CAS: 945-51-7; Sulfinyldibenzene

• 英文名称Sulfinyldibenzene
• 中文名称二苯基亚砜
• IUPAC名称sulfinyldibenzene
• 其它别名二苯亚砜; 苯基亚砜; Phenyl Sulphoxide
• CAS编号945-51-7
• MFCD编号:MFCD00002085
• EINECS号:213-415-9
• FDA UNII编号:4V290005U9
• 分子式:C12H10OS
• 分子量:202.28
• 产品CID: 1997000
• 产品分类有机原料→分子砌块→芳环类化合物→苯类化合物

• 相似结构搜索
• 产品信息参考
• InChIKey: JJHHIJFTHRNPIK-UHFFFAOYSA-N
• InChI=1S/C12H10OS/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H…
• 计算化学: 氢键受体数1.0氢键供体数0.0可旋转键数2.0

物理性质

• 熔点69-71°C
• 沸点357.6°C at 760 mmHg
• 闪点206-208°C/13mm
• 密度1.1833 (粗估)
• PSA:17.07
• LogP:2.8533
• 折射率1.6090 (估算)
• 蒸汽压5.55E-05 mmHg at 25 °C
• 溶解性Chloroform (Slightly), DMSO (Slightly)
• 外观形态白色至类白色结晶粉末
• 储存条件密封, 常温干燥保存
• 产品应用农药中间体,用于生产阳离子光引发剂,铀(Ⅵ)萃取剂等.
• 性质描述白色晶体,沸点206-208°C,熔点66-71°C

MSDS等安全信息

• GHS符号GHS07
• 危险类别特定目标器官毒性 - 单次接触 类别3
  皮肤腐蚀/刺激 类别2
  严重眼刺激 类别2A
• 警示词Warning
• 危险描述H335 |可能引起呼吸道刺激.
  H315 |造成皮肤刺激.
  H319 |造成严重眼刺激.
• 防范说明P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
• UN编号NONH for all modes of transport
• 危险品标志Xi
• 风险等级Irritant
• 安全声明22-24/25
• 危险类别码Intraperitoneal LD50 (mouse) = 750 mg/kg; [RTECS] May cause irritation; [Alfa Aesar MSDS] See Dimethyl sulfoxide.
• WGK Germany3

欧盟法规

上下游产品

合成工艺路线路线简述

• 合成目标产物 Phenyl Sulfoxide 主要起始原料 Diphenyl Sulfide
• 100-68-5 = 945-51-7
  反应条件:1.1 Catalysts: Glucose Dehydrogenase,Cyclohexanone Monooxygenase Solvents: Methanol,Water; 8.5 H,30 °C
  标题:Cyclohexanone Monooxygenase And Its Application In The Catalysis Of Thioether
  参考文献:China]
  
  139-66-2 = 945-51-7
  反应条件:1.1 Reagents: Hydrogen Peroxide Catalysts: Cerium Molybdenum Oxide Solvents: Ethanol; 30 Min,20 °C
  标题:Scaled-Up,Selective And Green Synthesis Of Sulfoxides Under Mild Conditions Using (Ceiii-Movi)Ox/aniline Hybrid Rods As An Efficient Catalyst
  作者:Feghhi,Aliyeh; Malakooti,Reihaneh; Malakooti,Sadeq
  参考文献:Applied Organometallic Chemistry 日期:2019 卷标:33(12)]
  
  139-66-2 = 945-51-7
  反应条件:1.1 Reagents: Hydrogen Peroxide Catalysts: N,N-Bis[(3,5-Dichloro-2-Hydroxyphenyl)Methyl]Glycine (Reaction Products With Functionalized Graphene Oxide,Iron Complex) Solvents: Water; 7 H,Rt
  标题:Selective And Green Oxidation Of Sulfides In Water Using A New Iron(Iii) Bis(Phenol) Amine Complex Supported On Functionalized Graphene Oxide
  作者:Aghajani,Milad; Safaei,Elham; Karimi,Babak
  参考文献:Synthetic Metals 日期:2017 卷标:233 页码:63-73]
  
