CAS: 49543-63-7; (4-(Tert-Butyl)Phenyl)Methanethiol

上下游产品

CAS号120-51-4 苯甲酸苄酯 | CAS号100-51-6 苯甲醇 | CAS号340-04-5 α-(三氟甲基)苄醇

对叔丁基苯甲醛置于potassium Ethyl Xanthogenate体系中,用 N,N-二甲基甲酰胺 作为反应溶剂,150.0 °C,101.33 Kpa 条件下,反应生成 对叔丁基苄硫醇
参考文献:黄原酸钾促进的还原硫化反应:从醛到硫醇,二硫化物和硫酯衍生物
标题:黄原酸钾促进的还原硫化反应:从醛到硫醇,二硫化物和硫酯衍生物
摘要:在此,我们开发了一种直接构建c-S键以获得具有生物活性的含硫化合物的合成策略,以及一种涉及醛或酮的还原硫化以获得多种取代的硫醇,二硫化物和硫酯衍生物的方法. Etocs 2 K 被证明可以作为 Berzelius 试剂或 Lawesson 试剂构建 C-S 键的潜在替代品.
DOI:10.1039/d3Cc05637F

专利信息

专利号:US-8476441-B2
优先权日:2009-01-29
标 题 :Intermediates in the enantioselective synthesis of 3-(aminomethyl)-5-methyl-hexanoic acid
发明人：CONNON STEPHEN JOSEPH; PESCHIULLI ALDO; MARKEY LYN
权利人:CONNON STEPHEN JOSEPH; PESCHIULLI ALDO; MARKEY LYN; TRINITY COLLEGE DUBLIN
摘要:(S)-(+)-3-(aminomethyl)-5-methyl-hexanoic acid or (S)-pregabalin is an anticonvulsive drug. In addition to its use as an anticonvulsive agent, pregabalin has also been indicated as a medicament in the treatment of anxiety, neuropathic pain and pain in patients with fibromyalgia. Provided herein are thioester intermediates in the synthesis of and processes for the synthesis of 3-(aminomethyl)-5-methyl-hexanoic acid in the (R) or (S) configuration.

专利号:US-11685712-B2
优先权日:2019-12-30
标 题 :Synthesis of monofunctional thiuram accelerator
发明人：SPILKER THOMAS FRANKLIN; Jin ji yang; FEHER FRANK J
权利人:GOODYEAR TIRE & RUBBER
摘要:The present invention provides a route for synthesizing monofunctional thiuram compounds that is safe, environmentally friendly, and cost effective. This method specifically involves synthesizing a monofunctional thiuram by (1) reacting a tetraorganylthiuram disulfide with an organyl mercaptan to produce the monofunctional thiuram and a dithiocarbamate metal salt or a dithiocarbamate metalloid salt under basic conditions, (2) separating the monofunctional thiuram in an organic phase from the dithiocarbamate metal salt or the dithiocarbamate metalloid salt in an aqueous phase, and (3) recovering the monofunctional thiuram from the aqueous phase. The monofunctional thiuram compounds made in accordance with this invention are of particular value as accelerators for use in the vulcanization of rubber. The use of these monofunctional thiuram compounds as accelerators provides good cure rates and as well as good scorch safety.

专利号:US-2023029068-A1
优先权日:2019-12-30
标题:Synthesis of monofunctional thiuram accelerator

专利号:US-2012046468-A1
优先权日:2009-01-29
标题 :Intermediates in the enantioselective synthesis of 3-(aminomethyl)-5-methyl-hexanoic acid

专利号:EP-3845520-B1
优先权日:2019-12-30
标题:Synthesis of monofunctional thiuram accelerator

专利号:US-2021198194-A1
优先权日:2019-12-30
标题 :Synthesis of monofunctional thiuram accelerator