CAS: 86-65-7; 7-Aminonaphthalene-1,3-Disulfonic Acid

该化合物是一种有机化合物,其特点是氯化萘结构,具有两个磺酸组和一个氨基磺酸组,该化合物一般是一种深色固体,在水中可溶解,在各种应用中有用,特别是在染色工业中,作为异性染料的前体;全氟辛烷磺酸组的存在增强了其溶性与再活性,允许其参与电子生物替代反应;此外,氨基化合物组可以起到核素作用,进一步扩大其反应特征;该化合物还用于生物化学应用,例如用于合成荧光探针和作为分析化学的试剂;其特性,包括某些条件下的pH敏感度和稳定性,使其在研究和工业过程中具有价值;在处理该化合物时,应注意安全防范,因为如果浸泡或吸入,可能会对健康造成危害.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

CAS号81-16-3 2-萘胺-1-磺酸 | CAS号118-32-1 2-萘酚-6,8-二磺酸 | CAS号91-59-8 2-萘胺 | CAS号86-60-2 7-氨基萘-1磺酸 | CAS号93-00-5 2-萘胺-6-磺酸 | CAS号7664-93-9 硫酸 | CAS号74631-01-9 [2]naphthylamin... | CAS号7664-41-7 氨 | CAS号90-51-7 6-氨基-4-羟基-2-萘磺酸 | CAS号578-22-3 5-羟基-2-甲基苯甲酸 | CAS号118-32-1 2-萘酚-6,8-二磺酸 | CAS号85-49-4 1,3,7-Naphthale... | CAS号6094-26-4 1,3-Naphthalene... | CAS号3771-14-0 4-羟基-萘-2-磺酸

合成工艺路线路线简述

  • 1552308-43-6 + 121983-34-4 + 61886-35-9 = 86-65-7 + 93-00-5 + 92-28-4
    反应条件:1.1 Reagents: Sulfuric Acid; Ph 1,30 °C1.2 Reagents: Ammonia,Ammonium Bisulfite Solvents: Water
    标题:Preparation Of 2-Amino-3,6,8-Naphthalene Trisulfonic Acid
    参考文献:China]

    = 86-65-7
    反应条件:1.1 Reagents: Ammonium Hydroxide Catalysts: Potassium Bisulfite
    标题:Manufacture Of 6,8-Disulfo-2-Aminonaphthalene From 6,8-Disulfo-2-Naphthol
    参考文献:Czechoslovakia]

    86-65-7 = 86-65-7
    反应条件:1.1 Reagents: (3-Chloropropyl)Triethoxysilane (Coated On Ldh Of Zinc And Chromium) Solvents: Toluene; 24 H,Reflux
    标题:One-Pot Synthesis Of Benzopyrano[2,3-D]Pyrimidine Derivatives Catalyzed By Ldhs@propyl-Andsa
    作者:Emami-Nori,Alahyar; Et Al
    参考文献:Canadian Journal Of Chemistry 日期:2020 卷标:98(5) 页码:228-235
7-氨基萘-1磺酸置于硫酸体系中,化学反应生成 7-氨基-1,3-萘二磺酸
参考文献:Armstrong; Wynne,Chemical News And Journal Of Industrial Science,1890,Vol. 62,P. 163
标题:Armstrong; Wynne,Chemical News And Journal Of Industrial Science,1890,Vol. 62,P. 163

海关参考信息

专利信息


专利号:US-5260386-A
优先权日:1990-08-20
标 题 :Synthesis of tagged polymers by post-polymerization (trans) amidation reaction
发明人:FONG DODD W; HOOTS JOHN E
权利人:NALCO CHEMICAL CO
摘要:A polymer having pendant fluorescent groups is prepared by (trans)amidation of a preformed polymer by reaction with an amine-containing organic fluorescent composition of the Formula III Formula III wherein one of R5 and R6 may be hydrogen, and wherein within at least one of R5 and R6, or within R5 and R6 taken together, is an organic fluorescent group wherein the organic fluorescent group includes a polynuclear aromatic ring system. A degree of (trans)amidation derivatization of the polymer is accomplished by heating the admixture of polymer and fluorescent agent for a sufficient period of time. A second amine-containing post-polymerization derivatization agent other than the organic fluorescent composition of Formula III is added to the admixture or to at least a portion of the reaction product of the (trans)amidation derivatization, and is heated therewith to accomplish a degree of sequential or simultaneous post-polymerization derivatization with the second amine-containing post-polymerization derivatization agent.

