CAS: 1674-38-0; Dodecanophenone

该化合物是属于芳烃类的高纯度有机化合物,其特征是附于长的脂质链的联苯组,在合成有机化学和专门应用中有用;该化合物在标准条件下具有稳定性,在合成香料,药品和精美化学品时具有多种特性的中间体;其疏水性质和明确界定的结构允许在通灵和凝聚反应中精确地进行反动;在质量和可靠性能一致的情况下,1-phenyldodcan-1-1适合需要受控的氯酮功能的研究和工业过程;建议适当的处理和储存保持其完整性.

结构式图片

相似化合物

6048-82-4 6008-36-2 1671-75-6

物理性质

MSDS等安全信息

上下游产品

lauric acid benzoic acid n-dodecanoyl chloride benzene5-phenyl-5-undecyl-imidazolidine-2,4-dione 5-phenyl-hexadecan-5-ol 7-phenyl-°Ctadecane 9-phenyl-eicosane

合成工艺路线路线简述

    📜二苄醚置于叔丁基过氧化氢,Manganese(Iv) Oxide,Magnesium体系中,用 四氢呋喃,二氯甲烷,水 用作溶剂,-20.0~20.0 °C,101.33 Kpa 条件下,反应 44.0H,反应生成月桂基苯甲酮
    参考文献:Mno2/tbhp:用于氧化烯丙基和苄基亚甲基官能团的多功能且用户友好的试剂组合
    标题:Mno2/tbhp:用于氧化烯丙基和苄基亚甲基官能团的多功能且用户友好的试剂组合
    摘要:在活化的 Mno2 存在下,Ch2Cl2 中的叔丁基过氧化氢 (Tbhp) 能够氧化不同类别化合物的烯丙基和苄基亚甲基.我描述了基于两个连续步骤的一锅氧化方案.在低温下进行的第一步中,Mno2 催化亚甲基的氧化.这之后是第二步,其中反应温度升高,使 Mno2 既可以催化未反应的 Tbhp 分解,又可以氧化可能形成的烯丙醇.所提出的氧化程序通常适用,尽管其效率,区域选择性和化学选择性在很大程度上取决于底物的结构.
    Doi:10.1002/ejoc.201500829

    海关参考信息

    专利信息


    专利号:US-7517828-B2
    优先权日:2003-04-25
    标 题 :Chiral broensted acid catalyst for asymmetric synthesis and method of asymmetric synthesis with the catalyst
    发明人：AKIYAMA TAKAHIKO
    权利人:TOAGOSEI CO LTD
    摘要:A compound usable as an asymmetric synthesis catalyst which can be easily synthesized without using any metal such as a lanthanoid group element; a method of asymmetric synthesis with the compound; and a chiral compound obtained by the asymmetric synthesis method. A Broensted acid is used as a catalyst in asymmetric synthesis, the chiral Broensted acid being represented by formula (1) below or formula (3) below. The asymmetric synthesis method employs the catalyst. Asymmetric synthesis with the catalyst gives a chiral compound.

    专利号:US-2006276329-A1
    优先权日:2003-04-25
    标题:Asymmetric synthesis catalyst based on chiral brsnsted acid and method of asymmetric synthesis with the catalyst

    专利号:EP-1623971-A1
    优先权日:2003-04-25
    标 题:Asymmetric-synthesis catalyst based on chiral broensted acid and method of asymmetric synthesis with the catalyst

    其他信息查阅

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    实用工具

    ⚠️全国化工行业净网倡议书
    📋制造商识别码
    📖 海关编码查询
    📝MSDS生成器

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    [参考文献]: Alejandro Fernández-Pumarega, Et Al. Tadpole Toxicity Prediction Using Chromatographic Systems. J Chromatogr A. 2015 Oct 30:1418:167-176.
    [参考文献]: Ali Modir-Rousta, Et Al. New Pressure-Assisted Sweeping On-Line Preconcentration For Highly Polar Environmentally Relevant Nitrosamines: Part 2. Cationic And Anionic Surfactants With Zero-Flow Capillaries. Electrophoresis. 2015 Apr;36(7-8):1016-23.
    [参考文献]: Elisabet Fuguet, Et Al. Solute-Solvent Interactions In Micellar Electrokinetic Chromatography: Iv. Characterization Of Electroosmotic Flow And Micellar Markers. Electrophoresis. 2002 Jan;23(1):56-66.

    合成参考文献


    摘要:Murai, K.; Fujioka, H., Science of Synthesis Knowledge Updates, (2016) 2, 295.
    摘要:Sandrock, D. L., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 1, 348.
    摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198
    参考文献:10.1007/s11657-019-0617-y
    摘要:Tanumihardjo SA, Gannon BM, Kaliwile C, Chileshe J, Binkley NC. Restricting vitamin A intake increases bone formation in Zambian children with high liver stores of vitamin. Archives of Osteoporosis. 2019 Jun 28;14(1):72. doi: 10.1007/s11657-019-0617-y.
    📝 需求与反馈
    尽可能描述清楚需求与问题信息
    ×

    通知