专利号:US-9610568-B2 优先权日:2012-02-15 标题 :Catalytically active body for the synthesis of dimethyl ether from synthesis gas 发明人:SCHÄFER ALEXANDER; VON FEHREN THORSTEN; MADON ROSTAM 权利人:BASF SE 摘要:The invention relates to a catalytically active body for the synthesis of dimethyl ether from synthesis gas. In particular, the invention relates to an improved catalytically active body for the synthesis of dimethyl ether, whereby the components of the active body comprise a defined particle size distribution. Furthermore, the present invention concerns a method for the preparation of a catalytically active body, the use of the catalytically active body and a method for preparation of dimethyl ether from synthesis gas.
专利号:US-4267070-A 优先权日:1979-10-30 标题:Catalyst for the synthesis of aromatic monoisocyanates 发明人:NEFEDOV BORIS K; MANOV-JUVENSKY VLADIMIR I; DERGUNOV JURY I; RYSIKHIN ANATOLY I; CHIMISHKIAN ALEXANDR L 权利人:NEFEDOV BORIS K; MANOV JUVENSKY VLADIMIR I; DERGUNOV JURY I; RYSIKHIN ANATOLY I; CHIMISHKIAN ALEXANDR L 摘要:A catalyst for the synthesis of aromatic monoisocyanates comprising 1.64 to 16.6% by weight of palladium chloride, 0.16 to 47.6% by weight of an oxide of a metal of Group VB of the periodic system, 1.5 to 81.8% by weight of an oxide of a metal of Group VI B of the periodic system, 1.64 to 89.8% by weight of pyridine or an alkylsubstituted pyridine. n The use of the catalyst according to the invention in the synthesis of aromatic monoisocyanates makes it possible to obtain a high degree of conversion of the starting compound of up to 100%, a high yield of the desired product of up to 97%, and increased productivity of the catalyst of up to 40 g of the desired product per g of PdCl 2 per hour.
专利号:WO-2008062139-A1 优先权日:2006-11-24 标题 :Method for the synthesis of light aldehyde by the catalytic oxidation of the corresponding alcohol in a reactor made of specific materials 发明人:DUBOIS JEAN-LUC; DUPONT NICOLAS; FERRER FREDERIC; VAN VEEN ANDRE; MIRODATOS CLAUDE 权利人:ARKEMA FRANCE; DUBOIS JEAN-LUC; DUPONT NICOLAS; FERRER FREDERIC; VAN VEEN ANDRE; MIRODATOS CLAUDE 摘要:The present invention relates to a method for the synthesis of light aldehyde by the gaseous-phase oxy-dehydrogenation of the corresponding alcohol at a temperature of between 500 and 700°C in adiabatic conditions and in the presence of a metal silver catalyst, characterised in that the oxy-dehydrogenation reaction is carried out in a reactor made of a metal or metal alloy capable of forming a surface layer of chemically inert oxides in nominal operating conditions. More particularly, the metal is selected from titanium, zirconium and tantalum. The metallic alloys include at least 19 wt % or chromium and at least one alloy element selected from aluminium, silicon, manganese, magnesium, wherein the total concentration of said metals is higher than 2 wt %, or selected from the rare earths comprising lanthanum, yttrium, or cerium with a concentration of between 0.1 and 0.5 %
专利号:US-2005087449-A1 优先权日:2002-03-04 标题:Electrochemical synthesis of ammonia 发明人:DENVIR ADRIAN; MURPHY OLIVER J; CISAR ALAN; ROBERTSON PRISCILLA; USELTON KYLE 摘要:A method for electrochemical synthesis of ammonia gas comprising providing an electrolyte between an anode and a cathode, providing hydrogen gas to the anode, oxidizing negatively charged nitrogen-containing species present in the electrolyte at the anode to form an adsorbed nitrogen species, and reacting the hydrogen with the adsorbed nitrogen species to form ammonia. Preferably, the hydrogen gas is provided to the anode by passing the hydrogen gas through a porous anode substrate. It is also preferred to produce the negatively charged nitrogen-containing species in the electrolyte by reducing nitrogen gas at the cathode. However, the negatively charged nitrogen-containing species may also be provided by supplying a nitrogen-containing salt, such as lithium nitride, into the molten salt electrolyte mixture in a sufficient amount to provide some or all of the nitrogen consumed in the production of ammonia.
