CAS: 867-36-7; Dichlorodipropylstannane

该化合物是一种有机锡化合物,其分子式为C6H14Cl2Sn,主要用作有机合成和催化的中间体,其主要优点包括由于锡-碳联系的稳定性,在交叉反应中具有高度的回反应性,如静态联结;该化合物显示出选择性的回反应性,使其对在制药和农用化学中构建复杂的分子框架具有价值;其丙基化合物组增加了有机溶剂中的溶性,促进了同质反应条件;二氯二丙基锡还被用于聚合物稳定,并成为其他有机锡衍生物的前体;妥善处理由于其湿度敏感度和潜在毒性而必不可少.

结构式图片

上下游产品

tetrapropylstannane thionyl chloridedi-n-propylstannane Di-n-propyl-Zinn(IV)-difluorid dipropyl-tin dibromide 3CH2CH2)2SnCl2((C6H5)3PO)}{(CH3CH2CH2)2SnCl2((C6H5)3PO)}

合成工艺路线路线简述

  • 2176-98-9 = 867-36-7
    反应条件:1.1 Reagents: Thionyl Chloride
    标题:Reactions Of Thionyl Chloride With Tetraorganotin(Iv) Compounds
    作者:Narula,Suraj P.; Et Al
    参考文献:Indian Journal Of Chemistry 日期:1983 卷标:(3) 页码:246-7]

    2176-98-9 = 867-36-7
    反应条件:1.1 Reagents: Tin Tetrachloride; 2 H,Rt -> 100 °C; 4 H,100 °C -> 220 °C
    标题:Synthesis And Characterization Of Linear Poly(Dialkylstannane)S
    作者:Choffat,Fabien; Et Al
    参考文献:Macromolecules (Washington 日期:2007 卷标:40(22) 页码:7878-7889]

    927-77-5 = 867-36-7
    反应条件:1.1 Reagents: Tin Tetrachloride Solvents: Diethyl Ether,Hexane; 1 H,Cooled; 2 H,Reflux1.2 Solvents: Toluene; 1 H,90 °C1.3 Reagents: Hydrochloric Acid Solvents: Water; Cooled2.1 Reagents: Tin Tetrachloride; 2 H,Rt -> 100 °C; 4 H,100 °C -> 220 °C
    标题:Synthesis And Characterization Of Linear Poly(Dialkylstannane)S
    作者:Choffat,Fabien; Et Al
    参考文献:Macromolecules (Washington 日期:2007 卷标:40(22) 页码:7878-7889
📜四丙基锡置于四氯化碳体系中,用45%的收率获得产物二正丙基二氯锡
参考文献:Razuvaev,G. A.; Vyazankin,N. S.; Gladyshev,E. N.,Zhurnal Obshchei Khimii,1962,Vol. 32,P. 2154-2160
标题:Razuvaev,G. A.; Vyazankin,N. S.; Gladyshev,E. N.,Zhurnal Obshchei Khimii,1962,Vol. 32,P. 2154-2160

海关参考信息

专利信息


专利号:US-2024383928-A1
优先权日:2021-07-30
标 题:Production of diorganotin dihalides
发明人:VINCENT ROBERT; ZIMMERMANN JARROD C
权利人:MERCK PATENT GMBH
摘要:The disclosed and claimed subject matter relates to the safe and efficient synthesis of diorganotin dihalide compounds of the formula R2SnX2 that as-synthesized are free of tetraalkyltin (R4Sn), trialkyltin halide (R3SnX) and monoalkyltin trihalide (RSnX3) species and of methods for their synthesis and use.

专利号:US-8329923-B2
优先权日:2010-06-17
标 题:4, 4′ disubstituted 4H-cyclopentadithiophene and new methods for synthesizing the same
发明人:VANDERZANDE DIRK; LUTSEN LAURENCE; VAN MIERLOO SARAH
权利人:VANDERZANDE DIRK; LUTSEN LAURENCE; VAN MIERLOO SARAH; IMEC; UNIV HASSELT
摘要:The present preferred embodiments relate to a method for the synthesis of a compound having the following general formula: n nthe method comprising the step of reacting, in presence of a diprotic acid having a negative pKa, a compound having the general formula:n n nwherein R 1 and R 2 are organic groups and wherein X and Y are independently selected from the group consisting of hydrogen, chloro, bromo, iodo, boronic acid, boronate esters, borane, pseudohalogen and organotin. It further relates to compounds so obtained and to compounds resulting from the ring closure of compound (II).

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✅ COA系统入驻 | 共享模式

合成参考文献


摘要:Schafer, E. W., Jr., and W. A. Bowles Jr. 1985. Acute oral toxicity and repellency of 933 chemicals to house and deer mice. Archives of Environmental Contamination and Toxicology 14:111-129. https://www.aphis.usda.gov/ws/nwrc/chem-effects-db/S_schafer851.pdf
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