专利号:US-5455367-A 优先权日:1993-04-22 标 题:Method for the synthesis of silanes or organosilicon hydrides by the reduction of the corresponding silicon halides or organosilicon halides 发明人:KLEIN KLAUS-DIETER; KNOTT WILFRIED; KOERNER GOETZ 权利人:GOLDSCHMIDT AG TH 摘要:A method for the synthesis of silanes or organosilicon hydrides by the reduction of the corresponding silicon halides or organosilicon halides with a magnesium hydride in a liquid reaction medium is carried out by utilizing the following distinguishing features: n a) the use of non-pyrophoric, preferably autocatalytically produced, storage magnesium hydride as magnesium hydride, n b) the use of conventional ethers as reaction medium, and n c) the continuous removal of the magnesium halide formed being deposited on the surface of the magnesium hydride particles during the reaction by the action of mechanical energy or ultrasound so as to form a fresh surface.
专利号:WO-2019197122-A1 优先权日:2018-04-10 标 题:Process for treatment of at least one cell with a chemical synthesis product in a microarray 发明人:BENZ MAXIMILIAN; LEVKIN PAVEL A; MOLLA MIJANUR R; ROSENFELD ALISA; BREHM MARIUS 权利人:KARLSRUHER INST TECHNOLOGIE 摘要:The present invention relates to a process for treatment of at least one cell with a chemical synthesis product in a microarray, a stacked microarray, a kit comprising at least one microarray and the use of a microarray for the chemical synthesis of a chemical synthesis product and for the treatment of at least one cell with the chemical synthesis product in a microarray.
专利号:US-9751909-B2 优先权日:2011-09-07 标 题 :Synthesis and uses of nucleic acid compounds with conformationally restricted monomers 发明人:MATRAY TRACY J; MACIAGIEWICZ IWONA M; HOUSTON JR MICHAEL E 权利人:MATRAY TRACY J; MACIAGIEWICZ IWONA M; HOUSTON JR MICHAEL E; MARINA BIOTECH INC 摘要:Processes for synthesis of conformationally restricted nucleomonomers (CRN) by ozonolysis or oxidation of a 2′-vinyl substituted nucleoside precursor with protected 3′-hydroxyl, 4′-hydroxymethyl and 5′-hydroxyl positions. The CRN nucleomonomers can be used to prepare nucleic acid compounds. CRN nucleomonomers for nucleic acid compounds can be prepared in high yields and in multi-gram scale. The nucleic acid compounds can be of various regulatory classes such as antisense RNA for therapeutic modalities useful for treating or preventing diseases or disorders by up- or down-regulating the expression of genes and other nucleic acid based regulatory systems in a cell.
专利号:US-6518383-B1 优先权日:1997-07-17 标题 :Branched polyolefin synthesis 发明人:WILCZEK LECH 权利人:DU PONT 摘要:This invention relates to a process for the synthesis of addition polymers containing branches upon branches and having a polymerizable olefin end group by a convenient one-pot polymerization of selected vinyl monomers with chain polymerization initiators and a method to provide olefinic end groups by chain termination agents; and polymers produced thereby characterized by branch-on-branch structure and lower inherent viscosity than heretofore possible.
专利号:US-6897278-B2 优先权日:1997-07-17 标题:Branched polyolefin synthesis 发明人:WILCZEK LECH 权利人:DU PONT 摘要:This invention relates to a process for the synthesis of addition polymers containing branches upon branches and having a polymerizable olefin end group by a convenient one-pot polymerization of selected vinyl monomers with chain polymerization initiators and a method to provide olefinic end groups by chain termination agents; and polymers produced thereby characterized by branch-on-branch structure and lower inherent viscosity than heretofore possible.
专利号:US-7576169-B2 优先权日:2003-10-23 标 题:Facile synthesis of polyhedral silsesquioxane anions and use thereof 发明人:HASEGAWA ISAO; LAINE RICHARD M; ASUNCION MICHAEL Z; TAKAMURA NORIHIRO 权利人:UNIV MICHIGAN 摘要:Polyhedral silsesquioxane anions are economically prepared by reaction of a silica source derived from combusted organic material with a quaternary ammonium hydroxide compound. Reaction of the resulting anions with chlorosilanes may be effected in near stoichiometric fashion in organic solvent containing reactive quantities of organic acids such as formic acid. The functional groups on the resulting functionalized silsesquioxanes may be substituted for other functional groups by reaction with di- or polysiloxanes in the presence of a synthetic ion exchange resin.
参考标题:Direct Synthesis Of Dialkylarylvinylsilane Derivatives: Metathesis Of Dialkylaryl-Iso-Propenylsilane And Its Application To Tetracyclic Silacycle Dye Synthesis 作者:Shohei Yoshioka,Tsunayoshi Takehara,Tsuyoshi Matsuzaki,Takeyuki Suzuki,Hirofumi Tsujino,Tadayuki Uno,Yasuo Tsutsumi,Kenichi Murai,Hiromichi Fujioka,Mitsuhiro Arisawa 摘要:The Metathesis Of Dialkylarylvinylsilane, Which Has Not Been Accomplished To Date, Is Achieved Using Dialkylaryl-Iso-Propenylsilane As A Substrate. In Addition, We Discovered That The Reason Why The Metathesis Of A Ruthenium Carbene Complex And Dialkylarylvinylsilane Is Difficult Is The Formation Of A Carbide Complex.
合成参考文献
摘要:Fringuelli, F.; Piermatti, O.; Pizzo, F.; Vaccaro, L., Science of Synthesis, (2010) 47, 644. 摘要:Micalizio, G. C., Science of Synthesis Knowledge Updates, (2012) 4, 62. 摘要:Micalizio, G. C., Science of Synthesis Knowledge Updates, (2012) 4, 87. 摘要:Krause, N.; Arisetti, N., Science of Synthesis Knowledge Updates, (2020) 3, 73. 摘要:Micalizio, G. C., Science of Synthesis Knowledge Updates, (2012) 4, 92.