CAS: 15635-87-7; Iridium(Iii) Acetylacetonate

该化合物是一个协调化合物,其特点是其中心与2,2,4-五聚酯相协调.该化合物通常呈现深色外观,通常从褐色到黑色,在丙酮和乙醇等有机溶剂中可溶解.它因其稳定性而闻名,常常被用作各种有机反应的催化剂,包括C-H活化和聚合过程.该化合物的中心处于+3氧化状态,有助于其独特的电子特性和再活动.此外,(III) 2,4-五聚醚可展示发光性,使其在光学应用中具有意义.其协调性一般为辛酸,这是过渡性金属复合物的常见特征.在处理该化合物时,应当采取安全防范措施,因为如果浸入或吸入,可能会对健康造成危害,而且应当保持适当的储存条件,以确保其稳定性.

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    专利号:US-2023001402-A1
    优先权日:2019-11-25
    标题:Iridium-based amorphous electrocatalyst and synthesis of same
    发明人:LI GUANGFU; CHUANG PO-YA ABEL
    权利人:UNIV CALIFORNIA
    摘要:A method of fabricating a catalyst material comprises forming or receiving a precursor solution of an iridium precursor compound, adding a 3d orbital transition metal to the precursor solution, adding a surfactant compound to the precursor solution to provide a precursor and surfactant mixture, reacting the iridium precursor compound with a nitrate salt of an alkaline metal cation to provide a reaction product comprising an iridium nitrate, and calcining the iridium nitrate at a specified calcination temperature to convert the iridium nitrate to form catalyst particles comprising an iridium oxide.

    专利号:US-7399857-B2
    优先权日:2005-03-31
    标题 :Synthesis of organometallic cyclometallated transition metal complexes
    发明人:LUSSIER BARBARA B; DEATON JOSEPH C
    权利人:EASTMAN KODAK CO
    摘要:A process for forming a tris-cyclometallated complex comprises the step of reacting;n a) an M(I) complex, wherein M represents Rh or Ir, and said complex comprises at least two ligands and contains at least two alkenyl groups pi-bonded to M, with b) a heterocyclic compound capable of forming a organometallic cyclometallated complex.

    专利号:US-2006224007-A1
    优先权日:2005-03-31
    标题 :Synthesis of organometallic cyclometallated transition metal complexes
    发明人:LUSSIER BARBARA B; DEATON JOSEPH C
    权利人:EASTMAN KODAK CO
    摘要:A process for forming a tris-cyclometallated complex comprises the step of reacting; a) an M(I) complex, wherein M represents Rh or Ir, and said complex comprises at least two ligands and contains at least two alkenyl groups pi-bonded to M, with b) a heterocyclic compound capable of forming a organometallic cyclometallated complex.

    专利号:US-6235910-B1
    优先权日:1998-09-22
    标题:Process for the preparation of imidazolidine-2, 4-diones
    发明人:BELLER MATTHIAS; ECKERT MARKUS; MORADI WAHED
    权利人:DEGUSSA
    摘要:A process for the preparation of compounds of the general formula (I)by reacting an aldehyde compound of the general formula (II)with a urea compound of the general formula (III)in the presence of carbon monoxide and a catalytically active metal compound. Compounds of the general formula (I) are important intermediates for the synthesis of alpha-amino acids.

    专利号:US-7005522-B2
    优先权日:2004-06-29
    标 题 :Synthesis of organometallic cyclometallated transition metal complexes
    发明人:DEATON JOSEPH C
    权利人:EASTMAN KODAK CO
    摘要:A process for forming a tris-cyclometallated iridium or rhodium complex comprises reacting in the presence of a solvent:n a) a bis-cyclometallated complex comprising an Ir (III) or Rh (III) metal, two bidentate ligands, two monodentate ligands and a counterion, and b) a heterocyclic compound capable of forming an organometallic cyclometallated complex.

    专利号:US-7015344-B2
    优先权日:2004-06-29
    标题 :Synthesis of organometallic cyclometallated group viiib metal complexes
    发明人:DEATON JOSEPH C
    权利人:EASTMAN KODAK CO
    摘要:A process for forming an organometallic cyclometallated Group viiib metal complex comprises reacting a Group viiib metal compound with a heterocyclic compound capable of forming an organometallic cyclometallated complex in the presence of a solvent comprising an aromatic oxygen containing compound.

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