CAS: 4250-81-1; Pent-1-Yn-1-Ylbenzene

上下游产品

propyl benzenesulfonate (phenylethynyl)sodium Phosphoric acid (Z)-2-benzenesulfonyl-1-phenyl-pent-1-enyl ester diethyl ester (5-bromo-pent-1-ynyl)-benzene 2-phenyl-pentanoic acid methyl ester (1,1,2,2-tetrafluoropentyl)benzene ((E)-1,2-Dichloro-pent-1-enyl)-benzene ((E)-1-Chloro-2-iodo-pent-1-enyl)-benzene

📜1-苯基-2-戊酮置于三乙烯二胺,氧气,Copper(L) Chloride体系中,用 甲醇,二甲基亚砜 作为反应溶剂,100.0 °C,101.33 Kpa 条件下,反应 12.0H,反应生成 1-苯基戊烯
参考文献:铜催化的酮衍生的n-甲苯磺酰hy的有氧氧化转化:炔烃的入口.
标题:铜催化的酮衍生的n-甲苯磺酰hy的有氧氧化转化:炔烃的入口.
摘要:已开发出一种新的策略,涉及铜催化的酮衍生部分转化为各种合成的有价值的内部炔烃和二炔.该方法的特点是廉价的金属催化剂,绿色氧化剂,非常好的官能团耐受性,高区域选择性和易于获得的原料.进行氧化去质子反应以形成内部炔烃和对称二炔.进行hydr与卤化物和末端炔的交叉偶联反应,得到官能化的炔和不对称的共轭二炔.提出了通过碳卡宾中间体进行cc三键形成的机理.
DOI:10.1002/anie.201405058

专利信息

专利号:US-9920160-B2
优先权日:2014-09-03
标题 :Method for synthesis of polymer containing multiple epoxy groups
发明人：GAO CHAO; ZHENG YAOCHEN; PENG LI; CAI SHENGYING; WENG ZHULIN
权利人:UNIV ZHEJIANG
摘要:A method for a synthesis of a polymer containing multiple epoxy groups includes steps of: under protection of nitrogen or argon, with a photosensitive free radical initiator under an ultraviolet light irradiation, initiating a mixture of a dithiol compound and alkynyl glycidyl ether or other alkynyl-containing compounds to proceed a thiol-yne polymerization, so as to obtain the polymer. The number of the epoxy groups is able to be adjusted through changing a type of a dithiol monomer, a mixing ratio of the dithiol monomer, and a mixing ratio between the alkynyl glycidyl ether and other alkynyl compounds. The present invention has advantages of: fast reaction, convenient process, easy post-processing, a large number of the epoxy groups, and adjustable and controllable content. The obtained polymer has a wide potential application in fields of coating, adhesive, ink, encapsulating material, resin for composite material, additive, high performance material, function material, and so on.

专利号:US-7261871-B2
优先权日:2001-09-28
标 题 :Fabrication of carbon nanotube films from alkyne-transition metal complexes
发明人：IYER VIVEKANANTAN S; VOLLHARDT K PETER C
权利人:UNIV CALIFORNIA
摘要:A simple method for the production or synthesis of carbon nanotubes as free-standing films or nanotube mats by the thermal decomposition of transition metal complexed alkynes with aryl, alkyl, alkenyl, or alkynyl substituents. In particular, transition metal (e.g. Co, Ni, Fe, Mo) complexes of diarylacetylenes, e.g. diphenylacetylene, and solid mixtures of these complexes with suitable, additional carbon sources are heated in a vessel. More specifically, the heating of the transition metal complex is completed at a temperature between 400-800° C. and more particularly 550-700° C. for between 0.1 to 24 hours and more particularly 0.5-3 hours in a sealed vessel under a partial pressure of argon or helium.