  139-66-2 = 945-51-7
  反应条件:1.1 Reagents: Hydrogen Peroxide Catalysts: Copper,[[4,4′-[(1-Methyl-1,2-Ethanediyl)Bis[(Nitrilo-Kn)Ethylidyne]]Bis[1,3-Ben... Solvents: Ethanol; 20 Min,25 °C
  标题:Catalytic Activity And Electrochemical Properties Of Cu(Ii)-Schiff Base Complex Encapsulated In The Nanocavities Of Zeolite-Y For Oxidation Of Olefins And Sulfides
  作者:Rayati,Saeed; Khodaei,Elham; Jafarian,Majid
  参考文献:Journal Of Coordination Chemistry 日期:2017 卷标:70(15) 页码:2736-2750]
  
  139-66-2 = 945-51-7
  反应条件:1.1 Reagents: Acetic Anhydride,Carbamide Peroxide Catalysts: Imidazole,Iron Oxide (Fe3O4),Silica,2102606-38-0 Solvents: Ethanol; 5 Min,Rt
  标题:Mn-Schiff Base Complex Supported On Magnetic Nanoparticles: Synthesis,Crystal Structure,Electrochemical Properties And Catalytic Activities For Oxidation Of Olefins And Sulfides
  作者:Rayati,Saeed; Khodaei,Elham; Jafarian,Majid; Wojtczak,Andrzej
  参考文献:Polyhedron 日期:2017 卷标:133 页码:327-335]
  
  139-66-2 = 945-51-7
  反应条件:1.1 Reagents: Carbamide Peroxide,Oxygen Catalysts: (Pb-7-35-11264)-[(Benzoic Acid-Ko) 2-[[2-(Hydroxy-Ko)Phenyl]Methylene]Hydrazidat... Solvents: Methanol,Dichloromethane; 35.25 Min,Rt
  标题:Catalytic Efficacy Of An Oxido-Peroxido Tungsten(Vi) Complex: Synthesis,X-Ray Structure And Oxidation Of Sulfides And Olefins
  作者:Amini,Mojtaba; Bagherzadeh,Mojtaba; Eftekhari-Sis,Bagher; Ellern,Arkady; Keith Woo,L.
  参考文献:Journal Of Coordination Chemistry 日期:2013 卷标:66(11) 页码:1897-1905]
  
  139-66-2 = 945-51-7
  反应条件:1.1 Reagents: Hydrogen Peroxide Catalysts: Molybdate(3-),Tetracosa-μ-Oxododecaoxo[μ12-[phosphato(3-)-Ko:Ko:Ko:Ko′:Ko′:Ko′:... Solvents: Decane,2,2,4-Trimethylpentane,Water; 60 Min,Rt
  标题:Multiphase Oxidation Of Alcohols And Sulfides With Hydrogen Peroxide Catalyzed By Heteropolyacids
  作者:Tundo,Pietro; Romanelli,Gustavo P.; Vazquez,Patricia G.; Arico,Fabio
  参考文献:Catalysis Communications 日期:2010 卷标:11(15) 页码:1181-1184]
  
  139-66-2 = 945-51-7
  反应条件:1.1 Reagents: Hydrogen Peroxide Catalysts: 2-[3-(Triethoxysilyl)Propyl]-1,2-Benzisoselenazol-3(2H)-One (Silica Supported) Solvents: Methanol,Water; 2 H,Rt
  标题:New Recoverable Organoselenium Catalyst For Hydroperoxide Oxidation Of Organic Substrates
  作者:Wojtowicz,Halina; Soroko,Grazyna; Mlochowski,Jacek
  参考文献:Synthetic Communications 日期:2008 卷标:38(12) 页码:2000-2010]
  
  139-66-2 = 945-51-7
  反应条件:1.1 Reagents: Hydrogen Peroxide Catalysts: (Sp-5-42)-[n-[[3-Ethoxy-2-(Hydroxy-Ko)Phenyl]Methylene]-3-Pyridinecarbohydrazonn... Solvents: Ethanol,Water; 15 Min,Reflux
  标题:Oxovanadium And Dioxomolybdenum Complexes: Synthesis,Crystal Structure,Spectroscopic Characterization And Applications As Homogeneous Catalysts In Sulfoxidation
  作者:Kargar,Hadi; Kaka-Naeini,Azar; Fallah-Mehrjardi,Mehdi; Behjatmanesh-Ardakani,Reza; Amiri Rudbari,Hadi; Et Al
  参考文献:Journal Of Coordination Chemistry 日期:2021 卷标:74(9-10) 页码:1563-1583]
  
