CAS: 38078-71-6; 4-Cyano-Tempo

该化合物是一种稳定的硝基乙基化合物,在氧化反应中广泛用作催化剂或催化剂,其主要优点包括在有氧条件下高度稳定,有效的再氧化活动,以及将酒精转化为碳基化合物的选择性. 半碳基组增强了其在极溶剂中的溶解性,扩大了其在有机合成中的应用性. 作为一个持久性激进体,它促进受控的激进聚合过程,提供精确的分子重量控制. 它的坚固结构确保了最小的降解,使之适合长期反应. 4-Cyano-TEMPO还被用于电化学应用,并因其对磁性特性而成为ERP光谱的旋转标签.

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37149-18-1 2564-83-2 7031-93-8

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4-oxo-2,2,6,6-tetramethylpiperidin-oxyl [(p-methylphenyl)sulfonylmethyl]isonitrile 1-hydroxy-4-cyano-2,2,6,6-tetramethylpiperidinium chloride 2,2,6,6-Tetramethyl-4-piperidone 1-oxyl-4-carboxyl-2,2,6,6-tetramethylpiperidine

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    专利信息


    专利号:WO-2013182636-A1
    优先权日:2012-06-07
    标 题 :Synthesis of a viral protease inhibitor
    发明人:ALLEGRINI PIETRO; BRUNOLDI ENRICO; ATTOLINO EMANUELE
    权利人:DIPHARMA FRANCIS SRL
    摘要:Disclosed is a process for the preparation of telaprevir of formula (I) or a salt thereof, comprising the oxidation reaction of a compound of formula (II) or a salt thereof, (II) wherein said oxidation is conducted in a solvent in the presence of a supported oxidising agent.

    专利号:WO-2024237180-A1
    优先权日:2023-05-16
    标题 :(meth)acrylate compound production method
    发明人:NAKAKURA KOKI; SHIRAI SHINYOU
    权利人:MITSUBISHI GAS CHEMICAL CO
    摘要:The present invention provides, inter alia, a (meth)acrylate compound production method capable of suppressing polymerization of a feedstock acrylic acid ester at the time of synthesis and obtaining a reaction product having higher purity. The (meth)acrylate compound production method according to the present invention is characterized by comprising at least a step for carrying out an ester exchange reaction of spiroglycol and a (meth)acrylic acid ester in the presence of a polymerization inhibitor, the polymerization inhibitor containing an N-oxyl compound and a polymerization inhibitor having a boiling point of 246°C or less.

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    合成参考文献


    参考文献:10.1134/s0006297910070126
    摘要:Myasoedova KN, Timofeev KN. Conformational changes near the cytochrome P450 active site upon binding of two different ligands. Biochemistry (Mosc). 2010 Jul;75(7):899–904. doi: 10.1134/s0006297910070126.
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