CAS: 937-34-8; Phenyl Hydrogen Sulfate

该化合物是一种有机化合物,其特征是附于一个酚状结构的硫酸盐组的存在,它一般视其特定形式和浓度而呈现为无色的黄色黄色液体或固体,以其在水中的溶解性闻名,受极硫酸盐组的影响,使其在各种化学应用中有用.硫酸盐经常用于其他化学化合物的合成中,并可作为有机反应的中间体.由于硫酸盐组的存在,它具有酸性,可以参与各种化学反应,包括核生殖器替代.此外,硫酸盐可以参与生物过程,特别是活生物生物体中苯酚化合物的代谢性.在处理该物质时,应当采取安全防范措施,因为它可能对接触时的健康造成危害.

结构式图片

MSDS等安全信息

    上下游产品

    phenylchlorosulfate sodium phenoxide phenol 2-carboxyphenyl phenyl sulphatephenol sodium phenoxide

    合成工艺路线路线简述

    • 653605-14-2 = 937-34-8 [标题:Reaction Conditions
      标题:Product Class 7: Aryl Hypohalites,Aryl Peroxides,And Aryloxy Sulfur Compounds
      作者:Chen,J.; Chiu,C. K.-F.
      参考文献:Science Of Synthesis 日期:2007 卷标:31 页码:665-704]

      = 937-34-8
      反应条件:1.1 Reagents: Triethylamine Solvents: Dichloromethane; Cooled1.2 Reagents: Chlorosulfonic Acid; Cooled; 2 H,Rt
      标题:Assessment Of Uremic Toxins In Advanced Chronic Kidney Disease Patients On Maintenance Hemodialysis By Lc-Esi-Ms/ms
      作者:Ragi,Nagarjunachary; Pallerla,Pavankumar; Babi Reddy Gari,Aravind Reddy; Lingampelly,Sai Sachin; Ketavarapu,Vijayasarathy; Et Al
      参考文献:Metabolomics 日期:2023 卷标:19(3)]

      = 937-34-8
      反应条件:1.1 Reagents: Sulfuric Acid Solvents: Xylene; 2 H,Reflux; 3 H,Reflux1.2 Reflux
      标题:Polycondensation Product Containing Phosphate Or Sulfate Derivative Of Phenol And Aldehyde For Dispersant And Hydraulic Composition
      参考文献:Japan]

      = 937-34-8
      反应条件:1.1 Reagents: Sulfur Trioxide Solvents: Nitromethane; -35 °C
      标题:Sulfur Trioxide
      作者:Cerfontain,Hans; Bakker,Bert H.
      参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001 卷标:1 页码:1-4]

      = 937-34-8
      反应条件:1.1 Reagents: Chlorosulfonic Acid Solvents: Carbon Disulfide,N,N-Diethylaniline
      标题:Arylsulfuric Acids
      作者:Burehardt,George Norman; Lapworth,Arthur; Ashworth,Frank
      参考文献:Journal Of The Chemical Society 日期:1926 卷标:684 页码:684-90]

      = 937-34-8
      反应条件:1.1 Reagents: Sulfur Trioxide
      标题:Aromatic Sulfonation. 90. Sulfonation Of Three Symmetrical 2,6-Dialkylphenols,2,6-Dimethylanisole. Sulfation And Sulfonation Product Distributions And Mechanisms
      作者:Cerfontain,Hans; Koeberg-Telder,Ankie; Lambrechts,Hans J. A.; De Wit,Peter
      参考文献:Journal Of Organic Chemistry 日期:1984 卷标:49(25) 页码:4917-23]

      = 937-34-8
      反应条件:1.1 Reagents: Chlorosulfonic Acid Solvents: Dichloromethane,Pyridine; 0 °C; 0 °C -> Rt; 24 - 72 H,Rt1.2 Reagents: Potassium Carbonate Solvents: Water
      标题:Transition-State Interactions In A Promiscuous Enzyme: Sulfate And Phosphate Monoester Hydrolysis By Pseudomonas Aeruginosa Arylsulfatase
      作者:Van Loo,Bert; Berry,Ryan; Boonyuen,Usa; Mohamed,Mark F.; Golicnik,Marko; Et Al
      参考文献:Biochemistry 日期:2019 卷标:58(10) 页码:1363-1378]