专利号:US-2015096900-A1 优先权日:2012-05-25 标题:Alloys of the type fe3aita(ru) and use thereof as electrode material for the synthesis of sodium chlorate or as corrosion resistant coatings 发明人:SCHULZ ROBERT; SAVOIE SYLVIO 权利人:HYDRO QUÉBEC; MEEIR TECHNOLOGIE INC 摘要:Disclosed is an alloy of the formula: Fe 3−x Al 1+x M y T z Ta t wherein M represents at least one catalytic specie selected from the group consisting of Ru, Ir, Pd, Pt, Rh, Os, Re and Ag; T represents at least one element selected from the group consisting of Mo, Co, Cr, V, Cu, Zn, Nb, W, Zr, Y, Mn, Cd, Si, B, C, O, N, P, F, S, CI, Na and Ti; and Ta represents tantalum. Such an alloy can be used as an electrode material for the synthesis of sodium chlorate. It can also be used as a coating for protection against corrosion.
专利号:US-8916730-B2 优先权日:2008-06-03 标题:Method for the synthesis of dialkoxy alkanes by means of the selective oxidation of alcohols 发明人:DUBOIS JEAN-LUC 权利人:DUBOIS JEAN-LUC; ARKEMA FRANCE 摘要:The invention relates to a method for the synthesis of dialkoxyalkanes by means of the partial selective oxidation of a light alcohol. According to said method, the light alcohol is oxidized in the presence of molecular oxygen or a gas containing molecular oxygen, and a solid oxidation catalyst based on at least one metal in a reactive medium comprising a gaseous phase containing an acid compound according to the Pearson classification, having a pKa of less than 6.3 in solution in water. The reaction is carried out in a vapor or in a liquid phase.
参考文献:10.1016/j.arth.2011.04.024 摘要:Kamath AF, Gee AO, Nelson CL, Garino JP, Lotke PA, Lee GC. Porous tantalum patellar components in revision total knee arthroplasty minimum 5-year follow-up. J Arthroplasty. 2012 Jan;27(1):82–7. doi: 10.1016/j.arth.2011.04.024. 参考文献:10.1016/j.saa.2011.06.043 摘要:Srikumar T, Brik MG, Srinivasa Rao C, Gandhi Y, Krishna Rao D, Ravi Kumar V, Veeraiah N. Spectral and fluorescent kinetics features of Nd3+ ion in Nb2O5, Ta2O5 and La2O3 mixed lithium zirconium silicate glasses. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2011 Oct;81(1):498–503. doi: 10.1016/j.saa.2011.06.043. 参考文献:10.3174/ajnr.a2547 摘要:Binning MJ, Yashar P, Orion D, Hauck EF, Levy EI, Hopkins LN, Siddiqui AH. Use of the Outreach Distal Access Catheter for microcatheter stabilization during intracranial arteriovenous malformation embolization. AJNR Am J Neuroradiol. 2012 Oct;33(9):E117–9. 参考文献:10.1302/0301-620x.93b8.26233 摘要:Periasamy K, Watson WS, Mohammed A, Murray H, Walker B, Patil S, Meek RMD. A randomised study of peri-prosthetic bone density after cementedversustrabecular fixation of a polyethylene acetabular component. The Journal of Bone and Joint Surgery. British volume. 2011 Aug;93-B(8):1033–44. doi: 10.1302/0301-620x.93b8.26233. 参考文献:10.22203/ecm.v010a07 摘要:Andersen LK, Contera SA, Justesen J, Duch M, Hansen O, Chevallier J, Foss M, Pedersen FS, Besenbacher F. Cell volume increase in murine MC3T3-E1 pre-osteoblasts attaching onto biocompatible tantalum observed by magnetic AC mode atomic force microscopy. Eur Cell Mater. 2005 Dec 02;10():61–8; discussion 68. doi: 10.22203/ecm.v010a07.