专利号:US-5869543-A 优先权日:1996-10-22 标题:Process for the synthesis of polyethylene carboxylate from polyethylene carboxylate waste 发明人:BOOS FRANK; SCHNITTKER NORMAN; SEELIG JOACHIM 权利人:ZIMMER AG 摘要:The invention comprises a method for synthesizing polyethylene terephthalate from waste polyethylene terephthalate by cleavage with ethylene glycol and separation of bis(hydroxyethylene) terephthalate from the cleavage mixture with a specific temperature program, recrystallization from water, and esterification and polycondensation with the addition of terephthalic acid. n The invention further comprises a method for synthesis of polyethylene naphthalate from waste polyethylene naphthalate in a similar manner.
专利号:US-12215369-B2 优先权日:2019-03-01 标题:Method for the in vivo synthesis of 4-hydroxymethylfurfural and derivatives thereof 发明人:ALEXANDRINO PAULO MOISES RADUAN; GOUVEA IURI ESTRADA; QUEIROZ VERONICA LEITE 权利人:BRASKEM SA 摘要:The present disclosure provides recombinant microorganisms and methods for the production of 4-HMF, 2,4-furandimethanol, furan-2,4-dicarbaldehyde, 4-(hydroxymethyl)furoic acid, 2-formylfuran-4-carboxylate, 4-formylfuran-2-carboxylate, and/or 2,4-FDCA from a carbon source. The method provides for engineered microorganisms that express endogenous and/or exogenous nucleic acid molecules that catalyze the conversion of a carbon source into 4-HMF, 2,4-furandimethanol, furan-2,4-dicarbaldehyde, 4-(hydroxymethyl)furoic acid, 2-formylfuran-4-carboxylate, 4-formylfuran-2-carboxylate, and/or 2,4-FDCA. The disclosure further provides methods of producing polymers derived from 4-HMF, 2,4-furandimethanol, furan-2,4-dicarbaldehyde, 4-(hydroxymethyl)furoic acid, 2-formylfuran-4-carboxylate, 4-formylfuran-2-carboxylate, and/or 2,4-FDCA.
专利号:US-8748726-B2 优先权日:2009-08-17 标题:Synthesis of silver, antimony, and tin doped bismuth telluride nanoparticles and bulk bismuth telluride to form bismuth telluride composites 发明人:PURKAYASTHA ARUP; JOSHI PURUSHOTTAM 权利人:PURKAYASTHA ARUP; JOSHI PURUSHOTTAM; LAIRD TECHNOLOGIES INC 摘要:According to various aspects, exemplary embodiments are provided of thermoelectric materials, which embodiments may have improved figure of merit. In one exemplary embodiment, a thermoelectric material generally includes bismuth telluride nanoparticles, which may be undoped or doped with at least one or more of silver, antimony, tin, and/or a combination thereof. The bismuth telluride nanoparticles may be dispersed in a matrix material comprising particulate bismuth telluride. Methods for making undoped and doped bismuth telluride nanoparticles are also disclosed, which may include a solvothermal method for making bismuth telluride nanoparticles having a size ranging from 1 to 200 nanometers.
专利号:US-3829428-A 优先权日:1972-09-01 标题 :Process for the catalytic vapor-phase synthesis of alkylpyridines 发明人:HARGIS C 权利人:EASTMAN KODAK CO 摘要:PROCESS FOR THE VAPOR-PHASE PRODUCTION OF 2- AND 4PICOLINE WHICH COMPRISES CONTACTING A MIXTURE OF AMMONIA AND ACETALDEHYDE IN THE VAPOR-PHASE AT AN ELEVATED TEMPERATURE IN THE PRESENCE OF A CATALYST OF SILICA-ALUMINA AND A CO-CATALYST SELECTED FROM LITHIUM PHOSPHATE, NIOBIUM PENTOXIDE, TANTIALUM PENTIOXIDE, BISMUTH TRIOXIDE, ANTIMONY (IV) OXIDE, OR A MIXTURE OF ANTIMONY (IV) OXIDE AND POTASSIUM OXIDE.
专利号:WO-2007104357-A1 优先权日:2006-03-14 标 题 :Synthesis of amines with catalytic amounts of mild lewis acids 发明人:NUGENT THOMAS CHRISTOPHER; WAKCHAURE VIJAY NARAYAN; EL-SHAZLY MOHAMED MAHMOUD 权利人:UNIV JACOBS BREMEN GMBH; NUGENT THOMAS CHRISTOPHER; WAKCHAURE VIJAY NARAYAN; EL-SHAZLY MOHAMED MAHMOUD 摘要:The invention relates to methods for producing primary, secondary and tertiary amines and corresponding enantiopure or enantioenriched primary or secondary amine products, comprising the steps of reductively aminating a ketone, with a nitrogen auxiliary in the presence of a hydrogenating catalyst and a hydrogenating agent, wherein the reductive animation is performed under the influence of a mild Lewis acid, the mild Lewis acid being present at the onset of the reductive amination in at most 25 mol% of the ketone or the nitrogen auxiliary.
专利号:US-9079164-B2 优先权日:2012-03-26 标题:Single reaction synthesis of texturized catalysts 发明人:WOODFIELD BRIAN F; SMITH STACEY; SELCK DAVID; BARTHOLOMEW CALVIN H; MA XUCHU; XU FEN; OLSEN REBECCA E; ASTLE LYNN 权利人:UNIV BRIGHAM YOUNG 摘要:Methods are described for making a texturized catalyst. The textural promoter may be a high-surface area, high-porosity, stable metal oxide support. The catalyst is manufactured by reacting catalyst precursor materials and support materials in a single, solvent deficient reaction to form a catalyst. The catalyst may be particles or a coating or partial coating of a support surface.
[参考文献]: Bin Zhou, Et Al. Monodisperse Agsbs2 Nanocrystals: Size-Control Strategy, Large-Scale Synthesis, And Photoelectrochemistry. Chemistry. 2015 Jul 27;21(31):11143-51.
合成参考文献
摘要:Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku, Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972, -(17), 1972 摘要:L808: ATSDR - Agency for Toxic Substances and Disease Registry (1990). Toxicological profile for silver. U.S. Public Health Service in collaboration with U.S. Environmental Protection Agency (EPA). http://www.atsdr.cdc.gov/toxprofiles/tp.asp id=539&tid=97