CAS: 106948-24-7; N-[dimethyl(Prop-2-Enyl)Silyl]-N-Propan-2-Ylpropan-2-Amine

英文名称N-[dimethyl(Prop-2-Enyl)Silyl]-N-Propan-2-Ylpropan-2-Amine
中文名称烯丙基(二异丙基氨基)二甲基硅烷
其它别名Silanamine,1,1-dimethyl-N,N-bis(1-methylethyl)-1-(2-propenyl)- (9CI)
CAS编号106948-24-7
MFCD编号:MFCD00191711
分子式:C11H25NSi分子量:199.41
产品CID: 107986
产品分类化学试剂 → 硅烷试剂

相似结构搜索
产品信息参考;;;
InChIKey: GSTVYECJWYQBKF-UHFFFAOYSA-N
1S/C11H25NSi/c1-8-9-13(6,7)12(10(2)3)11(4)5/h8,10-11H,1,9H2,2-7H3
计算化学: 氢键受体数1.0氢键供体数*可旋转键数5.0

MSDS等安全信息

危险品标志Xi
安全声明26-36/37/39-36/37
危险类别码36/37/38

上下游产品

(diisopropylamino)(chloro)dimethylsilane allylmagnesium bromide diisopropylamine [((E)-3-Cyclohexyl-propenyl)-dimethyl-silanyl]-diisopropyl-amine {Dimethyl-[(R)-1-((S)-phenyl-trimethylsilanyloxy-methyl)-allyl]-silanyl}-diisopropyl-amine (1S,2R)-1-phenylbut-3-ene-1,2-diol (1R,2S)-1-phenyl-3-butene-1,2-diol

合成工艺路线路线简述

📜二异丙胺以乙醚用作溶剂,化学反应生成烯丙基(二异丙基氨基)二甲基硅烷
参考文献:Silafunctional Compounds In Organic Synthesis. 33. Metalated Allylaminosilane: A New,Practical Reagent For The Stereoselective .Alpha.-Hydroxyallylation Of Aldehydes To Erythro-1,2-Diol Skeletons
标题:Silafunctional Compounds In Organic Synthesis. 33. Metalated Allylaminosilane: A New,Practical Reagent For The Stereoselective .Alpha.-Hydroxyallylation Of Aldehydes To Erythro-1,2-Diol Skeletons
摘要:
Doi:10.1021/jo00381A053

专利信息

专利号:US-11767388-B1
优先权日:2019-09-18
标题 :Silicon-functionalized rubber
发明人：ENSIGN SETH CODY; VIELHABER MARGARET FLOOK; JOHNGRASS JENA LYNN; MA LIQING
权利人:GOODYEAR TIRE & RUBBER
摘要:The compatibility between silica fillers and synthetic rubbers which are synthesized utilizing lanthanide-based catalyst systems, such as neodymium catalyst systems can be improved by terminating the polymerization with a vinyl silane terminating agent. In doing so the vinyl silane is allowed to react with the polymer chain ends of the neodymium rubber to functionalize the chain ends of the polymer chains with silicon containing groups. This results in the rubber having better characteristics for utilization in tire rubber formulations, such a tire tread formulations, that exhibit improved wear characteristics and lower rolling resistance. The process for the synthesis of such functionalized polydiene rubber comprises (1) polymerizing a diene monomer in the presence of a lanthanide-based catalyst system, and (2) terminating the polymerization with a vinyl silane terminator. The functionalized polydiene rubber composition made by this method is comprised of a polydiene rubber which is functionalized at its chain ends with a silicon containing group.