CAS: 52570-16-8; Naproanilide

该化合物是属于类类硅化物的化学化合物,其特征是其结构,其结构包括一个通过氨化物结合连接而连接到阴离子细胞的环环环系统,该化合物一般是白色的,以其在包括制药和农用化学在内的各个领域的潜在用途而著称.Naproanilid在有机溶剂中表现出中等溶解性,在标准条件下相对稳定.其化学特性包括能够参与各种典型的氨化物反应,例如水解和细胞化.此外,它可能展示生物活动,使其对医药化学感兴趣.应该参考安全数据,以便处理和接触准则,如任何化学物质一样.

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上下游产品

CAS号42308-20-3 Propanamide, 2-... | CAS号135-19-3 2-萘酚 | CAS号135-88-6 N-苯基-2-萘胺

合成工艺路线路线简述

    📜2-Bromopropionanilide,2-萘酚置于potassium Hydroxide体系中,用 二甲基亚砜 作为反应溶剂,化学反应 2.0H,反应生成 萘丙胺
    参考文献:无金属条件下苯酚的直接胺化
    标题:无金属条件下苯酚的直接胺化
    摘要:在此,我们公开了通过使用胺化试剂直接胺化苯酚来无金属合成芳胺.该反应过程使用容易获得的胺化试剂,并为具有各种官能度的广泛芳胺提供了一种通用的合成途径,收率非常好至极好.通过使用胺化和氧化偶联反应的两步路线,我们从两种市售酚类合成了三种天然存在的咔唑生物碱:Murrayafoline A,Mukonine 和黄花碱.
    DOI:10.1055/s-0033-1338703

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    专利信息


    专利号:WO-2024256370-A1
    优先权日:2023-06-13
    标 题 :Synthesis of glufosinate using an amidase-based process
    发明人：ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.

    专利号:US-2025120400-A1
    优先权日:2021-12-10
    标题:Synthesis of glufosinate using a hydantoinase-based process
    发明人：DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.

    专利号:US-11919928-B2
    优先权日:2016-03-16
    标题 :Method for producing dihydrotentoxin
    发明人：KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI
    权利人:KUMIAI CHEMICAL INDUSTRY CO
    摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.

    专利号:US-2021386068-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
    发明人：KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.

    专利号:US-2021352899-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
    发明人：KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.

    专利号:ES-2717283-T3
    优先权日:2012-07-24
    标 题:Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid or a derivative thereof and herbicides inhibitors of VLCFA synthesis and synthesis of fatty acids / lipids

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    主要参考文献


    1: Abuin E, Lissi E, Ahumada M, Calderón C. Effect of human serum albumin on the kinetics of N-glutaryl-L-phenylalanine p-nitroanilide hydrolysis catalyzed by α-chymotrypsin. Protein J. 2011 Feb;30(2):143-7. doi: 10.1007/s10930-011-9315-3. 5(10):4915-4923. doi: 10.1021/acsomega.9b03750.
    3: Abuin E, Lissi E, Calderón C. Kinetics of N-glutaryl-L-phenylalanine p-nitroanilide hydrolysis catalyzed by alpha-chymotrypsin in aqueous solutions of alkyltrimethylammonium bromides. J Colloid Interface Sci. 2007 Apr 15;308(2):573-6. doi: 10.1016/j.jcis.2007.01.007. Epub 2007 Jan 10. 72(2):205-10. doi: 10.1016/0009-8981(76)90074-7. 23(1):79-85. 26(12):2476-80. doi: 10.1002/elps.200500047. 26(11):1528-33. doi: 10.1248/bpb.26.1528. 57(1):127-38. doi: 10.1016/0049-3848(90)90201-m. 52(30):5145-54. doi: 10.1021/bi400629r. Epub 2013 Jul 17.
    10: Tokai S, Bito T, Shimizu K, Arima J. Methionine residues lining the substrate pathway in prolyl oligopeptidase from Pleurotus eryngii play an important role in substrate recognition. Biosci Biotechnol Biochem. 2018 Jul;82(7):1107-1115. doi: 10.1080/09168451.2018.1459177. Epub 2018 Apr 6. 55(5):812-8. doi: 10.1007/s000180050334. 258(22):13552-7. 1(1):37-9. doi: 10.1165/ajrcmb/1.1.37. 527(1):42-55. doi: 10.1016/0005-2744(78)90254-1. 742(3):539-57. doi: 10.1016/0167-4838(83)90272-8. 48(11):1740-4. doi: 10.1248/cpb.48.1740. 187(2):173-80. doi: 10.1016/0009-8981(90)90344-r. 47(4):453-8. doi: 10.1016/j.toxicon.2006.01.001. Epub 2006 Feb 20. 2--substrate inhibition in the catalyzed hydrolysis of N alpha-p-tosyl-L-arginine methyl ester. Arch Biochem Biophys. 2002 Apr 1;400(1):7-14. doi: 10.1006/abbi.2002.2764. 152(2):239-44. doi: 10.1016/0003-2697(86)90404-5.

    合成参考文献


    摘要:Japan Pesticide Information., (40)(32), 1982
    摘要:Farm Chemicals Handbook., -(C318), 1991
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