CAS: 571-61-9; 1,5-Dimethylnaphthalene

该化合物是一种多环芳烃,其分子式为C12H12;它是氯化萘的衍生物,其1和5位置上有两个甲基组,该化合物通常用作有机合成和特殊化学品生产中的中间体,其僵硬的芳烃结构和甲基替代品有助于其在各种化学工艺中的稳定性和反应性. 1,5-二甲基甲二烯还被用于研究应用,特别是在涉及多氟乙烷及其衍生物的研究中.该化合物在水中表现出低溶性,但在有机溶剂中可溶性,因此适合用于非水系统,建议进行适当的处理和储存,因为其具有潜在的易燃性.

结构式图片

相似化合物

571-58-4 575-41-7 581-42-0

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

methyl magnesium iodide 5-methyl-1-tetralone 1,5-bis(chloromethyl)naphthalene 4,8-dimethyl-1,2-dihydro-naphthalene 1,5-bis(chloromethyl)naphthalene -naphthalin1,5-Bis--naphthalin trans-1,5-Bis-(4-phenyl-styryl)-naphthalin trans-1,5-Bis-(3,4-dimethoxy-styryl)-naphthalin

合成工艺路线路线简述

    📜2,6-二叔丁基萘置于盐酸,三氯化铝,锌体系中,用 溶剂黄146,苯 作为反应溶剂,化学反应 10.33H,反应生成 1,5-二甲基萘
    参考文献:Pozdnyakovich,Yu. V.,Journal Of Organic Chemistry Ussr (English Translation),1981,P. 1386-1387
    标题:Pozdnyakovich,Yu. V.,Journal Of Organic Chemistry Ussr (English Translation),1981,P. 1386-1387

    海关参考信息

    专利信息


    专利号:US-6924385-B2
    优先权日:2002-11-18
    标 题:Method for synthesis of aliphatic isocyanates from aromatic isocyanates
    发明人:LETTMANN CHRISTIAN; KOHLSTRUK STEPHAN; STOCHNIOL GUIDO; SPYROU EMMANOUIL
    权利人:DEGUSSA
    摘要:The invention relates to a method for synthesis of aliphatic isocyanates from aromatic isocyanates in substantially 3 stages. In particular, the invention relates to a method for synthesis of bis{4-isocyanatocyclohexyl}methane (H 12 MDI) from bis{4-isocyanatophenyl}methane (MDI). More especially, the invention relates to a method for synthesis of H 12 MDI with a trans-trans isomer content of <30%, preferably of <20%, particularly preferably of 5 to 15%.

    专利号:US-2003162992-A1
    优先权日:2001-12-14
    标 题 :Preparation of intermediates useful in the synthesis of antiviral nucleosides
    发明人:WATANABE KYOICHI A; DU JINFA
    摘要:The present invention is an efficient process for the manufacture of α-acyloxyacetaldehyde, a key intermediate in the synthesis of 1,3-oxathiolane and 1,3-dioxolane nucleosides.

    专利号:US-6472534-B2
    优先权日:1999-10-21
    标 题:Methods for the preparation of intermediates in the synthesis of HIV-protease inhibitors
    发明人:BORER BENNETT C; ZOOK SCOTT E; BUSSE JULIETTE K
    权利人:AGOURON PHARMA
    摘要:Methods for the preparation of chemical intermediates in the synthesis of HIV-protease inhibitors related to and including nelfinavir mesylate are disclosed. The method of this invention comprises converting tetrohydran derivatives into oxazolines to provide key reaction intermediates for the preparation of nelfinavir. Also disclosed is a method for the preparation of a chiral amino alcohol from an epoxy-tetrahydrofuran.

    专利号:US-6495710-B2
    优先权日:2000-01-14
    标题:Synthesis and use of dimethyl 1,5-naphthalenedicarboxlyates and intermediates therefrom
    发明人:MACEK JOHN A; ROSEN BRUCE I; HOLZHAUER JUERGEN K; BRAMLET JOHN S; LILLWITZ LARRY D; SCHNEIDER DAVID J; LANG LAWRENCE L; PASCHKE EDWARD E; WEIS JOHN M; VISWANATH YENAMANDRA; SAKELLARIDES STEFANOS L
    权利人:BP CORP NORTH AMERICA INC
    摘要:The synthesis of dimethyl-1,5-naphthalenedicarboxylate and polymers and articles formed therefrom is disclosed, as well as applications for dimethyl-1,5-naphthalenedicarboxylate, its corresponding acid 1,5-NDA, and various synthesis intermediates.

    专利号:US-6512086-B2
    优先权日:2000-07-25
    标 题 :Process for preparation of organosilicon compositions
    发明人:GRECO ALBERTO; AUSILIO ANTONIO; POZZI ENRICO
    权利人:MAPEI SPA
    摘要:Process for the preparation of fluid organosilicon compounds usable in adhesive, coating and sealant formulations is described. The process includes the synthesis of organosilicon prepolymer compositions starting from unsaturated polyurethanes obtained in turn from unsaturated monoalcohol polyethers and diisocyanates with a controlled NCO/OH ratio, to which chlorosilanes are added in the presence of methyl or ethyl orthoformates. These organosilicon compositions are able to cross-link through silicon-alkoxy end groups of the type:

    专利号:US-8759469-B2
    优先权日:2007-07-25
    标题 :Synthesis of urethanes and polyurethanes catalysed by carbenes
    发明人:MIGNANI GERARD; DESTARAC MATHIAS; TATON DANIEL; GNANOU YVES; BACEIREDO ANTOINE; KATO TSUYOSHI; BONNETTE FABIEN; SIVASANKARAPILLAI GOPAKUMAR
    权利人:MIGNANI GERARD; DESTARAC MATHIAS; TATON DANIEL; GNANOU YVES; BACEIREDO ANTOINE; KATO TSUYOSHI; BONNETTE FABIEN; SIVASANKARAPILLAI GOPAKUMAR; Vencorex Frence; CENTRE NAT RECH SCIENT
    摘要:The present invention relates to a process for preparing a compound comprising at least a urethane group —HN—C(â•?O)—O, said process comprising a step (E) in which a compound (I) comprising at least an isocyanate functional group —Nâ•?Câ•?O is reacted with an organic compound (II) carrying at least a hydroxyl group —OH, said reaction being carried out in a presence of a carbene (III) used as a catalyst.

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Toyota, S.; Iwanaga, T., Science of Synthesis, (2010) 45, 774.
    摘要:Barsegyan, Y. A.; Vil’, V. A.; Tomkinson, N. C. O.; Terent’ev, A. O., Science of Synthesis Knowledge Updates, (2022) 1, 239.
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