CAS: 181257-35-2; Bis(2-Furyl)Chlorophosphine
该化合物是一种有机磷的化合物,其特征是,磷原子有两种附着于磷原子的纤维基体组,该物质也与氯原子相连,该化合物通常在三角金字塔几何学中显示磷中心,受电阴氯原子和电饱和的柔性动物组的影响,它会给该化合物的再活性和在有机合成和协调化学中的潜在应用作出贡献.它作为绿灯,可以参与各种化学反应,包括核生殖替代和核离子协调,使它在开发磷离心和催化作用方面变得宝贵.此外,柔性环的存在可能会带来独特的电子特性,并增强它对电击球体的再活性.在处理该化合物时,安全因素至关重要,因为有机磷化合物可以表现出毒性,需要适当的储存和处置方法.
相似化合物
5518-52-5物理性质
MSDS等安全信息
欧盟法规
ECHA物质C&L通报上下游产品
2-lithiofuran 2,2'-(N,N-diethylaminophosphiniden)bisfuran furanbis(2-furyl)-N,N-bis-[(S)-1-phenyl-ethyl]phosphinamine [methoxy(2-(di-2-furylphosphanyl)phenyl)methyl]ferr°Cene 1-(4-(dicyclohexylphosphino)phenyl)-2-(di-2-furylphosphino)-4,5-dimethyl-1H-imidazole 1-(4-(diphenylphosphino)phenyl)-2-(di-2-furylphosphino)-4,5-dimethyl-1H-imidazole合成工艺路线路线简述
📜呋喃-2-基-锂置于三氯化磷体系中,用 乙醚,正己烷 用作溶剂,以53%的收率获得二(2-呋喃)氯化膦
参考文献:Synthesis,Resolution And Application Of 2,2'-Bis(Di-2-Furylphosphino)-1,1'-Binaphthalene
标题:Synthesis,Resolution And Application Of 2,2'-Bis(Di-2-Furylphosphino)-1,1'-Binaphthalene
摘要:A Six Step Synthesis And Resolution Of (+/-)-2,2'-Bis(Di-2-Furylphosphino)-1,1'-Binaphthalene 4 (Tetfubinap) Is Described Along With Its Use In Asymmetric Inter-And Intramolecular Heck Reactions. (C) 2001 Elsevier Science Ltd. All Rights Reserved.
Doi:10.1016/s0957-4166(01)00035-0
专利信息
专利号:US-7375241-B2
优先权日:2003-12-12
标题 :Ferrocenyl-1,2-diphosphines, the production thereof and their use
发明人：LOTZ MATTHIAS; KESSELGRUBER MARTIN; THOMMEN MARC; PUGIN BENOIT
权利人:SOLVIAS AG
摘要:The invention relates to compounds of formula (I) provided in the form of racemic compounds, mixtures of diastereomers or essentially pure diastereomers, wherein R 1 represents a hydrogen atom or C 1 -C 4 -alkyl, and at least one secondary phosphine depicts an unsubstituted or substituted cyclic phosphine group, or phosphonium salts thereof having one or two monovalent anions or a divalent anion. The compounds of formula (I) can be obtained by means of a novel method and are valuable ligands for catalytically active metal complexes in asymmetrical synthesis
专利号:CN-115772197-A
优先权日:2022-11-30
标题:Synthesis method of bis (2-furyl) phosphorus chloride
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📌 第三方产品分析报告
合成参考文献
合成方法参考DOI号:10.1016/S0957-4166(01)00035-0
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