CAS: 3937-28-8; Allyldichlorosilane

该化合物是有机硅化合物,其结构结构中含有硅和氯原子,其结构中含有一个附于硅原子的乙烯组(2-丙-丙-1-基),该物质进一步粘结在两个氯原子之上,该化合物一般是淡黄色液体的无色,以其反应性为名,特别是由于存在可参与各种化学反应,包括聚合和交叉链接的乙烯组,该化合物的存在.

结构式图片

上下游产品

allyl bromide 3-chloroprop-1-ene °Ctyltrichlorosilane Dichlorosilane allyltrimethoxysilane (prop-2-enyl)diphenylsilane allyltrichlorosilane allyltrimethoxysilane

合成工艺路线路线简述

    📜3-溴丙烯置于三氯硅烷,Magnesium体系中,用 乙醚 用作溶剂,化学反应 2.0H,以39%的收率获得烯丙基二氯硅烷
    参考文献:Schmidbaur,Hubert; Doerzbach,Cornelia,Zeitschrift Fur Naturforschung,B: Chemical Sciences,1987,Vol. 42,# 9,P. 1088-1096
    标题:Schmidbaur,Hubert; Doerzbach,Cornelia,Zeitschrift Fur Naturforschung,B: Chemical Sciences,1987,Vol. 42,# 9,P. 1088-1096

    海关参考信息

    专利信息


    专利号:US-8779179-B2
    优先权日:2010-05-28
    标 题:Synthesis of silyl acetylenes
    发明人:CLOUGH ROBERT S; ANTHONY JOHN E; PAYNE MARCIA M
    权利人:CLOUGH ROBERT S; ANTHONY JOHN E; PAYNE MARCIA M; 3M INNOVATIVE PROPERTIES CO
    摘要:The present disclosure provides a method of preparing silylethynyl compounds in which two of the hydrocarbyl groups bonded to the silicon exclusive of the ethynyl group, are the same and one is different, that may be used in preparing novel silylethynyl functionalized acene semiconductor chromophores.

    专利号:US-11767388-B1
    优先权日:2019-09-18
    标 题 :Silicon-functionalized rubber
    发明人:ENSIGN SETH CODY; VIELHABER MARGARET FLOOK; JOHNGRASS JENA LYNN; MA LIQING
    权利人:GOODYEAR TIRE & RUBBER
    摘要:The compatibility between silica fillers and synthetic rubbers which are synthesized utilizing lanthanide-based catalyst systems, such as neodymium catalyst systems can be improved by terminating the polymerization with a vinyl silane terminating agent. In doing so the vinyl silane is allowed to react with the polymer chain ends of the neodymium rubber to functionalize the chain ends of the polymer chains with silicon containing groups. This results in the rubber having better characteristics for utilization in tire rubber formulations, such a tire tread formulations, that exhibit improved wear characteristics and lower rolling resistance. The process for the synthesis of such functionalized polydiene rubber comprises (1) polymerizing a diene monomer in the presence of a lanthanide-based catalyst system, and (2) terminating the polymerization with a vinyl silane terminator. The functionalized polydiene rubber composition made by this method is comprised of a polydiene rubber which is functionalized at its chain ends with a silicon containing group.

    专利号:EP-3039027-A1
    优先权日:2013-08-30
    标题 :Slurry phase direct synthesis of organohalosilanes from cyclone fines

    专利号:EP-3039027-B1
    优先权日:2013-08-30
    标题:Slurry phase direct synthesis of organohalosilanes from cyclone fines

    专利号:US-2013150606-A1
    优先权日:2010-05-28
    标题:Synthesis of silyl acetylenes

    专利号:JP-2016530277-A
    优先权日:2013-08-30
    标题:Direct slurry phase synthesis of organohalosilanes from cyclone fine particles

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.1007/978-3-642-68661-0_11
    摘要:Weber WP. Allylic Silanes. 1983. In: Reactivity and Structure Concepts in Organic Chemistry.
    参考文献:10.2478/s11532-012-0079-1
    摘要:Khan E, Wrackmeyer B. Synthesis, NMR characterization and reactivity of 1-silacyclohex-2-ene derivatives. 2012 Jul 21;10(5):1633–9. doi: 10.2478/s11532-012-0079-1.
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