CAS: 6088-51-3; Bis(6-Hydroxy-2-Naphthyl) Disulfide
该化合物其结构特征为两套环状物,由硫化物桥连接,该化合物一般在室温时是固体,由于存在氯化萘环,以其独特的芳香特性而闻名.它溶于有机溶剂中,但溶解度有限.DTBN具有抗氧化性,因此它具有各种化学用途,包括作为聚合物稳定剂和有机合成的试剂.在环状物中存在氢化物组有助于其再活动,使其参与各种化学反应,例如氧化和减少过程.此外,在降低条件下,可以将脱硫物结合分离出来,这些条件可以在生物化学应用中加以利用.安全数据表明,与许多有机化合物一样,应该谨慎处理,因为如果浸入或吸入,可能会对健康造成危害.
- 英文名称Bis(6-Hydroxy-2-Naphthyl) Disulfide
- 中文名称双(6-羟基-2-萘)二硫
- IUPAC名称2,2'-Dihydroxy-6,6'-dinaphthyl disulfide
- 其它别名2-Naphthol,6,6'-dithiodi- (6CI,7CI,8CI); (6,6'-Dihydroxy-2,2'-dinaphthyl)disulfide; 2,2'-Dihydroxy-6,6'-dinaphthyl disulfide; 6,6'-Dithiodi(2-naphthol); Bis(6-hydroxy-2-naphthyl)disulfide; DDD (analytical)
- CAS编号6088-51-3
- MFCD编号:MFCD00004083
- EINECS号:228-025-4
- FDA UNII编号:Y4YW3C2D2S
- 分子式:C20H14O2S2分子量:350.45
- 产品CID: 1590114
- 产品分类化学试剂 → 有机试剂 → 多环化合物
物理性质
MSDS等安全信息
欧盟法规
ECHA物质C&L通报REACH预注册上下游产品
CAS号125518-82-3 6-[(ethoxycarbo... | CAS号6088-50-2 (6-Oxy-naphthyl...合成工艺路线路线简述
- 合成目标产物 6-Hydroxy-2-Naphthyl Disulfide 主要起始原料 Ethanamine, N-[(3,5-Dichlorophenyl)Methylene]-2,2-Diethoxy-
- (文献来源)合成步骤主要原料 Ethanamine, N-[(3,5-Dichlorophenyl)Methylene]-2,2-Diethoxy-
📜(6-Oxy-Naphthyl-(2))-Mercaptan置于碘体系中,用 甲醇,水 作为反应溶剂,化学反应生成 双(6-羟基-2-萘)二硫
参考文献:Effects Of Oxygen-sulfur Substitution On Glycosaminoglycan-Priming Naphthoxylosides
标题:Effects Of Oxygen-sulfur Substitution On Glycosaminoglycan-Priming Naphthoxylosides
摘要:Three Series Of Sulfur-Containing Analogs To The Selectively Antiproliferative 2-(6-Hydroxynaphthyl) Beta-D-Xylopyranoside Were Synthesized And Their Biological Properties Investigated. A Short,General Route To Hydroxynaphthyl Disulfides From Dihydroxy-Naphthalenes Was Developed To Utilize The Disulfide Bond As A Sulfur-Selective Protecting Group To Enable The Orthogonal Protection Of Hydroxyls And Thiols. The Results Indicate That Hydrophobic,Uncharged Oxygen-Sulfur Substituted Naphthoxylosides Are Taken Up By Calls And Initiate Priming Of Gag Chains To A Greater Extent Compared To The Oxygen Analogs. No Correlation Between Priming Ability And Antiproliferative Activity Was Observed. (C) 2007 Elsevier Ltd. All Rights Reserved.
DOI:10.1016/j.Bmc.2007.05.008
海关参考信息
- 2902902000-精萘
2908199090-其他酚的卤化衍生物
2908999090-其他酚的硝化衍生物
2918290000-其他含酚基羧酸 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:CN-112979908-A
优先权日:2021-02-25
标 题 :A kind of rosin-based self-healing polymer and its synthesis method and application
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
主要参考文献
1: Želježić D, Herceg Romanić S, Klinčić D, Matek Sarić M, Letinić JG. Persistent Organochlorine Pollutants in Placentas Sampled from Women in Croatia and an Evaluation of Their DNA Damaging Potential In Vitro. Arch Environ Contam Toxicol. 2018 Feb;74(2):284-291. doi: 10.1007/s00244-017-0503-9. Epub 2018 Jan 9. doi: 10.1016/j.aca.2017.11.056. Epub 2017 Nov 30. doi: 10.1016/j.chroma.2017.10.018. Epub 2017 Oct 7. doi: 10.1002/bmc.3993. Epub 2017 May 21. doi: 10.1080/19393210.2017.1282988. Epub 2017 Apr 5. eCollection 2016.
8: Pelletier M, El-Fityani T, Graham A, Rutter A, Michelutti N, Zeng DM, Sivarajah B, Smol JP, Hodson PV. Tracking pesticide use in the Saint Lawrence River and its ecological impacts during the World Exposition of 1967 in Montreal, Canada. Sci Total Environ. 2016 Dec 1;572:498-507. doi: 10.1016/j.scitotenv.2016.08.064. Epub 2016 Aug 18. doi: 10.13277/j.hjkx.2016.08.023. Chinese. doi: 10.1530/EDM-15-0135. Epub 2016 Jun 10.
12: Huo F, Tang H, Wu X, Chen D, Zhao T, Liu P, Li L. Utilizing a novel sorbent in the solid phase extraction for simultaneous determination of 15 pesticide residues in green tea by GC/MS. J Chromatogr B Analyt Technol Biomed Life Sci. 2016 Jun 15;1023-1024:44-54. doi: 10.1016/j.jchromb.2016.04.053. Epub 2016 May 4. doi: 10.1007/s10661-015-4889-4. Epub 2015 Oct 11. doi: 10.1186/s13013-015-0040-0. eCollection 2015.
合成参考文献
摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198
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