CAS: 19984-57-7; 1-(Adamantan-1-yl)Pyridin-1-Ium Bromide

该化合物是一种四硝基铵盐,其独特结构是将一个固态基团与一个酸合二为一,这种化合物一般是白色的,是白色的,是非白色固体的,由于溴反离子性质,可溶于水和酒精等极地溶剂;亚坦基组的存在有助于其疏水特性,而环则加强其在极地环境中的溶解性;这种化合物经常用于有机合成,并作为一种分阶段转移催化剂,因为它能够促进离子在不同阶段的转移;此外,它可能表现出抗微生物特性,使其在各种生物应用中具有兴趣;在标准条件下,它的稳定可以方便处理和储存,尽管应注意避免接触水分,从而导致水解.

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131042-78-9 104-73-4 2534-66-9

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pyridine 1-Adamantyl bromide

合成工艺路线路线简述

    📜吡啶,1-溴金刚烷 反应 6.0H,以97%的收率获得1-(1-金刚烷基)溴化吡啶
    参考文献:Quaternization Of Pyridine With 1-Bromoadamantane
    标题:Quaternization Of Pyridine With 1-Bromoadamantane
    摘要:
    Doi:10.1007/bf00956562

    海关参考信息

    专利信息


    专利号:US-6524551-B2
    优先权日:2001-01-26
    标 题:Synthesis of MCM-58
    发明人：DHINGRA SANDEEP S
    权利人:EXXONMOBIL OIL CORP
    摘要:This invention provides a process for the synthesis of MCM-58 using 1-(1-adamantyl)pyridinium cations as a directing agent. The resultant MCM-58 is useful in a variety of hydrocarbon conversion reactions including toluene disproportionation, transalkylation of aromatics, reaction of paraffins with aromatics, paraffin isomerization and alkylation of aromatics with olefins.

    专利号:US-2002164284-A1
    优先权日:2001-01-26
    标 题 :Synthesis of MCM-58

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    主要参考文献

    参考标题:Synthesis Of Mcm-58
    摘要:This Invention Provides A Process For The Synthesis Of Mcm-58 Using 1-(1-Adamantyl) Pyridinium Cations As A Directing Agent. The Resultant Mcm-58 Is Useful In A Variety Of Hydrocarbon Conversion Reactions Including Toluene Disproportionation, Transalkylation Of Aromatics, Reaction Of Paraffins With Aromatics, Paraffin Isomerization And Alkylation Of Aromatics With Olefins.

    合成参考文献


    参考文献:10.1007/s10593-014-1628-7
    摘要:Shadrikova VA, Golovin EV, Klimochkin YN. Adamantylation of Pyridine Derivatives. Chemistry of Heterocyclic Compounds. 2015 Jan 06;50(11):1586–94. doi: 10.1007/s10593-014-1628-7.
    参考文献:10.1007/s10593-015-1792-4
    摘要:Shadrikova VA, Golovin EV, Shiryaev VA, Baimuratov MR, Rybakov VB, Klimochkin YN. Synthesis of adamantyl-containing phenylpiperidines. Chemistry of Heterocyclic Compounds. 2015 Oct;51(10):891–8. doi: 10.1007/s10593-015-1792-4.
    参考文献:10.1134/s1070363212110205
    摘要:Chernov’yants MS, Burykin IV, Starikova ZA, Rostovskaya AA. Crystal and molecular structure of diphenyliodonium diiodobromide. Russian Journal of General Chemistry. 2012 Nov;82(11):1842–5. doi: 10.1134/s1070363212110205.
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