CAS: 996-08-7; Dibromo(Dibutyl)Stannane

该化合物是一种有机锡化合物,其特征是二溴和二丁基功能组,这种沙纳衍生物主要用于有机合成和催化,特别是用于涉及锡介质联结或卤素交换过程的反应,其定义明确的分子结构确保了一致性的回动性,使其成为选择性转化的可靠试剂.该化合物在受控条件下的稳定性允许在合成应用中进行精确处理. 二溴二丁基斯坦南(Dimmoblybutylstanne)还被用于改变表面特性的物质科学,或用作高级含锡材料制作过程中的前体.建议在无水环境中适当储存,以保持其完整性.

结构式图片

欧盟法规

ECHA物质C&L通报

上下游产品

1-bromo-butane tin tetra-n-butyltin(IV) boron tribromidetributyltin bromide dibutylstannane hexaphenylditin

合成工艺路线路线简述

  • 合成目标产物 Di-N-Butyldibromotin 主要起始原料 1-Bromobutane And Tin
  • (文献来源)合成步骤主要原料 1-Bromobutane 和 Tin
📜二丁基二氯化锡置于sodium Bromide Or Potassium Bromide体系中,用 丙酮 作为反应溶剂,化学反应生成 二溴化二丁锡
参考文献:一些具有氮和氧供体配体的二卤代二有机锡二卤化物和双假卤化物配合物的合成和119Mmössbauer光谱
标题:一些具有氮和氧供体配体的二卤代二有机锡二卤化物和双假卤化物配合物的合成和119Mmössbauer光谱
摘要:合成和119米的类型r的114个络合物的sn穆斯堡尔谱2 Snx 2,L 2(rme等,正pr,正丁基,正-十月中,Ph,Bz; X氟,氯,溴,I,Ncs,L 2 2单齿或二齿1 O-或n-供配体(S)),其中74个是新的,则报告.大部分复合物是同构的,具有八面体反式-R 2 Snx 4几何约锡,而二苯基复合物5(rph值; X氯,L 2 amp,Nphen; Xncs,L 2  Bipy,Phen,Tmphen)采用顺式-R 2 Snx 4八面体结构.
DOI:10.1016/s0022-328X(00)85834-9

海关参考信息

专利信息


专利号:US-2024368099-A1
优先权日:2022-01-18
标 题:Methods for the synthesis of di(hydroxymethyl)tetrahydrofuran and its application in polyesters and polyurethanes
发明人:SPIEGELBERG BRIAN; BRANDT ADRIAN; BECK HORST; KUX ALEXANDER; TIN SERGEY; DE VRIES JOHANNES GERARDUS
权利人:HENKEL AG & CO KGAA
摘要:The present invention relates to the synthesis of di(hydroxymethyl)tetrahydrofuran (DHMTHF) and the preparation of trans-enriched mixtures of DHMTHF. The invention further refers to polyester polyols which are obtained by reaction of cis/trans DHMTHF mixtures with a dicarboxylic acid. The invention further relates to polyurethanes and compositions containing a polyester polyol comprising DHMTHF, in particular to such polyurethane-containing (adhesive) compositions.

专利号:US-2024383928-A1
优先权日:2021-07-30
标 题:Production of diorganotin dihalides
发明人:VINCENT ROBERT; ZIMMERMANN JARROD C
权利人:MERCK PATENT GMBH
摘要:The disclosed and claimed subject matter relates to the safe and efficient synthesis of diorganotin dihalide compounds of the formula R2SnX2 that as-synthesized are free of tetraalkyltin (R4Sn), trialkyltin halide (R3SnX) and monoalkyltin trihalide (RSnX3) species and of methods for their synthesis and use.

专利号:US-8933181-B2
优先权日:2006-10-06
标题:Branched polymers and methods for their synthesis and use
发明人:MOURI HIROSHI; LUO STEVEN; KURASCH JESSICA; ROBERTSON CHRISTOPHER G; WARREN SANDRA
权利人:MOURI HIROSHI; LUO STEVEN; KURASCH JESSICA; ROBERTSON CHRISTOPHER G; WARREN SANDRA; BRIDGESTONE CORP
摘要:Branched polymers including multi-branched polymers, functionalized branched polymers, star-branched polymers, and dendigraft polymers. Methods for the synthesis of branched polymers and method for the use of branched polymers in tire components are also included.

专利号:US-2018009956-A1
优先权日:2014-11-27
标题 :Synthesis of polymer polyols in unsaturated polyols, polymer polyols and their use

专利号:US-11767388-B1
优先权日:2019-09-18
标 题 :Silicon-functionalized rubber
发明人:ENSIGN SETH CODY; VIELHABER MARGARET FLOOK; JOHNGRASS JENA LYNN; MA LIQING
权利人:GOODYEAR TIRE & RUBBER
摘要:The compatibility between silica fillers and synthetic rubbers which are synthesized utilizing lanthanide-based catalyst systems, such as neodymium catalyst systems can be improved by terminating the polymerization with a vinyl silane terminating agent. In doing so the vinyl silane is allowed to react with the polymer chain ends of the neodymium rubber to functionalize the chain ends of the polymer chains with silicon containing groups. This results in the rubber having better characteristics for utilization in tire rubber formulations, such a tire tread formulations, that exhibit improved wear characteristics and lower rolling resistance. The process for the synthesis of such functionalized polydiene rubber comprises (1) polymerizing a diene monomer in the presence of a lanthanide-based catalyst system, and (2) terminating the polymerization with a vinyl silane terminator. The functionalized polydiene rubber composition made by this method is comprised of a polydiene rubber which is functionalized at its chain ends with a silicon containing group.

专利号:US-8329923-B2
优先权日:2010-06-17
标 题:4, 4′ disubstituted 4H-cyclopentadithiophene and new methods for synthesizing the same
发明人:VANDERZANDE DIRK; LUTSEN LAURENCE; VAN MIERLOO SARAH
权利人:VANDERZANDE DIRK; LUTSEN LAURENCE; VAN MIERLOO SARAH; IMEC; UNIV HASSELT
摘要:The present preferred embodiments relate to a method for the synthesis of a compound having the following general formula: n nthe method comprising the step of reacting, in presence of a diprotic acid having a negative pKa, a compound having the general formula:n n nwherein R 1 and R 2 are organic groups and wherein X and Y are independently selected from the group consisting of hydrogen, chloro, bromo, iodo, boronic acid, boronate esters, borane, pseudohalogen and organotin. It further relates to compounds so obtained and to compounds resulting from the ring closure of compound (II).

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品牌试剂参考报价(招募中)

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

合成参考文献


摘要:Sangyo Igaku. Japanese Journal of Industrial Health., 15(3), 1973
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