CAS: 151636-94-1; 10-Deacetyl-10-Dehydrobaccatin V

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上下游产品

10-脱乙酰基巴卡丁 Iii 10-Deacetylbaccatin Iii 32981-86-5

合成工艺路线路线简述

    📜10-脱乙酰基巴卡丁 Iii置于copper Diacetate体系中,用 甲醇 用作溶剂,化学反应 48.0H,以47%的收率获得7-表-10-氧代-10-去乙酰基浆果赤霉素iii
    参考文献:Appendino,Giovanni; Fenoglio,Ivana; Cravotto,Giancarlo,Gazzetta Chimica Italiana,1994,Vol. 124,# 6,P. 253-258
    标题:Appendino,Giovanni; Fenoglio,Ivana; Cravotto,Giancarlo,Gazzetta Chimica Italiana,1994,Vol. 124,# 6,P. 253-258

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    专利信息


    专利号:US-2010069643-A1
    优先权日:2005-12-21
    标 题:Convergent Process for the Synthesis of Taxane Derivatives
    发明人：MCCHESNEY JAMES D; HENRI JOHN T; VENKATARAMAN SYLESH K; LAMB RODGER L; FOSTER JONATHAN E; SUMMER CHRISTIAN M; YE SHANGPING
    权利人:MCCHESNEY JAMES D; HENRI JOHN T; VENKATARAMAN SYLESH K; LAMB RODGER L; FOSTER JONATHAN E; SUMMER CHRISTIAN M; YE SHANGPING
    摘要:The application provides a process for the preparation of taxane derivatives and intermediates useful in such processes.

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    ✅ COA系统入驻 | 共享模式

    主要参考文献

    参考标题:Synthesis Of Modified Baccatins Via An Oxidation-Reduction Protocol
    作者:Giovanni Appendino,Jasmin Jakupovic,Giancarlo Cravotto,Renata Enriù,Marcella Varese,Ezio Bombardelli |发布日期:1995.5
    摘要:(12R)-7-Trietylsilyl-11-Dihydro-10-Deacetylbaccatin Iii (2), 10-Epi-10-Deacetylbaccatin Iii (4) And The 7,8-Seco Baccatin Iii (5A) Were Synthesized From 10-Deacetylbaccatin Iii Via An Oxidation-Reduction Protocol.

    合成参考文献


    参考文献:10.5281/zenodo.5794106
    摘要:The LOTUS Initiative for Open Natural Products Research: frozen dataset union wikidata (with metadata) | DOI:10.5281/zenodo.5794106
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