专利号:US-5001136-A
优先权日:1990-06-07
标 题 :Leukotriene-synthesis-inhibiting 2-substitutedmethylamino-5-(hydroxy or alkoxy)pyridines
发明人：WALKER FREDERICK J
权利人:PFIZER
摘要:2-substitutedmethylamino-amino 5-(hydroxy or alkoxy) pyridines and derivatives thereof are disclosed. The compounds are inhibitors of leukotriene synthesis and are therefore useful for the treatment of pulmonary, inflammatory, dermatological, allergic and cardiovascular diseases.

专利号:US-3850911-A
优先权日:1960-09-22
标题:Steroid synthesis
发明人：HUGHES G; SMITH H
权利人:HUGHES G; SMITH H
摘要:1. A CHEMICAL COMPOUND HAVING A CYCLOPENTANOPHENANTHRENE CARBON-CARBON SKELETON CONTAINING AT LEAST 19 AND UP TO A MAXIMUM OF 40 CARBON ATOMS AND IN WHICH AT LEAST B AND THE C RING ARE AT LEAST PARTIALLY HYDROGENATED, INCLUDING A NUCLEUS SELECTED FROM THE GROUP CONSISTING OF SATURATED AND UNSATURATED GONANE AND 8ISOGONANE NUCLEI HAVING UP TO A MAXIMUM OF FIVE (5) DOUBLE BONDS AND HAVING A PART THEREOF IN THE 13-POSITION F MONOVALENT POLYCARBON ALKYL RADICAL HAVING 2 TO ABOUT 16 CARBON ATOMS, SAID RINGS AND THE 13 AND OTHER POSITIONS OF THE NUCLEUS BEING IDENTIFIED ACCORDING TO STEROID NOMENCLATURE.

专利号:US-6583315-B2
优先权日:2000-12-23
标 题:Process for preparing ethanebis(alkylphosphinic) acids
发明人：SICKEN MARTIN; WEFERLING NORBERT; SCHMITZ HANS-PETER
权利人:CLARIANT GMBH
摘要:The invention relates to a process for preparing ethanebis(alkylphosphinic) acids by n a) reacting elemental yellow phosphorus with alkyl halides in the presence of alkali metal hydroxide or of alkaline earth metal hydroxide to give a mixture whose main constituents are the alkali metal salts and/or alkaline earth metal salts of alkylphosphonous, phosphorous, and hypophosphorous acid, n b) liberating alkylphosphonous, phosphorous, and hypophosphorous acid by adding mineral acids, and also at the same time precipitating the alkali metal ions and, respectively, alkaline earth metal ions in the form of their salt of the mineral acids, and then n c) esterifying the alkylphosphonous acid from the mixture of the alkylphosphonous, phosphorous, and hypophosphorous acid, n d) isolating the ester of alkylphosphonous acid from the mixture and hydrolyzing the same to give alkylphosphonous acid, and n e) preparing, from the alkylphosphonous acid, the corresponding ethanebis(alkylphosphinic) acid of the general formula (I) where R 1 and R 2 may be identical or different and are hydrogen, a carboxy group, a carboxylic acid derivative, an unsubstituted or substituted alkyl group having from 1 to 10 carbon atoms, phenyl, benzyl, or alkyl-substituted aromatics, and R 3 and R 4 are identical or different and are an unsubstituted or substituted alkyl group having from 2 to 20 carbon atoms, by free-radical-initiated reaction with alkynes, and also to the use of the ethanebis(alkylphosphinic) acids prepared by this process as starting material for preparing flame retardants and precursors for the synthesis of other phosphorus-containing compounds.

专利号:US-5491167-A
优先权日:1993-01-29
标题 :Hexahydronaphthalene ester derivatives, their preparation and their therapeutic uses
发明人：ISHIHARA SADAO; KOGEN HIROSHI; KOGA TEIICHIRO; KITAZAWA EIICHI; SERIZAWA NOBUFUSA
权利人:SANKYO CO
摘要:Compounds of formula (I): ##STR1## and their salts and esters have the ability to inhibit the synthesis of cholesterol, and can thus be used for the treatment and prophylaxis of hypercholesterolemia and of various cardiac disorders.