📜2-羟基庚酸置于盐酸体系中,化学反应生成1,1-二乙基己烷 参考文献:Bagard,Bulletin De La Societe Chimique De France,1907,Vol. <4>1,P. 313 标题:Bagard,Bulletin De La Societe Chimique De France,1907,Vol. <4>1,P. 313
专利号:US-9783477-B2 优先权日:2015-07-31 标题 :Synthesis of fuels and feedstocks 发明人:SUTTON ANDREW D; BROOKS TY; Jenkins Rhodri; MOORE CAMERON; Staples Orion 权利人:LOS ALAMOS NAT SECURITY LLC 摘要:Disclosed herein are embodiments of a method for making fuels and feedstocks from readily available alcohol starting materials. In some embodiments, the method concerns converting alcohols to carbonyl-containing compounds and then condensing such carbonyl-containing compounds together to form oligomerized species. These oligomerized species can then be reduced using by-products from the conversion of the alcohol. In some embodiments, the method further comprises converting saturated, oligomerized, carbonyl-containing compounds to aliphatic fuels.
专利号:US-2017029351-A1 优先权日:2015-07-31 标 题:Synthesis of fuels and feedstocks
专利号:US-7175871-B2 优先权日:2002-07-15 标题:Acyclic enol ethers, isomers thereof, organoleptic uses thereof and processes for preparing same 发明人:MOOKHERJEE BRAJA DULAL; NARULA ANUBHAV P S; PATEL SUBHA M; ARRUDA EDWARD MARK; MERRITT PATRICK M 权利人:INT FLAVORS & FRAGRANCES INC 摘要:Described are synthetically produced substantially pure enol ether compositions which are cis and/or trans isomers of enol ethers having the structures: n nwherein R 1 is C 4 –C 10 straight chain alkyl or C 9 8-alkenyl; and wherein R 2 is C 1 –C 4 alkyl, C 3 –C 4 2-alkenyl, C 4 3-alkenyl or C 10 non-allenic alkadienyl and uses thereof in imparting, augmenting or enhancing the aroma and/or taste of a consumable material such as a perfume composition, a cologne, a perfumed article such as a soap, cosmetic, hair preparation or detergent, a foodstuff, a chewing gum or an alcoholic or non-alcoholic beverage such as a carbonated beverage or fruit liquer. Also described is a process for synthesis of such enol ethers by means of (i) first forming an acetal having the structure:n R 1 —CH 2 —CH(OR 2 ) 2 n(ii) then carrying out a thermal decomposition reaction at pH<7 and then (iii) fractionally distilling the resulting reaction product to provide the enol ether.
参考文献:10.1007/978-3-030-58975-2_26 摘要:Barrales-Cureño HJ, Salgado-Garciglia R, López-Valdez LG, Reynoso-López R, Herrera-Cabrera BE, Lucho-Constantino GG, Zaragoza-Martínez F, Reyes-Reyes C, Aftab T. Use of Secondary Metabolites from Medicinal and Aromatic Plants in the Fragrance Industry. 2021. In: Medicinal and Aromatic Plants.