📜4,4'-二氟苯偶酰置于[双(2-甲氧基乙基)胺]三氟化硫体系中,化学反应 24.0H,以92%的收率获得产物1,2-二(4'-氟代苯基)-1,1,2,2,-四氟乙烷 参考文献:Direct Nucleophilic Fluorination Of Carbonyl Groups Of Benzophenones And Benzils With Deoxofluor 标题:Direct Nucleophilic Fluorination Of Carbonyl Groups Of Benzophenones And Benzils With Deoxofluor 摘要:The Carbonyl Groups Of Diaryl Ketones And Diaryl Diketones Were Directly Fluorinated With Bis(2-Methoxyethyl)Aminosulfur Trifluoride (Deoxofluor) Under Neat Conditions To Give The Corresponding Gem-Difluorides And Tetrafluorinated Derivatives In Moderate To High Yields. (C) 2008 Elsevier Ltd. All Rights Reserved. DOI:10.1016/j.Tet.2008.08.009
专利号:CN-112830862-B 优先权日:2021-01-04 标题 :A new type of fluorine-containing flame retardant, its synthesis method and its application in nylon 6 modification
参考标题:Silver-Catalyzed Decarboxylative Homocoupling Reaction For The Construction Of Tetrafluoroethylene-Bridging Aromatic Compounds 作者:Yong Wang,Huaxin Zhao,Xiaojuan Xie,Haizhen Jiang,Hongmei Deng,Jian Hao,Wen Wan 摘要:Abstract The Ag(I)-Catalyzed Decarboxylative Homocoupling From The Difluoroacetate Has Been Developed To The Synthesis Of Symmetric Cf2-Cf2 Containing Dimers. This Radical Dimerization Overpasses The Prefunctionalization Of The Substrate And Provides A Direct And Efficient Method For Construction Of Tetrafluoroethylene Bridge-Linked Homodimers. Graphical Abstract