      = 937-34-8 [标题:Reaction Conditions
      标题:Aromatic Sulfonation. 114. Sulfonation Of Anisole,Phenol,Toluene And Related Alkyl And Alkoxy Derivatives With Sulfur Trioxide. The Influence Of The Solvent System On The Reactivity And The Sulfonic Acid Product Distribution
      作者:Ansink,Harold R. W.; Cerfontain,Hans
      参考文献:Recueil Des Travaux Chimiques Des Pays-Bas 日期:1992 卷标:111(4) 页码:183-7]

      = 937-34-8 [标题:Reaction Conditions
      标题:Aromatic Sulfonation. 102. Sulfonation And Sulfation In Reactions Of C-Methylated Phenols And Anisoles With Sulfur Trioxide. 4-Substituted Phenyl Hydrogen Sulfates: Effective Reagents For Transsulfonation
      作者:Goossens,Hans D.; Lambrechts,Hans J. A.; Cerfontain,Hans; De Wit,Peter
      参考文献:Recueil Des Travaux Chimiques Des Pays-Bas 日期:1988 卷标:107(6) 页码:426-30
    📜Sodium Phenoxide置于1,4-二氧六环,三氧化硫,1,2-二氯乙烷体系中,化学反应生成 硫酸苯酯
    参考文献:Creep Behavior Of In Situ Dual-Scale Particles-Tib Whisker And Tic Particulate-Reinforced Titanium Composites
    标题:Creep Behavior Of In Situ Dual-Scale Particles-Tib Whisker And Tic Particulate-Reinforced Titanium Composites
    摘要:采用反应热压技术,从 B4C-Ti 体系中制造出了由原位双尺度颗粒,高谱比 Tib 晶须和细 Tic 颗粒增强的钛复合材料.这种复合材料的应力指数为 4.5-4.6,蠕变活化能为 298 Kj/mol.相比之下,未增强的钛的应力指数为 5.2-5.3,蠕变活化能为 259 Kj/mol.在所研究的蠕变速率下,复合钛和未增强钛的应力指数均未随蠕变速率的变化而变化.复合材料的抗蠕变性比未增强钛高出一个数量级以上.载荷传递机制是造成这一结果的原因.复合材料和未增强钛的蠕变都是由钛基体中的晶格扩散控制的.
    DOI:10.1557/jmr.2002.0338

    海关参考信息

    • 2904100000-仅含磺基的衍生物及其盐和乙酯
      2908199090-其他酚的卤化衍生物
      2908999090-其他酚的硝化衍生物
      2918290000-其他含酚基羧酸
    • 💡 提示:海关信息按照顺序优先匹配,如需确认的海关信息,请参考相关资料。
    • 详情请参考:📖 海关编码查询和海关进出口税则

    专利信息


    专利号:US-5714587-A
    优先权日:1993-03-31
    标 题 :Synthesis of anti-inflammatory compounds, and novel trisaccharides useful in the synthesis of anti-inflammatory compounds
    发明人:LAINE ROGER A
    权利人:UNIV LOUISIANA STATE; AGRICULTURAL AND MECHANICAL CO
    摘要:Anti-inflammatory compounds are useful, for example, in treating arthritis and heart attack patients. Novel oligosaccharides useful in the rapid synthesis of certain anti-inflammatory compounds are disclosed, as is a rapid method of synthesizing the oligosaccharides. Low pH can loosen the acceptor specificity of galactosyltransferase (lactose synthase: EC 2.4.1.22), allowing the rapid synthesis of novel oligosaccharides. The disaccharides cellobiose (β1→4), laminaribiose (β1→3), gentiobiose (β1→6) and maltose (α1→4) acted as acceptors for lactose synthase under low pH conditions. From these four acceptors, the following four novel trisaccharides were synthesized: Gal p (β1→4)Glc p (β1→3) -Glc, Gal p (β1→4)Glc p (β1→4)-Glc, Gal p (β1→4)Glc p (β1→6)-Glc and Gal p (β1→4)Glc p (α1→4)Glc. These trisaccharides, and other oligosaccharides, may be synthesized in a few days with the disclosed technique, as opposed to the several months which would likely have been required with more traditional organic synthetic methods. These trisaccharides may be used as intermediates in the rapid synthesis of anti-inflammatory compounds.

    专利号:WO-2009033269-A1
    优先权日:2007-09-11
    标 题 :Novel polysaccharide immunogens from alloiococcus otitidis and synthesis of a glycoconjugate vaccine thereof
    发明人:MONTEIRO MARIO ARTUR; ARAR SARIF; HARIMAYA ATSUSHI
    权利人:UNIV GUELPH; MONTEIRO MARIO ARTUR; ARAR SARIF; HARIMAYA ATSUSHI
    摘要:The application relates to Alloiococcus otitidis cell surface polysaccharides, compositions comprising Alloiococcus otitidis cell surface polysaccharides, synthesis of a glycoconjugate vaccine and includes kits, methods and uses thereof.

