CAS: 589-91-3; 4-Methylcyclohexanol

相似化合物

7731-28-4 7731-29-5 589-92-4

上下游产品

CAS号106-44-5 对甲酚 | CAS号589-92-4 4-甲基环己酮 | CAS号82166-21-0 2-methyl cyclohexane | CAS号498-00-0 香草醇 | CAS号93-51-6 2-甲氧基-4-甲基苯酚 | CAS号29648-66-6 4-亚甲基环己酮 | CAS号1579-40-4 对二甲苯基醚 | CAS号688-73-3 三正丁基氢化锡 | CAS号612069-15-5 1-(2,4-dimethyl... | CAS号98-85-1 苏合香醇 | CAS号589-92-4 4-甲基环己酮 | CAS号591-49-1 1-甲基-1-环己烯 | CAS号591-48-0 3-甲基-1-环己烯 | CAS号591-47-9 4-甲基-1-环己烯 | CAS号7732-18-5 水 | CAS号7731-29-5 trans-4-甲基环己醇 | CAS号3058-01-3 3-甲基己二酸 | CAS号87-83-2 2,3,4,5,6-五溴甲苯

对甲酚置于氢气体系中,用 正己烷 作为反应溶剂,80.0 °C,1.0 Mpa 条件下,反应生成 4-甲基环己醇
参考文献:用于高性能催化的坚固多孔金属硅酸盐材料中 Ni0/niii 异质结的稳定化
标题:用于高性能催化的坚固多孔金属硅酸盐材料中 Ni0/niii 异质结的稳定化
摘要:异质结构纳米材料显示出替代贵金属基催化剂的巨大潜力,因为异质结可以诱导电子重定位并促进电子和电荷载流子在富电子和缺电子金属位点之间的异质结构边界处的迁移;然而,异质结的不稳定性极大地阻碍了它们的实际应用.我们在此报告了一种制备和稳定 Ni 0 /ni Ii的有效策略使用镍配位络合物作为双功能模板的多孔金属硅酸盐 (Pms) 材料 Pms-22 内的异质结.pms-22中金属镍和硅酸镍之间的协同活性极大地提高了苯酚加氢的催化活性,可以在50oc的极低温度下活化苯酚.最重要的是,Pms-22 在催化中表现出强大的稳定性,这归因于金属镍和硅酸镍在受限孔内的异质界面处的强相互作用和电荷转移.因此,这项工作为提高异质结构纳米材料在催化应用中的稳定性和活性开辟了一条新途径.
DOI:10.1021/acs.Inorgchem.2C02624

专利信息

专利号:US-8647848-B2
优先权日:2008-06-13
标题:Enzymatic synthesis of sphingolipids
发明人：HOLLMANN FRANK; THUM OLIVER; TOELLE CHRISTOPH; PROVINZANO ANGELO; KOREVAAR CORNELIS GERRIT NIJS
权利人:HOLLMANN FRANK; THUM OLIVER; TOELLE CHRISTOPH; PROVINZANO ANGELO; KOREVAAR CORNELIS GERRIT NIJS; EVONIK GOLDSCHMIDT GMBH
摘要:The invention relates to the enzymatic synthesis of sphingolipids and compositions that contain sphingolipids from lysosphingolipids and carbonic esters, and to cosmetic, dermatological or pharmaceutical formulations containing said sphingolipids or compositions.

专利号:US-4451666-A
优先权日:1982-08-06
标题:Synthesis of oxalate esters by the oxidative carbonylation of alcohols with a heterogeneous manganese promoted Pd-V-P catalyst
发明人：SOFRANKO JOHN A; GAFFNEY ANNE M
权利人:ATLANTIC RICHFIELD CO
摘要:Synthesis of dialkyl oxalates by the heterogeneous catalyzed oxidative carbonylation of liquid monohydric saturated alcohols of from 1 to 20 carbon atoms with carbon monoxide and oxygen or an oxygen-containing gas in the presence of a catalytic amount of a catalyst comprising palladium or a salt thereof in combination with a crystalline vanadium-phosphorus-manganese containing compound.

专利号:US-2007082943-A1
优先权日:2005-04-01
标 题:Process for preparation of substantially pure glimepiride
发明人：KADAM SURESH M; TARUR VENKATASUBRAMANIAN R; NAIK SANJAY J; GAVHANE SACHIN B
权利人:KADAM SURESH M; TARUR VENKATASUBRAMANIAN R; NAIK SANJAY J; GAVHANE SACHIN B
摘要:The present invention discloses a novel process for purification of trans-4-methyl cyclohexylamine HCl and 4[-2-(3-Ethyl-4-methyl-2-carbonyl pyrrolidine amido) ethyl] benzene sulfonamide used in the synthesis of 3-Ethyl-2,5-dihydro-4-methyl-N-[2-[4-[[[[(trans-4-methyl cyclohexyl)amino]carbonyl]amino]sulfonyl]phenyl]ethyl]-2-oxo-1H-pyrrole-1-carboxamide (I), popularly known as Glimepiride. The present invention also discloses a novel purification of Glimepiride usingS methanolic ammonia and glacial acetic acid to obtain highly pure Glimepiride Form I (I) having the undesired cis isomer below 0.15%. Glimepiride (I) is useful in the treatment of diabetes mellitus.

专利号:US-2013172553-A1
优先权日:2009-11-25
标题 :Chiral synthesis of isoxazolines, isoxazoline compounds, and uses thereof
发明人：SIELECKI-DZURDZ THAIS; PRUITT JAMES
权利人:SIELECKI-DZURDZ THAIS; PRUITT JAMES; CPSI STOCKHOLDER TRUST
摘要:Processes for the chiral syntheses of isoxazolines and intermediates are described. Compounds prepared thereby, and methods of using the compounds are also described.

专利号:US-9802952-B2
优先权日:2013-07-15
标 题:Method and apparatus for the synthesis of dihydroartemisinin and artemisinin derivatives
发明人：KOPETZKI DANIEL; MCQUADE DAVID TYLER; SEEBERGER PETER H; GILMORE KERRY
权利人:MAX-PLANCK-GESELLSCHAFT ZUR FÖRDERUNG DER WSS E V; MAX-PLANK-GESELLSCHAFT ZUR FÖRDERUNG DER WSS E V
摘要:The present invention is directed to a method for continuous production of dihydroartemisinin and also artemisinin derivatives derived from dihydroartemisinin by using artemisinin or dihydroartemisinic acid (DHAA) as starting material as well as to a continuous flow reactor for producing dihydroartemisinin as well as the artemisinin derivatives. It was found that the reduction of artemisinin to dihydroartemisinin in a continuous process requires a special kind of reactor and a special combination of reagents comprising a hydride reducing agent, at least one activator such as an inorganic activator, at least one solid base, at least one aprotic solvent and at least one C 1 -C 5 alcohol.

专利号:US-4447639-A
优先权日:1982-08-06
标题:Oxidative carbonylation of alcohols to dialkyl oxalates using a heterogeneous iron promoted Pd-V-P catalyst
发明人：SOFRANKO JOHN A; GAFFNEY ANNE M
权利人:ATLANTIC RICHFIELD CO
摘要:Synthesis of dialkyl oxalates by the heterogeneous catalyzed oxidative carbonylation of liquid monohydric saturated alcohols of from 1 to 20 carbon atoms with carbon monoxide and oxygen or an oxygen-containing gas in the presence of a catalytic amount of a catalyst comprising palladium or a salt thereof in combination with a crystalline vanadium-phosphorus-iron containing compound.