CAS: 131-08-8; Sodium 9,10-Dioxo-9,10-Dihydroanthracene-2-Sulfonate

该化合物是一种可溶水的炭疽子化衍生物,广泛用作有机合成和染料制造的中间体,其主要优点包括水溶性高,在温和条件下稳定,在催化过程中作为再氧化媒介的活性.该化合物在工业应用中特别受到重视,在生产蒸发染料和作为电子转移剂时特别受到重视.其磺酸混合物会增强与极地溶剂的兼容性,促进同质反应条件.此外,它在碱性环境中表现出一贯的性能,使之适合需要精确控制氧化作用的专门化学工艺.

结构式图片

欧盟法规

REACH注册ECHA物质C&L通报REACH预注册

合成工艺路线路线简述

    海关参考信息

    专利信息


    专利号:US-9126995-B2
    优先权日:2011-11-08
    标题:Method for catalytic asymmetric synthesis of optically active isoxazoline compound and optically active isoxazoline compound
    发明人:TOYAMA KEN-ICHI; MORIYAMA YUJI; MATOBA KAZUTAKA; YAOSAKA MANABU; IKEDA EITATSU
    权利人:NISSAN CHEMICAL IND LTD
    摘要:There is provided a method for catalytic asymmetric synthesis of optically active isoxazoline compound and an optically active isoxazoline compound. A method for catalytic asymmetric synthesis of optically active isoxazoline compound of a formula (6) including reacting an α,β-unsaturated carbonyl compound of a formula (1) and a hydroxylamine in a solvent in the presence of a base by adding a chiral phase transfer catalyst. An optically active isoxazoline compound of a formula (13) that can be synthesized by the method.

    专利号:US-3956184-A
    优先权日:1974-04-24
    标题:Method of preparing silver catalyst for synthesis of formaldehyde by oxidizing methyl alcohol
    发明人:KRUGLIKOV ANATOLY ABRAMOVICH; YAKOVENKO ZEMFIRA IVANOVNA; ROZNINA MARINA IVANOVNA; ROGACHEVA ANNA MALOFEEVNA; BELOUSOV GERMAN IVANOVICH
    权利人:KRUGLIKOV ANATOLY ABRAMOVICH; YAKOVENKO ZEMFIRA IVANOVNA; ROZNINA MARINA IVANOVNA; ROGACHEVA ANNA MALOFEEVNA; BELOUSOV GERMAN IVANOVICH
    摘要:The method of preparing a silver catalyst for synthesis of formaldehyde by oxidizing methyl alcohol which consists in that a carrier is impregnated with an aqueous or an aqueous-alcohol solution containing complex ions of silver having the general formula [Ag(X) n ] + or [Ag(Y) 2 ] - , where X is ammonia, ethylenediamine, triethylenetetramine or triaminotriethylamine, Y is a thiocyanate, cyanide, acetate, or hydroxyl ion, and n is 1 or 2. The impregnated carrier is processed, at a temperature of from 10° - 100°C, with a reducing agent taken in the quantity sufficient to reduce the silver completely from said ion. The thus-prepared catalyst is dried at a temperature of from 80° to 400°C. It is recommended that the catalyst be washed with water before drying. The thus-prepared catalyst has a highly developed active surface with a small content of silver (the specific surface of the catalyst is 0.7 - 7 square meters per gram, with the metal silver content of the catalyst being from 5 - 10 per cent by weight). The catalyst is highly active and has good selectivity in the process of formaldehyde synthesis from methyl alcohol. The yield of formaldehyde with the proposed catalyst is from 75 - 80 per cent, calculating with reference to the passed methyl alcohol, with the selectivity of the process being from 89 - 95 per cent.

    专利号:US-4841045-A
    优先权日:1985-03-12
    标 题 :Synthesis of vinblastine and vincristine type compounds
    发明人:KUEHNE MARTIN
    权利人:UNIV VERMONT
    摘要:A new process for the stereospecific synthesis of alkaloids of the vinblastine and vincristine type including the synthesis of vinblastine and vincristine as well novel alkaloids which are active as anti-tumor agents.

    专利号:US-4897477-A
    优先权日:1985-03-12
    标题:Synthesis of vinblastine and vincristine type compounds
    发明人:KUEHNE MARTIN
    权利人:UNIV VERMONT
    摘要:A new process for the stereospecific synthesis of alkaloids of the vinblastine and vincristine type including the synthesis of vinblastine and vincristine as well novel alkaloids which are active as anti-tumor agents.

    专利号:US-9938297-B2
    优先权日:2014-08-04
    标 题:Process for the synthesis of everolimus and intermediates thereof
    发明人:RAO DHARMARAJ RAMACHANDRA; MALHOTRA GEENA; PULLELA VENKATA SRINIVAS; ACHARYA VINOD PARAMESHWARAN
    权利人:CIPLA LTD; CIPIA LTD
    摘要:The present invention relates to a novel process for the synthesis of everolimus of formula (I): n nand intermediates thereof.

    专利号:US-6159673-A
    优先权日:1996-07-17
    标 题:Oxonol compound, light-sensitive material and process for the synthesis of oxonol compound
    发明人:NISHIGAKI JUNJI; DEGUCHI YASUAKI
    权利人:FUJI PHOTO FILM CO LTD
    摘要:An oxonol compound is represented by the following formula (I): in which Z is an atomic group that forms a cyclic amide ring; each of W1 and W2 independently is an atomic group that forms an acidic nucleus ring; and M is a cation. Other oxonol compounds, a light-sensitive material containing an oxonol compound and a process for the synthesis of an oxonol compound are also disclosed.
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    合成参考文献


    摘要:Gigiena i Sanitariya. For English translation, see HYSAAV., 55(4)(93), 1990
    参考文献:10.2116/analsci.22.807
    摘要:Yokoyama T, Tsuchiya Y, Murakami G, Zenki M. Capillary electrophoretic determination of self-dimerization constants of aromatic carboxylate and sulfonate ions. Anal Sci. 2006 Jun;22(6):807–10. doi: 10.2116/analsci.22.807.
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