专利号:US-5399649-A 优先权日:1993-05-28 标 题 :Method for the preparation of diorganopolysiloxanes 发明人:OKAWA TADASHI 权利人:DOW CORNING TORAY SILICONE 摘要:A method for the high-purity synthesis of a diorganopolysiloxane having a functional group at only one molecular chain terminal, that is characterized by the preliminary silylation with a silylating agent of the silanol group-containing impurity present in the cyclic trisiloxane, and that is characterized by preliminarily converting the silanol group-containing impurity in the cyclic trisiloxane into a lithiated material by lithiation with an organolithium compound and then silylating this lithiated material using a silylating agent that contains silicon-bonded halogen.
专利号:US-11767388-B1 优先权日:2019-09-18 标 题 :Silicon-functionalized rubber 发明人:ENSIGN SETH CODY; VIELHABER MARGARET FLOOK; JOHNGRASS JENA LYNN; MA LIQING 权利人:GOODYEAR TIRE & RUBBER 摘要:The compatibility between silica fillers and synthetic rubbers which are synthesized utilizing lanthanide-based catalyst systems, such as neodymium catalyst systems can be improved by terminating the polymerization with a vinyl silane terminating agent. In doing so the vinyl silane is allowed to react with the polymer chain ends of the neodymium rubber to functionalize the chain ends of the polymer chains with silicon containing groups. This results in the rubber having better characteristics for utilization in tire rubber formulations, such a tire tread formulations, that exhibit improved wear characteristics and lower rolling resistance. The process for the synthesis of such functionalized polydiene rubber comprises (1) polymerizing a diene monomer in the presence of a lanthanide-based catalyst system, and (2) terminating the polymerization with a vinyl silane terminator. The functionalized polydiene rubber composition made by this method is comprised of a polydiene rubber which is functionalized at its chain ends with a silicon containing group.
专利号:WO-2024141492-A1 优先权日:2022-12-31 标题:Polymersomes comprising cleavable block copolymers 发明人:NORINKEVICIUS KAROLIS; DAUGAARD ANDERS EGEDE; REGUEIRA TORSTEN HØYBYE BAK; MADSEN PETER JEPPE 权利人:AQUAPORIN AS; UNIV DANMARKS TEKNISKE 摘要:A method for producing self-assembled polymersomes in a aqueous solution, wherein said polymersomes comprise amphiphilic diblock copolymers of the P1-b-P2 type, said method comprising the step of synthesizing R-C-O-P1-b-P2 block copolymers comprising a silyl ether (-C-O-Si-) bond and wherein P1 is a hydrophobic polymer and P2 is a hydrophilic polymer and R is any atom or group of atoms, wherein said synthesis comprises ring-opening polymerization of a cyclic monomer by an initiator in the presence of a catalyst, the initiator comprising a carbon-bound hydroxyl.
专利号:CN-109438633-A 优先权日:2018-09-11 标题:A kind of organosilicon toughening agent with anti-drip effect and synthesis method thereof
专利号:CN-109293856-A 优先权日:2018-09-11 标题 :A kind of organosilicon toughening agent of polymer-coated nano inorganic matter and synthesis method thereof
专利号:CN-109337025-A 优先权日:2018-09-11 标题 :A kind of anti-drip agent with toughening effect and synthesis method thereof