CAS: 2270-20-4; 5-Phenylvaleric Acid

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5-苯基戊烷-2,4-双酸置于甲酸,[pd(C,N-Npnhc)(η3-Allyl)](Bf4),三乙胺体系中,用 异丙醇 用作溶剂,化学反应 16.0H,反应生成5-苯基戊酸
参考文献:萘啶官能化的n-杂环卡宾配合物催化的α,β-不饱和羰基化合物的氢转移还原
标题:萘啶官能化的n-杂环卡宾配合物催化的α,β-不饱和羰基化合物的氢转移还原
摘要:银络合物的2-氯-7-(mesitylimidazolylidenylmethyl)萘啶(npnhc)与钯(II),提供[钯(铑(i)和铱(i)的金属前体的取代ç,ñ-Npnhc)(η 3-烯丙基)](bf 4)(5),Rhcl(cod)(c-Npnhc)(6A)和ircl(cod)(c-Npnhc)(6B).用agbf 4从6A和6B提取氯提供了螯合配合物[rh(cod)(c,N-Npnhc)](bf 4)(7A)和ir(cod)(c,N‐ Npnhc)(bf 4)(7B).使用NMR和元素分析对所有复合物进行表征,并使用x射线晶体学进一步证实5A和6A的结构细节.在催化活性研究中,发现配合物5是将α,β-不饱和羰基化合物氢转移还原为相应的饱和羰基化合物的有效催化剂.
Doi:10.1002/aoc.3673

专利信息

专利号:US-4400550-A
优先权日:1982-02-12
标题 :Synthesis of the navel orange worm pheromone (Z,Z)-11,13-hexadecadienal
发明人：BISHOP CLYDE E; MORROW GARY W
权利人:ALBANY INT CORP
摘要:A process for the synthesis of (Z,Z)-11-13-hexadecadienal is disclosed, starting with undecylenic alcohol.

专利号:US-5728827-A
优先权日:1993-07-09
标题 :Process for the synthesis of azetidinones
发明人：THIRUVENGADAM TIRUVETTIPURAM K; MCALLISTER TIMOTHY; TANN CHOU-HONG
权利人:SCHERING CORP
摘要:This invention provides a process for preparing azetidinones useful as intermediates in the synthesis of penems and as hypocholesterolemic agents, particularly for azetidinones substituted in the C-3 and C-4 positions and optionally substituted at the ring nitrogen, comprising reacting a β-(substituted-amino)amide, a β-(substituted-amino)acid ester, or a β-(substituted-amino)thiolcarbonic acid ester with a silylating agent and a cyclizing agent.

专利号:US-2006052577-A1
优先权日:2001-02-06
标题:Methods of synthesis of polymers and copolymers from natural products
发明人：SWIFT GRAHAM; WESTMORELAND DAVID G; HUGHES KATHLEEN
权利人:SWIFT GRAHAM; WESTMORELAND DAVID G; HUGHES KATHLEEN
摘要:Described are polymers and copolymers containing sorbitol, citric acid, starch, aspartic acid, succinic anhydride, adipic acid mixtures thereof, methods of their synthesis and their uses.

专利号:US-5589586-A
优先权日:1990-11-26
标 题 :Nucleosides attached to a solid support through a 3'-silyl linkage and their use in oligonucleotide synthesis
发明人：HOLMBERG LARS
权利人:PHARMACIA LKB BIOTECH
摘要:Support system for the synthesis of oligonucleotides wherein the first nucleoside is bound to the support via a silylether linkage, especially of the formula ##STR1## wherein B is a nucleoside or deoxynucleoside base. n R 1 is a protecting group. n R 2 is --H, --OH, or --OR 5 , in which R 5 is a protecting group. n R 3 , R 4 and X each represent alkyl, aryl, cycloalkyl, alkenyl, aralkyl, cycloalkylalkyl, alkyloxy, aryloxy, cycloalkyloxy, alkenyloxy, aralkyloxy. n S is a solid support, whereby not more than one of R 3 , R 4 and X represent alkyloxy, aryloxy, cycloalkyloxy, alkenyloxy, aralkyloxy or cycloalkylalkyloxy.

专利号:US-2021002677-A1
优先权日:2015-04-16
标 题:Synthesis of omega functionalized products
发明人：GONZALEZ RAMON; CHEONG SEOKJUNG; CLOMBURG JAMES M
权利人:GONZALEZ RAMON
摘要:The use of microorganisms to make omega- and/or omega-1-functionalized products through an iterative carbon chain elongation pathway that we call a reverse beta oxidation pathway. The pathway uses omega-functionalized CoA thioesters as primers and acetyl-CoA as the extender unit in a non-decarboxylative Claisen condensation, and then uses beta oxidation or fatty acid synthesis enzymes to complete the cycle, via reductase, dehydratase and reductase reactions. Various termination enzymes that act on the functionalized beta-keto acyl-CoA intermediates of the pathway and produce omega or omega-1 functionalized products. The action of termination enzymes on such intermediates yield a large variety of products.

专利号:US-2018135059-A1
优先权日:2015-04-16
标题 :Synthesis of omega functionalized products
发明人：GONZALEZ RAMON; CHEONG SEOKJUNG; CLOMBURG JAMES M
权利人:UNIV RICE WILLIAM M
摘要:The use of microorganisms to make omega- and/or omega-l-functionalized products through an iterative carbon chain elongation pathway that we call a reverse beta oxidation pathway. The pathway uses omega-functionalized CoA thioesters as primers and acetyl-CoA as the extender unit in a non-decarboxylative Claisen condensation, and then uses beta oxidation or fatty acid synthesis enzymes to complete the cycle, via reductase, dehydratase and reductase reactions. Various termination enzymes that act on the functionalized beta-keto acyl-CoA intermediates of the pathway and produce omega or omega-1 functionalized products. The action of termination enzymes on such intermediates yield a large variety of products.