CAS: 1207-12-1; 4,6-Dimethyldibenzothiophene

该化合物是一种有机化合物,其结构特征包括一个含有4和6个位置上两个甲基组的二苯并硫苯框架,该化合物属于多环芳芳香硫乙烷循环类别,因其稳定性和疏水性而闻名;该化合物一般在室内温度下是固体,由于其结构复杂,其熔点相对较高;硫磺在其结构中的存在有助于其独特的化学特性,包括各种化学反应中的潜在反应. 4,6-二甲基二苯并硫苯并苯对有机化学和材料科学等领域,尤其是与多环芳香烃及其环境影响有关的研究中都感兴趣.此外,该化合物在燃料化学方面可能具有相关性,因为此类化合物在化石燃料中可以找到,并可能影响石油产品的特性.应当参考安全数据,以便处理和接触准则,如任何化学物质一样,用于处理和接触.

结构式图片

相似化合物

23985-81-1 22099-23-6 7372-88-5

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C&L通报REACH预注册

上下游产品

3,3'-dimethyl-[1,1'-biphenyl]-2,2'-diol 4-methyldibenzothiophene dimethyl sulfate 2-thi°Cresol 4-methyldibenzothiophene biphenyl 3,3'-dimethyl-biphenyl 3-methylbiphenyl

合成工艺路线路线简述

    2,2'-二甲氧基-3,3'-二甲基联苯置于三溴化硼,Sodium Hydride体系中,用 二氯甲烷,N,N-二甲基甲酰胺 用作溶剂,化学反应 5.37H,反应生成4,6-二甲基二苯并噻吩
    参考文献:Synthesis Of Structurally Modified Atropisomeric Biaryl Dithiols. Observations On The Newman-Kwart Rearrangement
    标题:Synthesis Of Structurally Modified Atropisomeric Biaryl Dithiols. Observations On The Newman-Kwart Rearrangement
    摘要:The Preparation Of A Number Of Biaryldithiols From Biaryldiols Is Discussed. A Key Reaction Is The Newman-Kwart Thermorearrangement Of Bisthiocarbamates And Crucial Variables Of Temperature And Reaction Time Have Been Identified. Alternative Approaches To 3,3'-Disubstituted Dithiols Via Ortho Metallation Are Presented,The Benefit Of Using Such Disubstituted Compounds Is Illustrated With Representative Examples Of The Stereochemical Features Of The Derived Carbanions In Reactions With Prochiral Electrophiles. (C) 1997 Published By Elsevier Science Ltd.
    Doi:10.1016/s0040-4020(97)00268-8

    海关参考信息

    专利信息


    专利号:EP-2616475-A1
    优先权日:2010-09-14
    标题:Organometallic molybdenum acetylide dioxo complex and process for the preparation thereof
    发明人:UMBARKAR SHUBHANGI BHALCHANDRA; DONGARE MOHAN KERABA; BIRADAR ANKUSH; ACHAM VAIBHAV RAVINDRAKUMAR
    权利人:COUNCIL SCIENT IND RES
    摘要:The invention discloses organometallic molybdenum acetylide dioxo complex of formula (η 5 -C 5 H 5 )MoO 2 (-Cs≡CPh) and provides a simple, short, efficient process for the synthesis of organometallic molybdenum dioxo complex which is used as catalyst for a number of oxidation reactions.

    专利号:US-2013197245-A1
    优先权日:2010-09-14
    标 题:Organometallic Molybdenum Acetylide Dioxo Complex And Process For The Preparation Thereof
    发明人:UMBARKAR SHUBHANGI BHALCHANDRA; DONGARE MOHAN KERABA; BIRADAR ANKUSH; ACHAM VAIBHAV RAVINDRAKUMAR
    权利人:UMBARKAR SHUBHANGI BHALCHANDRA; DONGARE MOHAN KERABA; BIRADAR ANKUSH; ACHAM VAIBHAV RAVINDRAKUMAR
    摘要:An organometallic molybdenum acetylide dioxo complex of formula (η 5 -C 5 H 5 )MoO 2 (—Cs≡CPh) and provides a simple, short, efficient process for the synthesis of organometallic molybdenum dioxo complex which is used as catalyst for a number of oxidation reactions.

    专利号:CN-106391097-A
    优先权日:2016-09-23
    标题 :Synthesis of porous ZSM-5 zeolite and gamma-Al2O3 composite material and preparation of hydrodesulfurization catalyst

    专利号:CN-106391097-B
    优先权日:2016-09-23
    标题 :Porous ZSM-5 zeolite and γ-Al2O3The synthesis of composite material and prepare Hydrobon catalyst

    专利号:US-8084508-B2
    优先权日:2008-01-09
    标 题 :Ethanol as a feedstock for a BCTL facility
    发明人:YAKOBSON DENNIS; WRIGHT HAROLD A; PENNING RICHARD
    权利人:YAKOBSON DENNIS; WRIGHT HAROLD A; PENNING RICHARD; RENTECH INC
    摘要:A method of producing fuel by converting an alcohol stream comprising at least one alcohol into synthesis gas; providing a first synthesis gas stream, wherein at least a portion of the first synthesis gas stream comprises synthesis gas obtained from the alcohol conversion; converting a feed comprising synthesis gas via Fischer-Tropsch into a Fischer-Tropsch product comprising hydrocarbons, wherein at least a portion of the feed comprises synthesis gas from the first synthesis gas stream; and converting at least a portion of the Fischer-Tropsch product into fuel. A diesel fuel comprising hydrocarbons formed by Fischer-Tropsch conversion of synthesis gas derived from an alcohol stream comprising at least one alcohol.

    专利号:US-10406509-B2
    优先权日:2015-04-23
    标 题 :Nanoscale nickel phosphide catalysts for hydrotreatment
    发明人:BUSSELL MARK E
    权利人:WESTERN WASHINGTON UNIV
    摘要:This present disclosure is directed to methods for the preparation of a hydrotreatment catalyst, such as nanoscale nickel phosphide (i.e., Ni 2 P) particles supported on high-surface area metal oxides (e.g., silica, alumina, amorphous silica-alumina), in a manner that is compatible with conditions employed in commercial hydrotreating units. The catalyst synthesis includes impregnation, drying, and in situ reduction, and can provide highly active catalysts for the removal of S and N impurities from crude oil fractions.
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    合成参考文献


    参考文献:10.1134/s1061934817100021
    摘要:Afanas’ev IP, Gorshkova TA, Arystanbekova SA, Lapina MS, Volynskii AB. Determination of individual sulfur-containing compounds in gas condensate and petrol by gas chromatography. Journal of Analytical Chemistry. 2017 Sep 22;72(10):1095–101. doi: 10.1134/s1061934817100021.
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