CAS: 77-06-5; Gibberellin A3

上下游产品

CAS号510-75-8 赤霉素 A4+A7 | CAS号468-44-0 赤霉素A4 | CAS号78259-50-4 赤霉素A95

Rac-(1R,4Bs,7S,9As,10S,10As)-1,4B,7,10A-Tetramethyl-8-Methylene-1,10-Divinyl-2,3,4B,5,6,7,8,9,10,10A-Decahydro-1H-7,9A-Methanobenzo[a]Azulene置于吡啶,盐酸,氢氧化钾,Sodium Chlorite,Sodium Dihydrogenphosphate,2-甲基-2-丁烯,氨,水,碘,Lithium,碳酸氢钠,1,8-二氮杂双环[5.4.0]十一碳-7-烯,三乙胺,N,N-二异丙基乙胺,间氯过氧苯甲酸,Lithium Diisopropyl Amide体系中,用 四氢呋喃,二氯甲烷,水,1,2-二氯乙烷,叔丁醇,苯 作为反应溶剂,化学反应 10.42H,反应生成 赤霉素
参考文献:(+/-)-赤霉素的全合成
标题:(+/-)-赤霉素的全合成
摘要:(+/-)-赤霉素的全合成是通过高度立体控制的途径完成的.
DOI:10.1016/s0040-4039(00)95293-6

专利信息

专利号:US-8461357-B2
优先权日:2008-09-19
标题 :Expeditious synthesis of gibberellin A5 and esters thereof
发明人：FAIRWEATHER KELLY A; MANDER LEWIS N; PHARIS RICHARD P
权利人:FAIRWEATHER KELLY A; MANDER LEWIS N; PHARIS R P; UTI LIMITED PARTNERSHIP
摘要:An expeditious synthesis of gibberellin A 5 (GA 5 ) esters is presented, from which GA 5 may be prepared. The synthesis offers an inexpensive route of few steps to these compounds, starting from gibberellin A 3 (GA 3 ) esters in the presence of a metal hydride.

专利号:US-2018111889-A1
优先权日:2015-03-20
标 题:Methods of making multicyclic compounds using multicomponent/tandem reaction sequences
发明人：CHALIFOUX WESLEY A; CARMICHAEL RACHAEL A
权利人:BOARD OF REGENTS OF THE NEVADA SYSTEM OF HIGHER EDUCATION ON BEHALF OF THE UNIV OF NEVADA
摘要:Disclosed herein are embodiments of multicyclic compounds and methods of making such compounds. The disclosed methods reduce step-counts in the synthesis of complex targets, while reducing costs and waste streams.

专利号:US-2002055171-A1
优先权日:1998-05-27
标题 :Preparation of biologically active 3-methyleneoxindole and definition of its application in stimulation of plant growth and tissue repair
发明人：TULI VIRENDA KUMAR
摘要:Identification of the true nature and metabolic action of 3 -methyleneoxindole (MO), a naturally occurring catabolite of the plant auxin, indole- 3 -acetic acid (IAA). Description of the two novel methods of synthesis of MO which produce the pure, biologically active auxin compound of MO. Discovery and description of the causes for the erroneous classification of MO as an inert compound with no auxin activity. These findings and methods of synthesis correct the ubiquitous theoretical errors which have driven scientific investigation and plant science research of plant auxins for nearly forty years. n Researchers have failed to observe the auxin activity of MO because of the use of standard but incorrect synthetic techniques which have consistently produced impure forms of 3 -bromooxindole- 3 -acetic acid ( 3 -Brox), the synthetic precursor of MO. In addition, the use of dimethylsulfooxide as a solvent for MO has been identified as a major source of contamination of MO during synthesis. n This invention describes two novel methods for synthesizing (MO). By using purified MO and avoiding the use of dimethylsulfoxide, it was found that the resulting MO product to be 100 to 1,00 fold more effective than IAA in promoting rooting in plant cuttings; supporting tissue differentiation and growth in stage I, stage II and stage III media used for the micropropagation of explants; promoting the formation of callus tissue over wounded plant parts; and, stimulating the production of interstitial tissue between scion and rootstock to increase the success rate for grafting. Therefore, this invention identifies MO as the dominant auxin in shoot acceleration, root development, wound sealing and scion acceptance. n Finally, the correct pathway from IAA to MO is presented.

专利号:WO-2005103292-A1
优先权日:2004-04-27
标 题 :Method of monitoring gibberellin and abscisic acid synthesis during barley milling
发明人：OGAWA TOSHIYA
权利人:KIRIN BREWERY; OGAWA TOSHIYA
摘要:It is intended to provide a method of monitoring the synthesis of gibberellin and abscisic acid in germinating barley seeds during barley milling. Namely, a method of monitoring the synthesis of gibberellin and abscisic acid in germinating barley seeds during barley milling which comprises measuring the expression levels of gibberellin 3β-hydroxylase gene (HvGA3ox), gibberellin 20-oxidase gene (HvGA20ox) and 9-cis-epoxycarotenoid dioxygenase gene (HvNCED).

专利号:US-2025304985-A1
优先权日:2022-04-08
标题 :Genetically Engineered Plants for Increased Production of Vindoline
发明人：LEE-PARSONS CAROLYN; COLE LAUREN F
权利人:UNIV NORTHEASTERN
摘要:Two novel transcription factors, CrDELLA1 and CrDELLA2, are described in Catharanthus roseus plants. The DELLA transcription factors have a regulatory role in the synthesis of vinblastine and vincristine, two important anti-cancer compounds that have proved difficult to obtain in sufficient quantities. The present technology provides genetically modified C. roseus plants having enhanced DELLA activity, which leads to activation of multiple enzymes in the biosynthetic pathway leading to vinblastine and vincristine. The genetic modifications can be used together with activation of plant defense mechanisms and responses to light in order to boost vinblastine and vincristine synthesis.

专利号:US-2003157592-A1
优先权日:1999-12-16
标题:Moss genes from physcomitrella patens encoding proteins involved in the synthesis of tocopherols and carotenoids
发明人：LERCHL JENS; RENZ ANDREAS; EHRHARDT THOMAS; REINDL ANDREAS; CIRPUS PETRA; BISCHOFF FRIEDRICH; FRANK MARKUS; FREUND ANNETTE; DUWENIG ELKE; SCHMIDT RALF-MICHAEL; RESKI RALF; BADUR RALF
摘要:Isolated nucleic acid molecules, designated TCMRP nucleic acid molecules, which encode novel TCMRPs from e.g. Phycomitrella patens are described. The invention also provides antisense nucleic acid molecules, recombinant expression vectors containing TCMRP nucleic acid molecules, and host cells into which the expression vectors have been introduced. The invention still further provides isolated TCMRPs, mutated TCMRPs, fusion proteins, antigenic peptides and methods for the improvement of production of a desired compound from transformed cells, organisms or plants based on genetic engineering of TCMRP genes in these organisms.