CAS: 141607-35-4; (4R,5R)-5-((R)-2-((Tert-Butyldiphenylsilyl)Oxy)-1-Hydroxyethyl)-2,2-Dimethyl-1,3-Dioxolane-4-Carbaldehyde
该化合物是一种属于糖衍生物,即酸糖的衍生物的化学化合物.该化合物具有在2和3个位置受异丙基聚醚组保护的核糖脂糖结构,加强了其在合成应用中的稳定性和再活性.在5个位置上存在三丁基苯乙烯组是一个保护性组,在有机合成中通常用于防止今后步骤的不必要反应.该化合物通常用于碳水化合物化学,特别是核糖和其他生物相关分子的合成中.其独特的结构特征有助于其溶性与再活性,使其在制造更复杂的有机化合物时成为宝贵的中间体.与许多有机蛋化合物一样,它可能表现出特定的物理特性,如熔点,沸点,沸点和受分子结构和子结构影响的溶性.
- 英文名称(4R,5R)-5-((R)-2-((Tert-Butyldiphenylsilyl)Oxy)-1-Hydroxyethyl)-2,2-Dimethyl-1,3-Dioxolane-4-Carbaldehyde
- 中文名称5-O-叔丁基联苯基硅烷-2,3-O-异亚丙基-α,β-D-呋喃核
- IUPAC名称(4R,5R)-5-((R)-2-((tert-butyldiphenylsilyl)oxy)-1-hydroxyethyl)-2,2-dimethyl-1,3-dioxolane-4-carbaldehyde
- 其它别名5-O-TERT-BUTYLDIPHENYLSILYL-2,3-O-ISOPROPYLIDENE-ALPHA,BETA-D-RIBOFURANOSE; 5-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-D-ribofuranose; 5-O-TERT-BUTYLDIPHENYLSILYL-2,3-O-ISOPROPYLIDENE-ALPHA,SS-D-RIBOFURANOSE; 5-O-TERT-BUTYLDIPHENYLSILYL-2,3-O-ISOPROPYLIDENE-A,B-D-RIBOFURANOSE; 5-O-TERT-BUTYLDIPHENYLSILYL-2,3-O-ISOPROPYLIDENE-ALPHA,BETA-; 5-O-tert-Butyldiphenylsilyl-2,3-O-isopropylidene-,β-D-ribofuranose; (3aR,6R,6aR)-6-((tert-butyldimethylsilyloxy)methyl)-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-ol; 5-O-tert-Butyldiphenylsilyl-2,3-O-isopropylidene-alpha,~-D-ribofuranose
- CAS编号141607-35-4
- MFCD编号:MFCD01075719
- 分子式:C24H32O5Si
- 分子量:428.6
- 产品CID: 635398
- 产品分类生物化工 → 糖类化合物 → 单糖
物理性质
MSDS等安全信息
- 警示词warning
- 危险描述H303May be harmful if swallowed+H313Skin contact may be harmful+H333Inhalation may be harmful to the body
- 防范说明P264Thoroughly clean after treatmentP280Wear protective gloves/Wear protective clothing/Wear protective goggles/Wear a protective maskP305If it enters the eyesP351Rinse carefully with water for a few minutesP338Remove the contact lens(If any)And easy to operate,Continue flushingP337If eye irritation persistsP313Obtain medical advice/care
- 安全声明H303May be harmful if swallowed+H313Skin contact may be harmful+H333Inhalation may be harmful to the body
上下游产品
CAS号58479-61-1 叔丁基二苯基氯硅烷 | CAS号13199-25-2 2,3-O-异亚丙基-α,β-... | CAS号50-69-1 核糖合成工艺路线路线简述
海关参考信息
- 2902200000-苯
2905122000-异丙醇
2905310000-1,2-乙二醇
2905320000-1,2-丙二醇 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-9512426-B2
优先权日:2009-12-17
标 题:Method for rapidly evaluating performance of short interfering RNA with novel chemical modifications
发明人：BUTORA GABOR; DAVIES IAN W; FLANAGAN WILLIAM MICHAEL; FU WENLANG; KENSKI DENISE M; QI NING
权利人:SIRNA THERAPEUTICS INC
摘要:It is an object of the instant invention to provide a method for the rapid evaluation of novel sugar modifications to be used in siRNA synthesis including the rapid evaluation of chemical modification patterns within the siRNA to effectuate increased stability and ultimately increased efficacy of a siRNA therapeutic. It is a further object of the instant invention to provide novel nucleosides useful for siRNA therapy.
专利号:WO-03102007-A1
优先权日:2002-06-03
标题:Process for synthesising c-glycosides
发明人：ARMITT DAVID JOHN; BANWELL MARTIN GERHARDT
权利人:UNIV AUSTRALIAN; ARMITT DAVID JOHN; BANWELL MARTIN GERHARDT
摘要:The invention provides a process for the synthesis of C-glycosides. In the process, an O-glycosyl trichloroimidate is reacted with a pyrrole in the presence of a Lewis acid and the C-glycoside isolated from the foregoing reaction mixture. The invention also relates to the products of the process.
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📌 第三方产品分析报告
合成参考文献
参考文献:10.1055/s-0030-1258228
摘要:Werz D, Koester D, Holkenbrink A. Recent Advances in the Synthesis of Carbohydrate Mimetics. Synthesis. 2010 Aug 25;2010(19):3217–42. doi: 10.1055/s-0030-1258228.
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