    专利号:US-12054508-B1
    优先权日:2019-04-16
    标 题 :Compositions and methods for sulfation of carbohydrates and peptides via electron-deficient aryl sulfate diesters
    发明人:NIU JIA; LIU CHAO; YANG CANGJIE
    权利人:THE TRUSTEES OF BOSTON COLLEGE
    摘要:In one aspect, the disclosure relates to a facile strategy to introduce electron-deficient aryl sulfate diesters to silylated hydroxyl groups of carbohydrates and amino acids, among other substrates, wherein selective hydrolysis and the removal of an electron-deficient aromatic group allows for the efficient generation of sulfated carbohydrates, peptides, and other compounds. The incorporation of electron-deficient aryl sulfate diesters in the early stage of the synthesis of glycans, peptides, and the like, disclosed herein avoids time-consuming protecting group manipulations, simplifies the purification of sulfated products, and improves the overall yield and efficiency. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.

    专利号:US-8420607-B2
    优先权日:2006-06-30
    标 题 :Anthrax carbohydrates, synthesis and uses thereof
    发明人:CARLSON RUSSELL W; BOONS GEERT-JAN; QUINN CONRAD; VASAN MAHALAKSHMI; WOLFERT MARGREET A; BUSKAS THERESE; CHOUDHURY BISWA; KANNENBERG ELMAR; LEOFF CHRISTINE; MEHTA ALOK; SAILE ELKE; RAUVOLFOVA JANA; WILKINS PATRICIA
    权利人:CARLSON RUSSELL W; BOONS GEERT-JAN; QUINN CONRAD; VASAN MAHALAKSHMI; WOLFERT MARGREET A; CHOUDHURY BISWA; KANNENBERG ELMAR; LEOFF CHRISTINE; MEHTA ALOK; SAILE ELKE; RAUVOLFOVA JANA; WILKINS PATRICIA; HARVEY ALEX J; UNIV GEORGIA; US HEALTH
    摘要:The present invention presents the isolation, characterization and synthesis of oligosaccharides of Bacillus anthracis . Also presented are antibodies that bind to such saccharide moieties and various methods of use for such saccharide moieties and antibodies.

    专利号:US-12319712-B2
    优先权日:2018-05-09
    标 题:Methods of synthesizing a polynucleotide array using photoactivated agents
    发明人:RAJASEKARAN JOHN J; JAYARAMAN VASANTH; VENUGOPAL ANIRUDH; BEI KANG; WANG TIANHAO; KRISHNA KARTHIK; KRISHNAMURTHY HARI KRISHNAN
    权利人:VIBRANT HOLDINGS LLC
    摘要:Described herein are methods for the synthesis of DNA polynucleotides and polynucleotides, as well as methods for their deprotection and methods for the use of said compounds and compositions comprising said compounds. In particular, such compounds and compositions comprising them are used in methods for light-directed synthesis of DNA microarrays.

    专利号:US-5807943-A
    优先权日:1995-05-22
    标 题 :Synthesis of glycopolymers
    发明人:LEE YUAN-CHUAN; FAN JIAN-QIANG
    权利人:UNIV JOHNS HOPKINS
    摘要:Neoglycoconjugates and new intermediates for the synthesis thereof are synthesized by use of Endo-β-N-acetylglucosaminidase from Arthrobacter protophormiae (Endo-A) in a medium containing an organic solvent.

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.4268/cjcmm20110705
    摘要:Lv J, Chen H, Duan J, Yan H, Tang Y, Song B. [Influence of different processing methods on Angelica sinensis polysaccharides from same origin]. Zhongguo Zhong Yao Za Zhi. 2011 Apr;36(7):846–9.
    参考文献:10.4061/2011/258479
    摘要:Jolly A, Colavecchia SB, Fernández B, Fernández E, Mundo SL. Antibodies Induced by Lipoarabinomannan in Bovines: Characterization and Effects on the Interaction betweenMycobacterium aviumSubsp.paratuberculosisand MacrophagesIn Vitro. Veterinary Medicine International. 2011;2011():1–8. doi: 10.4061/2011/258479.
    📝 需求与反馈
    尽可能描述清楚需求与问题信息
    ×

    通知