CAS: 74213-24-4; 1,1-Dibromoformaldoxime

上下游产品

CAS号298-12-4 乙醛酸 | CAS号3545-80-0 glyoxilic acid oxime | CAS号62812-66-2 2-hydroxyiminoa... | CAS号168208-95-5 (2E)-(Hydroxyim... | CAS号51060-05-0 formonitrile oxide | CAS号7726-95-6 溴素 | CAS号15736-98-8 sodium,oxidoaza... | CAS号3545-78-6 2-(羟氨基)乙酸 | CAS号92114-96-0 mercuric fulminate | CAS号69676-53-5 N-(tert-butyl)o... | CAS号1120215-06-6 2-(3-溴-4,5-二氢-5... | CAS号1120214-99-4 3-溴-5-环己基-4,5-二氢-异噁唑 | CAS号1120215-02-2 3-溴-4,5-二氢-5-(4... | CAS号105174-97-8 3-溴异恶唑-5-甲酸乙酯 | CAS号111303-36-7 3-溴-4-异噁唑羧酸乙酯 | CAS号506-68-3 溴化氰 | CAS号124-38-9 二氧化碳 | CAS号7726-95-6 溴素 | CAS号10035-10-6 氢溴酸 | CAS号7803-49-8 羟胺

乙醛酸置于盐酸羟胺,溴体系中,用 水,二氯甲烷 作为反应溶剂,化学反应 27.0H,反应生成 1,1-二溴甲醛肟
参考文献:光辅助多样性导向合成的构象约束五(杂)环分子结构
标题:光辅助多样性导向合成的构象约束五(杂)环分子结构
摘要:光生氮杂二甲苯的分子内环加成提供了前所未有的多杂环支架,适用于随后的光化学后修饰以进一步增加分子复杂性.在这里,我们探索了快速"组装"新型光前体与能够产生潜在药效团并与随后的 1,3-偶极环加成相兼容的新型光前体的方法,以提供具有新结构核心,最少数量可旋转键的五环杂环,和高含量的 Sp3 杂化碳.光前体的模块化"组装"和初级光产物的光化学后修饰的潜在多样性为这种合成策略的组合实施提供了框架.
DOI:10.1002/ejoc.201403620

专利信息

专利号:US-6207863-B1
优先权日:1998-08-11
标题 :Synthesis of haloformimine compounds
发明人：BERRIER JOHN VINCENT; UMARVADIA ASHUTOSH SUMANTRAI
权利人:ROHM & HAAS
摘要:Disclosed is an improved method for the preparation of highly pure haloformimine compounds in high yields by reacting a formimine compound in a solvent with a halogenating agent while maintaining the pH of the halogenation reaction in the range of 2 to 5. The pH of the reaction may be maintained by a variety of means, such as by the addition of a base.

专利号:US-6133473-A
优先权日:1998-06-25
标 题 :Synthesis of carbamate compounds
发明人：BERRIER JOHN VINCENT
权利人:ROHM & HAAS
摘要:Disclosed is a method for the preparation of carbamate compounds substantially free of by-products; the carbamate compounds being prepared by reacting an isocyanate with a hydroxylated compound in the presence of certain catalysts that increase the rate of carbamylation while decreasing the rate of by-product formation.

专利号:US-4644072-A
优先权日:1985-04-12
标 题 :Intermediates for the production of epipodophyllotoxin and related compounds and processes for the preparation and use thereof
发明人：VYAS DOLATRAI M; SKONEZNY PAUL M
权利人:BRISTOL MYERS CO
摘要:There is provided a novel and efficient stereoselective total synthesis of epipodophyllotoxin and related epipodophyllotoxin compounds of the general formula ##STR1## wherein R 1 and R 2 each are independently hydrogen or (lower)alkoxy, or R 1 and R 2 , taken together, is methylenedioxy; R 4 and R 6 each are independently hydrogen or (lower)alkoxy; and R 5 is hydrogen or a phenol-protecting group; or an acid addition salt thereof. The present invention also provides novel intermediates and processes for the preparation of said intermediates, which are then converted into known antineoplastic agents.

专利号:US-5086182-A
优先权日:1985-04-12
标题:Intermediates for the production of epipodophyllotoxin and related compounds and processes for the preparation and use thereof
发明人：VYAS DOLATRAI M; SKONEZNY PAUL M
权利人:BRISTOL MYERS CO
摘要:There is provided a novel and efficient stereoselective total synthesis of epiodophyllotoxin and related epipodophyllotoxin compounds of the general formula wherein R1 and R2 are independently hydrogen or (lower)-alkoxy, or R1 and R2, taken together, is methylenedioxy; R4 and R6 each are independently hydrogen or (lower) alkoxy; and R5 is hydrogen or a phenol-protecting group; or an acid addition salt thereof. The present invention also provides novel intermediates and processes for the preparation of said intermediates, which are then converted into known antineoplastic agents.

专利号:US-4728740-A
优先权日:1985-04-12
标 题:Intermediates for the production of epipodophylotoxin and related compounds and processes for the preparation and use thereof
发明人：VYAS DOLATRAI M; SKONEZNY PAUL M
权利人:BRISTOL MYERS CO
摘要:There is provided a novel and efficient stereoselective total synthesis of epipodophyllotoxin and related epipodophyllotoxin compounds of the general formula wherein R1 and R2 each are independently hydrogen or (lower)alkoxy, or R1 and R2, taken together, is methylenedioxy; R4 and R6 each are independently hydrogen or (lower)alkoxy; and R5 is hydrogen or a phenol-protecting group; or an acid addition salt thereof. The present invention also provides novel intermediates and processes for the preparation of said intermediates, which are then converted into known antineoplastic agents.

专利号:US-4795819-A
优先权日:1985-04-12
标 题 :Intermediates for the production of epipodophyllotoxin and related compounds and processes for the preparation and use thereof
发明人：VYAS DOLATRAI M; SKONEZNY PAUL M
权利人:BRISTOL MYERS CO
摘要:There is provided a novel and efficient stereoselective total synthesis of epipodophyllotoxin and related epipodophyllotoxin compounds of the general formula ##STR1## wherein R 1 and R 2 each are independently hydrogen or (lower)alkoxy, or R 1 and R 2 , taken together, is methylenedioxy; R 4 and R 6 each are independently hydrogen or (lower)alkoxy; and R 5 is hydrogen or a phenol-protecting group; or an acid addition salt thereof. The present invention also provides novel intermediates and processes for the preparation of said intermediates, which are then converted into known antineoplastic agents.