fuels and chemicals. In another embodiment, ketene used to form fuels and chemicals may be manufactured from acetic acid which in turn can be synthesized from synthesis gas which is produced from coal, biomass, natural gas, etc.

专利号:US-9611186-B2
优先权日:2011-11-10
标 题 :Synthesis of high caloric fuels and chemicals via ketene and diketene intermediates
发明人：HENRI JOHN; ZYGMUNT JAN; BERGGREN MARK; ZUBRIN ROBERT
权利人:PIONEER ENERGY INC; Pioneer Energy
摘要:In one embodiment, the present application discloses methods to selectively synthesize higher alcohols and hydrocarbons useful as fuels and industrial chemicals from syngas and biomass. Ketene and ketonization chemistry along with hydrogenation reactions are used to synthesize fuels and chemicals. In another embodiment, ketene used to form fuels and chemicals may be manufactured from acetic acid which in turn can be synthesized from synthesis gas which is produced from coal, biomass, natural gas, etc.

专利号:US-4243787-A
优先权日:1977-11-23
标 题 :Bulk anionic polymerization process using an alkali metal amide and the salt of the same alkali metal with a hydroxylic compound
发明人：BOILEAU SYLVIE L; CAUBERE PAUL J; NDEBEKA GILBERTE; LECOLIER SERGE L; RAYNAL SERGE F
权利人:POUDRES & EXPLOSIFS STE NALE
摘要:The invention relates to a process for the anionic polymerization and copolymerization of vinyl, dienic and heterocyclic monomers. According to the invention, the process consists in carrying out the reaction in the presence of an initiator consisting of a molecular combination of an alkali metal amide and the salt of the same alkali metal with at least one hydroxylic compound and in the absence of solvent. The initiator can be prepared by intimately mixing its constituents or in the presence of a solvent of low polarity which is subsequently evaporated off, or in situ in the monomer. Application to the synthesis of special or widely used polymers and copolymers.