CAS: 4651-46-1; (3S,5S,9R,10S,13R,14R,17R)-17-((2R,5S,E)-5-Ethyl-6-Methylhept-3-En-2-yl)-10,13-Dimethyl-2,3,4,5,6,9,10,11,12,13,14,15,16,17-Tetradecahydro-1H-Cyclopenta[a]Phenanthren-3-Yl Acetate
- 英文名称(3S,5S,9R,10S,13R,14R,17R)-17-((2R,5S,E)-5-Ethyl-6-Methylhept-3-En-2-yl)-10,13-Dimethyl-2,3,4,5,6,9,10,11,12,13,14,15,16,17-Tetradecahydro-1H-Cyclopenta[a]Phenanthren-3-Yl Acetate
- 中文名称乙酸 α-波菜甾醇酯
- IUPAC名称(3S,5S,9R,10S,13R,14R,17R)-17-((2R,5S,E)-5-ethyl-6-methylhept-3-en-2-yl)-10,13-dimethyl-2,3,4,5,6,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl acetate
- 其它别名Alpha-Spinasterol Acetate; α-Spinasterol Acetate; Stigmasta-7,22-Dien-3-Ol, 3-Acetate, (3β,5α,22E)-; Alpha-Spinsterhoodacetate; α-Spinasterolacetate
- CAS编号4651-46-1
- MFCD编号:MFCD00200555
- 分子式:C31H50O2分子量:454.74
- 产品CID: 1463036
- 产品分类天然产物 → 甾体化合物
物理性质
MSDS等安全信息
上下游产品
Spinasterol acetic anhydride Acetic acid (3S,5S,9R,10S,13R,14R,17R)-17-{(E)-(1R,4S)-1,5-dimethyl-4-[2-(toluene-4-sulfonyloxy)-ethyl]-hex-2-enyl}-10,13-dimethyl-2,3,4,5,6,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl ester (22E,24S)-3β-hydroxy-5α-stigmasta-7,22-diene-24-carbaldehyde 7-Stigmastenyl acetate7-Stigmastenyl acetate R)-2-ethyl-3-methyl-butyraldehyde(R)-2-ethyl-3-methyl-butyraldehyde 3β-benzoyloxy-5α-stigmast-7-ene合成工艺路线路线简述
📜Acetic Acid (3S,5S,9R,10S,13R,14R,17R)-17-[(E)-(1R,4S)-4-(2-Hydroxy-Ethyl)-1,5-Dimethyl-Hex-2-Enyl]-10,13-Dimethyl-2,3,4,5,6,9,10,11,12,13,14,15,16,17-Tetradecahydro-1H-Cyclopenta[a]Phenanthren-3-Yl Ester置于吡啶,Sodium Iodide,锌体系中,用 乙二醇二甲醚 作为反应溶剂,化学反应 23.0H,反应生成 乙酸 Alpha-波菜甾醇酯
参考文献:软骨甾烷醇和菠固甾醇的合成[(22 E,24 R)-和(22 E,24 S)-5α-Stigmasta-7,22-Dien-3β-Ol]
标题:软骨甾烷醇和菠固甾醇的合成[(22 E,24 R)-和(22 E,24 S)-5α-Stigmasta-7,22-Dien-3β-Ol]
摘要:由乙基(22 E,24 S)-和(22 E,24 R)-3β-乙酰氧基-5α-Stigmasta-7,22-Dien-29-Oates合成spinastesterol(1A)和chrondrillasterol(1B),(2C)和(2D).
DOI:10.1039/p19810002561
海关参考信息
- 2901210000-乙烯
2901220000-丙烯
2905122000-异丙醇
2909110000-乙醚 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
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📌 第三方产品分析报告
合成参考文献
参考文献:10.1248/cpb.30.2570
摘要:KANAOKA M, YOSHIZAKI M, FUJINO H. Studies on the constituents of Trichosanthes species. I. On the neutral ether extracts of the dried roots of Trichosanthes japonica Regel, Trichosanthes kirilowii Maxim. and Trichosanthes cucumeroides Maxim.. Chem. Pharm. Bull. 1982;30(7):2570–4. doi: 10.1248/cpb.30.2570.
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