CAS: 30361-28-5; (2E,4E)-Octa-2,4-Dienal

主要参考文献

参考标题:Preparation Of Conjugated Dienoates With Bestmann Ylide: Towards The Synthesis Of Zampanolide And Dactylolide Using A Facile Linchpin Approach
作者:Jingjing Wang,Samuel Z Y Ting,Joanne E Harvey
摘要:Bestmann Ylide [(Triphenylphosphoranylidene)Ketene] Acts As A Chemical Linchpin That Links Nucleophilic Entities, Such As Alcohols Or Amines, With Carbonyl Moieties To Produce Unsaturated Esters And Amides, Respectively. In This Work, The Formation Of α,β,γ,δ-Unsaturated Esters (Dienoates) Is Achieved Through The Coupling Of Bestmann Ylide, An Alcohol And An α,β-Unsaturated Aldehyde. Primary And Secondary Alcohols, Including Allylic Alcohols, Are Suitable Substrates; The Newly Formed Alkene Has An E-Geometry. Strategically, This Represents A Highly Efficient Route To Unsaturated Polyketide Derivatives. A Linchpin Approach To The Synthesis Of A Major Fragment Of The Natural Products Zampanolide And Dactylolide Is Investigated Using Bestmann Ylide To Link The C16-C20 Alcohol With The C3-C8 Aldehyde Fragment.

合成参考文献

参考文献:10.1007/s12010-015-1898-2
摘要:Hinge V, Patil H, Nadaf A. Comparative Characterization of Aroma Volatiles and Related Gene Expression Analysis at Vegetative and Mature Stages in Basmati and Non-Basmati Rice (Oryza sativa L.) Cultivars. Applied Biochemistry and Biotechnology. 2015 Oct 19;178(4):619–39. doi: 10.1007/s12010-015-1898-2.
摘要:The Good Scents Company Information System