CAS: 25524-95-2; (Z)-6-(Pent-2-En-1-yl)Tetrahydro-2H-Pyran-2-One

该化合物是一种香味和香味中常用的香味化合物,其特点是其甘甜,花粉芳香的共聚物,在各种香味的配制中是一种流行选择;该物质在室内温度下无色可粉黄液体,在乙醇和油等有机溶剂中可溶解,但水溶性有限.茉莉甘甘酯的沸点相对较低,有助于其挥发性以及产品中传递持久香气的能力.其化学结构特征是乳腺环,其独特的芳香特性在于此.茉莉甘酯经常与其他香味成分结合使用,以在香水,化妆品和家用产品中创造复杂的香味特征.此外,在建议的浓度内,该物质被认为安全用于消费品.

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698-76-0 705-86-2 710-04-3

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CAS号25448-66-2 tetrahydro-6-(2... | CAS号16400-32-1 1-溴-2-戊炔 | CAS号87086-56-4 5-hydroxydec-7-... | CAS号87086-50-8 3-(2-pentynyl)-... | CAS号87086-46-2 6-(2-pentynyl)-... | CAS号765-87-7 1,2-环己二酮 | CAS号10316-66-2 2-羟基-2-环己烯-1-酮 | CAS号111-30-8 戊二醛

合成工艺路线路线简述

    📜1,2-环己二酮置于pd-Baso4 喹啉,Aluminum Oxide,Sodium Tetrahydroborate,氢气,氧气,亚甲兰,碳酸氢钠,对甲苯磺酸,Lithium Diisopropyl Amide体系中,用 甲醇,乙醚,水,苯 用作溶剂,化学反应 17.25H,反应生成(Z)-7-癸烯-5-酸
    参考文献:New Synthesis Of Jasmine Lactone And Related .Delta.-Lactones From 1,2-Cyclohexanedione. Preparation And Dye-Sensitized Photooxygenation Of 3-(2-Alkenyl)-And 3-(2-Alkynyl)-1,2-Cyclohexanediones
    标题:New Synthesis Of Jasmine Lactone And Related .Delta.-Lactones From 1,2-Cyclohexanedione. Preparation And Dye-Sensitized Photooxygenation Of 3-(2-Alkenyl)-And 3-(2-Alkynyl)-1,2-Cyclohexanediones
    摘要:
    Doi:10.1021/jo00356A035

    海关参考信息

    专利信息


    专利号:US-8653223-B2
    优先权日:2008-04-16
    标题:Transketalized compositions, synthesis, and applications
    发明人:SELIFONOV SERGEY; GOETZ ADAM EDWARD; JING FENG
    权利人:SELIFONOV SERGEY; GOETZ ADAM EDWARD; JING FENG; SEGETIS INC
    摘要:Ketal compounds of the structure I n nand a method of preparation of the compound from polyols and oxocarboxylates, as well as uses thereof.

    专利号:US-8546519-B2
    优先权日:2007-10-09
    标题 :Polyketal compounds, synthesis, and applications
    发明人:SELIFONOV SERGEY; ROTHSTEIN SCOTT D; WICKS DOUGLAS A; MULLEN BRIAN D; MULLEN TARA J; PRATT JASON D; WILLIAMS CHARLES T; WU CHUNYONG; ZHOU NING
    权利人:SELIFONOV SERGEY; ROTHSTEIN SCOTT D; WICKS DOUGLAS A; MULLEN BRIAN D; MULLEN TARA J; PRATT JASON D; WILLIAMS CHARLES T; WU CHUNYONG; ZHOU NING; SEGETIS INC
    摘要:The invention relates to polyketal compounds. The compounds are synthesized by the selective ketalization of oxocarboxylic acids, e.g. keto acids and semialdehydes, and esters thereof with tetrols and higher polyols that products two or more cyclic ketal ester moieties per molecule, wherein the cyclic ketal moieties are situated in a bis-, tris-, or polyketal conformation. The invention further relates to applications of these compounds and subsequent reactions thereof.

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    ✅ COA系统入驻 | 共享模式

    主要参考文献


    1: Zeng L, Zhou Y, Fu X, Liao Y, Yuan Y, Jia Y, Dong F, Yang Z. Biosynthesis of Jasmine Lactone in Tea ( Camellia sinensis) Leaves and Its Formation in Response to Multiple Stresses. J Agric Food Chem. 2018 Apr 18;66(15):3899-3909. doi: 10.1021/acs.jafc.8b00515. Epub 2018 Apr 6. doi: 10.1016/j.foodchem.2017.05.137. Epub 2017 May 29. doi: 10.1002/jms.3961. doi: 10.1021/acs.jafc.5b02741. Epub 2015 Aug 3. doi: 10.1039/c5ob00362h. doi: 10.1016/j.foodchem.2013.10.069. Epub 2013 Oct 24. doi: 10.1080/14786419.2013.831095. Epub 2013 Sep 5. doi: 10.1016/j.bmcl.2011.08.025. Epub 2011 Aug 12. Epub 2010 May 7. doi: 10.1016/j.bmcl.2009.03.012. Epub 2009 Mar 9. Epub 2006 Nov 20. doi: 10.1271/bbb.63.1122.

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