  139-66-2 = 945-51-7
  反应条件:1.1 Reagents: Tert-Butyl Hydroperoxide Catalysts: (Pb-7-23-111′1′2)-Diaquaoxodiperoxymolybdenum Solvents: 1-Butyl-3-Methylimidazolium Hexafluorophosphate; 1 H,20 °C
  标题:Experimental And Theoretical Insights Into The Oxodiperoxomolybdenum-Catalysed Sulphide Oxidation Using Hydrogen Peroxide In Ionic Liquids
  作者:Carrasco,Carlos J.; Montilla,Francisco; Alvarez,Eleuterio; Mealli,Carlo; Manca,Gabriele; Et Al
  参考文献:Dalton Transactions 日期:2014 卷标:43(36) 页码:13711-13730]
  
  139-66-2 = 945-51-7
  反应条件:1.1 Reagents: Hydrogen Peroxide Catalysts: Molybdate(5-),(Hydroxyaluminate)Tetracosa-μ-Oxoundecaoxo[μ12-[phosphato(3-)-Ko:... Solvents: Acetonitrile; 2 H,Reflux
  标题:A Highly Efficient,Green,Rapid,And Chemoselective Oxidation Of Sulfides Using Hydrogen Peroxide And Boric Acid As The Catalyst Under Solvent-Free Conditions
  作者:Rostami,Amin; Akradi,Jamal
  参考文献:Tetrahedron Letters 日期:2010 卷标:51(27) 页码:3501-3503]
  
  139-66-2 = 945-51-7
  反应条件:1.1 Reagents: Hydrogen Peroxide Catalysts: (Sp-5-13)-(Acetato-Ko)[2,7,12,17-Tetraphenyl-4-Oxa-21,22,23,24-Tetraazapentacycl... Solvents: Methanol,Water; 3 H,Rt
  标题:First Catalytic Application Of Metal Complexes Of Porpholactone And Dihydroxychlorin In The Sulfoxidation Reaction
  作者:Rahimi,Rahmatollah; Tehrani,Alireza Azhdari; Fard,Mahmood Azizpoor; Sadegh,Bahareh Mir Mohammad; Khavasi,Hamid Reza
  参考文献:Catalysis Communications 日期:2009 卷标:11(4) 页码:232-235]
  
  139-66-2 = 945-51-7
  反应条件:1.1 Reagents: Hydrogen Peroxide Catalysts: Imidazole,2420390-02-7 (Silica-Coated Iron Magnetic Nanoparticle Supported) Solvents: Ethanol; 90 S,Rt
  标题:A Manganese(Iii) Schiff Base Complex Immobilized On Silica-Coated Magnetic Nanoparticles Showing Enhanced Electrochemical Catalytic Performance Toward Sulfide And Alkene Oxidation
  作者:Rayati,Saeed; Khodaei,Elham; Nafarieh,Parinaz; Jafarian,Majid; Elmi,Bahareh; Et Al
  参考文献:Rsc Advances 日期:2020 卷标:10(29) 页码:17026-17036]
  
  139-66-2 = 945-51-7
  反应条件:1.1 Reagents: Hydrogen Peroxide Catalysts: 2144448-05-3 Solvents: Ethanol,Water; 8 H,Rt
  标题:Encapsulated Phosphomolybdic Acid In Tmu-16 Metal Organic Framework: Study The Catalytic Activity And Structural Stability Dependent On Synthetic Solvent
  作者:Saedi,Zahra; Yaghma,Mihan; Morsali,Ali; Roushani,Mahmoud
  参考文献:Inorganic Chemistry Communications 日期:2017 卷标:86 页码:159-164]
  