专利号:US-5308460-A
优先权日:1992-10-30
标 题 :Rapid synthesis and analysis of carbohydrates
发明人:MAZID M ABDUL; KLOCK JOHN C
权利人:GLYKO INC
摘要:The subject invention provides novel methods and apparatus for synthesizing carbohydrates of a desired structure. The subject synthesis methods include using carbohydrage-modifying enzymes to perform individual synthesis reaction steps and electrophoresis to purify the reaction products for possible further use as substrates in additional synthesis reactions. The subject invention also provides novel methods and apparatus for detecting carbohydrates of interest. The methods and apparatus for synthesizing or detecting carbohydrates involve the use of carbohydrate-modifying enzymes immobilized in a reaction matrix gel and fluorophore labelled substrates that may be removed from the reaction matrix gel by electrophoresis and subsequently analyzed or transferred to another reaction gel matrix. n The subject invention also provides methods for detecting and quantitating specific carbohydrate-modifying enzymes that might be present in a sample for analysis.

专利号:US-4719053-A
优先权日:1980-08-01
标题 :Beta-chloroethylsulfonylmethyl-benzoic halides as intermediates
发明人:SCHLAEFER LUDWIG; HAEHNLE REINHARD
权利人:HOECHST AG
摘要:New beta -chloroethylsuflonylmethyl-benzoic acid halides which can serve as fibre-reactive anchors for thesynthesis of novel organic, water-soluble compounds, preferably dyestuffs, having fibre-reactive and fibre-finishing properties, such as preferably dyestuff properties, and containing, as a fibre-reactive group, one or two beta -chloroethylsufonylmethylbenzoic acid amide groups. For the synthesis of these novel fibre-finishing compounds, said new beta -chloroethylsulfonylmethyl-benzoic acid halide compounds are reacted with an organic, water-soluble compound having fibre-finishing properties and continuing one or two amino groups. Also precursors of the fibre-finishing, fibre-reactive compounds, containing said beta -chloroethylsulfonylmethyl-benzxoic acid amid grouping, can be employed for their synthesis. The novel fibre-finishing compounds can be applied onto suitable fibre materials, such as especially cellulose fibre material and natural or synthetic polyamide fibre materials, and fixed on these fibre materials in a manner similar to application and fixation methods usual in the technique for fibre-reactive compounds. The fibre-finished material, such as dyed material, shows very good wet fastnesses.

专利号:US-4118384-A
优先权日:1976-02-21
标题 :Process for preparation of azo dyestuffs by coupling in presence of aromatic sulphonic acid-formaldehyde reaction product
发明人:MOLLS HANS-HEINZ; SCHIWY WILLY; HORNLE REINHOLD; NEBELING REINHARD
权利人:BAYER AG
摘要:Dyestuff dispersions and dyestuff solutions free from salt or at least having a low salt content are obtained in that the diazotization is carried out with addition of free dispersing agent acid to which, after the synthesis, either no basic agents are added or basic agents are added only up to a pH value of 3. The disclosed process gives dyestuff compositions of low salt content and results in readily dispersible dyestuffs when water insoluble dyestuffs are prepared and stable solutions when water soluble dyestuffs are prepared. The process is widely applicable and chemical constitution of the dyestuffs is conventional.

专利号:US-4035350-A
优先权日:1975-01-30
标 题:Process for the preparation of water-soluble azo dyestuffs by reacting an aromatic amine and a coupling component with alkali metal nitrite or alkyl nitrite in the absence of acid
发明人:LANDLER JOSEF; WORFEL ERHARD
权利人:HOECHST AG
摘要:A new and very advantageous Process had been found for the preparation of azo dyestuffs by diazotation and coupling in which the synthesis is carried out without the hitherto usual addition of an acid, with the proviso that at least one of the diazo and coupling components contains at least one acid group. Besides the saving of reaction material and subsequently of alkali for neutralization of the reaction medium and isolation of the dyestuff, highly concentrated solutions of the dyestuff and salt-free or practically salt-free dyestuffs can be obtained, and waste-water is no longer charged with big amounts of salts.

专利号:CA-2044456-A1
优先权日:1990-08-20
标 题 :Synthesis of tagged polymers by post-polymerization (trans) amidation reaction
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合成参考文献


参考文献:10.1006/abio.1996.9905
摘要:el Rassi Z, Postlewait J, Mechref Y, Ostrander GK. Capillary electrophoresis of carboxylated carbohydrates. III. Selective precolumn derivatization of glycosaminoglycan disaccharides with 7-aminonaphthalene-1,3-disulfonic acid fluorescing tag for ultrasensitive laser-induced fluorescence detection. Anal Biochem. 1997 Jan 15;244(2):283–90. doi: 10.1006/abio.1996.9905.
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