  139-66-2 = 945-51-7
  反应条件:1.1 Reagents: Hydrogen Peroxide Catalysts: Vanadium,[[2,2′-[(2,2-Dimethyl-1,3-Propanediyl)Bis[(Nitrilo-Kn)Methylidyne]]Bis... Solvents: Ethanol; 10 Min,25 °C
  标题:Ni(Ii) And V(Iv) Schiff Base Complexes Derived From 2,2'-Dimethylpropandiamine: The Crystal Structure,Electrochemical Properties And Catalytic Activities In Oxidation Of Sulfides
  作者:Rayati,Saeed; Khodaei,Elham; Jafarian,Majid; Bahrami,Arezo; Wojtczak,Andrzej; Et Al
  参考文献:Journal Of Coordination Chemistry 日期:2017 卷标:70(8) 页码:1424-1437]
  
  139-66-2 = 945-51-7
  反应条件:1.1 Reagents: Carbamide Peroxide Catalysts: (Oc-6-34)-(Ethanol)[(2-Hydroxybenzoic Acid-Ko) 2-[[2-(Hydroxy-Ko)-1-Naphthalenyl... Solvents: Methanol,Dichloromethane; Rt
  标题:New Molybdenum(Vi) Catalyst For The Epoxidation Of Alkenes And Oxidation Of Sulfides: An Experimental And Theoretical Study
  作者:Bagherzadeh,Mojtaba; Haghdoost,Mohammad Mehdi; Ghanbarpour,Alireza; Amini,Mojtaba; Khavasi,Hamid Reza; Et Al
  参考文献:Inorganica Chimica Acta 日期:2014 卷标:411 页码:61-66]
  
  139-66-2 = 945-51-7
  反应条件:1.1 Reagents: Carbamide Peroxide Catalysts: 12-Molybdophosphoric Acid Solvents: Methanol; 3 H,Rt
  标题:Molybdatophosphoric Acid As An Efficient Catalyst For The Catalytic And Chemoselective Oxidation Of Sulfides To Sulfoxides Using Urea Hydrogen Peroxide As A Commercially Available Oxidant
  作者:Hasaninejad,Alireza; Ali Zolfigol,Mohammad; Chehardoli,Gholamabbas; Mokhlesi,Mohammad
  参考文献:Journal Of The Serbian Chemical Society 日期:2010 卷标:75(3) 页码:307-316]
  
  139-66-2 = 945-51-7
  反应条件:1.1 Catalysts: 12-Tungstophosphoric Acid,1-Undecanaminium,11-Hydroxy-N-(11-Hydroxyundecyl)-N,N-Dimethyl-,Bromide (1:1) Solvents: Water; 30 Min,Rt1.2 Catalysts: Tetraethoxysilane Solvents: Ethanol,Water; 2 W,Rt1.3 Reagents: Hydrogen Peroxide Solvents: Acetonitrile,Water; Rt -> 40 °C; 90 Min,40 °C
  标题:Surfactant-Encapsulated Polyoxometalates As Immobilized Supramolecular Catalysts For Highly Efficient And Selective Oxidation Reactions
  作者:Qi,Wei; Wang,Yizhan; Li,Wen; Wu,Lixin
  参考文献:Chemistry - A European Journal 日期:2010 卷标:16(3) 页码:1068-1078]
  
  139-66-2 = 945-51-7
  反应条件:1.1 Reagents: Oxygen Catalysts: Ceric Ammonium Nitrate (Clay-Supported) Solvents: Methanol; 2 H,Rt
  标题:Clay-Supported Ceric Ammonium Nitrate As An Effective,Viable Catalyst In The Oxidation Of Olefins,Chalcones And Sulfides By Molecular Oxygen
  作者:Dhakshinamoorthy,Amarajothi; Pitchumani,Kasi
  参考文献:Catalysis Communications 日期:2009 卷标:10(6) 页码:872-878]
  
  139-66-2 = 945-51-7
  反应条件:1.1 Reagents: Hydrogen Peroxide Solvents: Water; 30 Min,Rt
  标题:Selective Oxidation Of Sulfides With H2O2 Catalyzed By Silica-Tungstate Core-Shell Nanoparticles
  作者:Sreedhar,B.; Radhika,P.; Neelima,B.; Hebalkar,Neha; Mishra,A. K.
  参考文献:Catalysis Communications 日期:2008 卷标:10(1) 页码:39-44

海关参考信息

• 2902200000-苯
  2930909099-其他有机硫化合物
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• 详情请参考：📖 海关编码查询和海关进出口税则

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• ➥ 象形图和危险代码
• ➥ 防范代码详解
• ➥ 危险代码说明
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